Write Lewis structures that obey the octet rule (duet rule for H) for each of the following molecules. Carbon is the central atom in \(\mathrm{CH}_{4}\), nitrogen is the central atom in \(\mathrm{NH}_{3}\), and oxygen is the central atom in \(\mathrm{H}_{2} \mathrm{O}\). a. \(\mathrm{F}_{2}\) \(\mathbf{b} . \mathbf{O}_{2}\) c. CO d. \(\overline{\mathrm{CH}_{4}}\) \(\mathbf{e} . \mathrm{NH}_{3}\) \(\mathbf{f .} \quad \mathbf{H}_{2} \mathbf{O}\) g. IIF

Short Answer

Expert verified
Lewis structures: a. F2: F - F b. O2: O = O c. CO: C ≡ O d. CH4: H | C - H | H e. NH3: H | N - H - H f. H2O: H - O - H g. IIF: I - F

Step by step solution

01

a. \(\mathrm{F}_{2}\)

1. Count the valence electrons: Fluorine has 7 valence electrons, so the total for F2 is 14. 2. Create a single bond between the fluorine atoms, accounting for 2 electrons. 3. Distribute the remaining 12 electrons in pairs to the outside atoms (fluorine) to satisfy the octet rule for each atom. Lewis structure for F2: F - F
02

b. \(\mathrm{O}_{2}\)

1. Count the valence electrons: Oxygen has 6 valence electrons, so the total for O2 is 12. 2. Create a double bond between the oxygen atoms, accounting for 4 electrons. 3. Distribute the remaining 8 electrons in pairs to the outside atoms (oxygen) to satisfy the octet rule for each atom. Lewis structure for O2: O = O
03

c. CO

1. Count the valence electrons: Carbon has 4 and oxygen has 6, so the total is 10. 2. Create a triple bond between the carbon and oxygen atoms, accounting for 6 electrons. 3. Distribute the remaining 4 electrons in pairs to the outside atom (oxygen) to satisfy the octet rule for each atom. Lewis structure for CO: C ≡ O
04

d. \(\mathrm{CH}_{4}\)

1. Count the valence electrons: Carbon has 4 and each hydrogen has 1, so the total is 8. 2. Create a single bond between the central atom (carbon) and the hydrogen atoms, accounting for 4 electrons. 3. Distribute the remaining 4 electrons in pairs to the hydrogen atoms to satisfy the duet rule for each hydrogen atom. Lewis structure for CH4: H | C - H | H
05

e. \(\mathrm{NH}_{3}\)

1. Count the valence electrons: Nitrogen has 5 and each hydrogen has 1, so the total is 8. 2. Create a single bond between the central atom (nitrogen) and the hydrogen atoms, accounting for 3 electrons. 3. Distribute the remaining 5 electrons: 3 as a lone pair on the nitrogen atom, and 2 as a pair to one hydrogen atom to satisfy the duet rule for each hydrogen atom. Lewis structure for NH3: H | N - H - H
06

f. \(\mathrm{H}_{2}\mathrm{O}\)

1. Count the valence electrons: Oxygen has 6 and each hydrogen has 1, so the total is 8. 2. Create a single bond between the central atom (oxygen) and the hydrogen atoms, accounting for 2 electrons. 3. Distribute the remaining 6 electrons in pairs to the outside hydrogen atoms to satisfy the duet rule for each hydrogen atom. Lewis structure for H2O: H - O - H
07

g. IIF

1. Count the valence electrons: Iodine has 7 and fluorine has 7, so the total is 14. 2. Create a single bond between the central atom (iodine) and the fluorine atoms, accounting for 2 electrons. 3. Distribute the remaining 12 electrons in pairs to the outside atoms (iodine and fluorine) to satisfy the octet rule for each atom. Lewis structure for IIF: I - F

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