Write Lewis structures that obey the octet rule for each of the following molecules. a. \(\mathrm{CCl}_{4}\) b. \(\mathrm{NCl}_{3}\) c. \(\operatorname{Sec} 1_{2}\) d. ICl In each case, the atom listed first is the central atom.

Short Answer

Expert verified
a. The Lewis structure of \(\mathrm{CCl}_{4}\): Cl | Cl - C - Cl | Cl b. The Lewis structure of \(\mathrm{NCl}_{3}\): Cl | Cl - N - Cl : c. The Lewis structure of \(SeO_{2}\): O : O - Se - O : d. The Lewis structure of ICl: I - Cl : : :

Step by step solution

01

a. Drawing the Lewis Structure of \(\mathrm{CCl}_{4}\)

1. Determine the total number of valence electrons: Carbon has 4 valence electrons and each chlorine atom has 7. Since there are 4 chlorine atoms, the total number of valence electrons is 4 + (4 × 7) = 32. 2. Identify the central atom: Carbon is the central atom. 3. Connect the chlorine atoms to the central carbon atom with single bonds: C-Cl. We have used 8 valence electrons so far. 4. Complete the octets of chlorine atoms by adding lone pair electrons to each chlorine atom: Each Cl atom needs 6 more electrons (3 lone pairs) to complete the octet. Thus, the Lewis structure of \(\mathrm{CCl}_{4}\) becomes: Cl | Cl - C - Cl | Cl
02

b. Drawing the Lewis Structure of \(\mathrm{NCl}_{3}\)

1. Determine the total number of valence electrons: Nitrogen has 5 valence electrons and each chlorine atom has 7. Since there are 3 chlorine atoms, the total number of valence electrons is 5 + (3 × 7) = 26. 2. Identify the central atom: Nitrogen is the central atom. 3. Connect the chlorine atoms to the central nitrogen atom with single bonds: N-Cl. We have used 6 valence electrons so far. 4. Complete the octets of chlorine atoms and nitrogen atom by adding lone pair electrons: Each Cl atom needs 6 more electrons (3 lone pairs) to complete the octet. Nitrogen needs 2 more electrons (1 lone pair) to complete the octet. The Lewis structure of \(\mathrm{NCl}_{3}\) becomes: Cl | Cl - N - Cl :
03

c. Drawing the Lewis Structure of \(SeO_{2}\)

1. Determine the total number of valence electrons: Selenium has 6 valence electrons and each oxygen atom has 6. Since there are 2 oxygen atoms, the total number of valence electrons is 6 + (2 × 6) = 18. 2. Identify the central atom: Selenium is the central atom. 3. Connect the oxygen atoms to the central selenium atom with single bonds: Se-O. We have used 4 valence electrons so far. 4. Complete the octets of oxygen atoms and selenium atom by adding lone pair electrons: Each O atom needs 6 more electrons (3 lone pairs) to complete the octet. Selenium needs 2 more electrons (1 lone pair) to complete the octet. The Lewis structure of \(SeO_{2}\) becomes: O : O - Se - O :
04

d. Drawing the Lewis Structure of ICl

1. Determine the total number of valence electrons: Iodine has 7 valence electrons and chlorine has 7 valence electrons, for a total number of valence electrons of 7 + 7 = 14. 2. Identify the central atom: Iodine is the central atom. 3. Connect the chlorine atom to the central iodine atom with a single bond: I-Cl. We have used 2 valence electrons so far. 4. Complete the octets of iodine and chlorine atoms by adding lone pair electrons: Each atom needs 6 more electrons (3 lone pairs) to complete the octet. The Lewis structure of ICl becomes: I - Cl : : :

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Most popular questions from this chapter

The formulas and common names for several substances are given below. Give the systematic names for these substances. a. sugar of lead b. blue vitrol c. quicklime d. Epsom salts e. milk of magnesia f. gypsum g. laughing gas \(\mathrm{Pb}\left(\mathrm{C}_{2} \mathrm{H}_{3} \mathrm{O}_{2}\right)_{2}\) \(\mathrm{CuSO}_{4}\) CaO \(\mathrm{MgSO}_{4}\) \(\mathrm{Mg}(\mathrm{OH})_{2}\) \(\mathrm{CaSO}_{4}\) \(\mathrm{N}_{2} \mathrm{O}\)

Without using Fig. \(3-4,\) predict which bond in each of the following groups will be the most polar. a. \(C-F, S i-F, G e-F\) b. \(P-C\) or \(S-C\) \(\mathbf{c} . \mathbf{S}-\mathbf{F}, \mathbf{S}-\mathbf{C} \mathbf{l}, \mathbf{S}-\mathbf{B r}\) d. \(\mathrm{Ti}-\mathrm{Cl}, \mathrm{Si}-\mathrm{Cl}, \mathrm{Ge}-\mathrm{Cl}\)

Write Lewis structures for \(\mathrm{CO}_{3}^{2-}, \mathrm{HCO}_{3}^{-},\) and \(\mathrm{H}_{2} \mathrm{CO}_{3}\). When acid is added to an aqueous solution containing carbonate or bicarbonate ions, carbon dioxide gas is formed. We generally say that carbonic acid \(\left(\mathrm{H}_{2} \mathrm{CO}_{3}\right)\) is unstable. Use bond energies to estimate \(\Delta E\) for the reaction (in the gas phase) $$\mathrm{H}_{2} \mathrm{CO}_{3} \longrightarrow \mathrm{CO}_{2}+\mathrm{H}_{2} \mathrm{O}$$Specify a possible cause for the instability of carbonic acid.

By analogy with phosphorus compounds, name the following: \(\mathrm{Na}_{3} \mathrm{AsO}_{4}, \mathrm{H}_{3} \mathrm{AsO}_{4}, \mathrm{Mg}_{3}\left(\mathrm{SbO}_{4}\right)_{2}\)

For each of the following, write an equation that corresponds to the energy given. a. lattice energy of \(\mathrm{NaCl}\) b. lattice energy of \(\mathrm{NH}_{4} \mathrm{Br}\) c. lattice energy of \(\mathrm{MgS}\) d. \(O=O\) double bond energy beginning with \(O_{2}(g)\) as a reactant

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