A mixture contains only \(\mathrm{NaCl}\) and \(\mathrm{Fe}\left(\mathrm{NO}_{3}\right)_{3} .\) A \(0.456-\mathrm{g}\) sample of the mixture is dissolved in water, and an excess of NaOH is added, producing a precipitate of \(\mathrm{Fe}(\mathrm{OH})_{3} .\) The precipitate is filtered, dried, and weighed. Its mass is 0.107 g. Calculate the following. a. the mass of iron in the sample b. the mass of \(\mathrm{Fe}\left(\mathrm{NO}_{3}\right)_{3}\) in the sample c. the mass percent of \(\mathrm{Fe}\left(\mathrm{NO}_{3}\right)_{3}\) in the sample

Short Answer

Expert verified
a. The mass of iron in the sample is \(0.0352 \ \mathrm{g}\). b. The mass of \(\mathrm{Fe}(\mathrm{NO}_{3})_{3}\) in the sample is \(0.152 \ \mathrm{g}\). c. The mass percent of \(\mathrm{Fe}(\mathrm{NO}_{3})_{3}\) in the sample is \(33.3\% \).

Step by step solution

01

Calculate moles of \(\mathrm{Fe}(\mathrm{OH})_{3}\)

First, we need to find the moles of \(\mathrm{Fe}(\mathrm{OH})_{3}\) produced in the precipitate. To do this, we'll use its molar mass (1 mole of \(\mathrm{Fe}(\mathrm{OH})_{3}\) equals \(169.87 \ \mathrm{g/mol}\)). $$ \mathrm{moles} \ \mathrm{Fe}(\mathrm{OH})_{3} = \dfrac{\mathrm{mass} \ \mathrm{Fe}(\mathrm{OH})_{3}}{\mathrm{Molar} \ \mathrm{mass} \ \mathrm{Fe}(\mathrm{OH})_{3}} = \dfrac{0.107 \ \mathrm{g}}{169.87 \ \mathrm{g/mol}} = 6.3 \times 10^{-4} \ \mathrm{mol} $$
02

Calculate moles of \(\mathrm{Fe}\) in the sample

Next, we'll use stoichiometry to determine the moles of \(\mathrm{Fe}\) in the sample. Since for every 1 mole of \(\mathrm{Fe}(\mathrm{OH})_{3}\) produced, there is 1 mole of \(\mathrm{Fe}\): $$ \mathrm{moles} \ \mathrm{Fe} = \mathrm{moles} \ \mathrm{Fe}(\mathrm{OH})_{3} = 6.3 \times 10^{-4} \ \mathrm{mol} $$
03

Find the mass of \(\mathrm{Fe}\) in the sample

Now, we can calculate the mass of \(\mathrm{Fe}\) in the sample using its molar mass (1 mole of \(\mathrm{Fe}\) equals \(55.85 \ \mathrm{g/mol}\)): $$ \mathrm{mass} \ \mathrm{Fe} = \mathrm{moles} \ \mathrm{Fe} \times \mathrm{molar} \ \mathrm{mass} \ \mathrm{Fe} = 6.3 \times 10^{-4} \ \mathrm{mol} \times 55.85 \ \mathrm{g/mol} = 0.0352 \ \mathrm{g} $$ This is the answer to part (a).
04

Calculate the mass of \(\mathrm{Fe}(\mathrm{NO}_{3})_{3}\) in the sample

We can now calculate the mass of \(\mathrm{Fe}(\mathrm{NO}_{3})_{3}\) in the sample by using stoichiometry and the molar mass of \(\mathrm{Fe}(\mathrm{NO}_{3})_{3}\) (1 mole of \(\mathrm{Fe}(\mathrm{NO}_{3})_{3}\) equals \(241.86 \ \mathrm{g/mol}\)): $$ \mathrm{mass} \ \mathrm{Fe}(\mathrm{NO}_{3})_{3} = \mathrm{moles} \ \mathrm{Fe} \times \mathrm{molar} \ \mathrm{mass} \ \mathrm{Fe}(\mathrm{NO}_{3})_{3} = 6.3 \times 10^{-4} \ \mathrm{mol} \times 241.86 \ \mathrm{g/mol} = 0.152 \ \mathrm{g} $$ This is the answer to part (b).
05

Calculate the mass percent of \(\mathrm{Fe}(\mathrm{NO}_{3})_{3}\) in the sample

Finally, calculate the mass percent of \(\mathrm{Fe}(\mathrm{NO}_{3})_{3}\) in the sample by dividing the mass of \(\mathrm{Fe}(\mathrm{NO}_{3})_{3}\) by the mass of the sample: $$ \mathrm{Mass} \ \mathrm{Percent} \ \mathrm{Fe}(\mathrm{NO}_{3})_{3} = \dfrac{\mathrm{mass} \ \mathrm{Fe}(\mathrm{NO}_{3})_{3}}{\mathrm{mass} \ \mathrm{sample}} \times 100 = \dfrac{0.152 \ \mathrm{g}}{0.456 \ \mathrm{g}} \times 100 = 33.3 \% $$ This is the answer to part (c).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Understanding the Mole Concept
The mole concept is a fundamental principle in chemistry that helps us quantify the number of particles, such as atoms or molecules, in a given sample. A mole is defined as the amount of substance containing as many elementary entities (atoms, molecules, ions, etc.) as there are atoms in 12 grams of carbon-12. This number is known as Avogadro’s number and is approximately equal to \(6.022 \times 10^{23}\).

When it comes to chemical reactions and stoichiometry, the mole concept allows us to convert between the mass of a substance and the number of moles, providing a bridge between the macroscopic world we can measure and the microscopic world of atoms and molecules.For example, in the textbook exercise we examined, we converted the mass of iron (III) hydroxide precipitate to moles using the molar mass, which illustrates the practical application of the mole concept in solving real-world chemistry problems.
Navigating Chemical Reactions
A chemical reaction is a process where reactants are transformed into products. Understanding chemical reactions involves recognizing how reactants are converted into products, usually via the breaking and forming of chemical bonds, and how the Law of Conservation of Mass applies. This law states that matter cannot be created or destroyed in a chemical reaction.

Using stoichiometry, we can use balanced chemical equations to relate the quantities of reactants and products. Stoichiometry is the quantitative relationship between the substances in a chemical reaction. The coefficients in the balanced chemical equation tell us the ratio in which reactants combine and products form. In the provided exercise, the stoichiometry between iron (III) nitrate and iron (III) hydroxide plays a crucial role in determining the mass and mass percent of iron (III) nitrate in the sample.
Calculating with Molar Mass
Molar mass is the mass of one mole of a substance (usually in grams per mole, g/mol) and is numerically equal to the substance’s relative atomic or molecular mass in atomic mass units (amu). Determining the molar mass of a compound involves adding the molar masses of the individual elements present in the formula, with their corresponding atomic molar masses and ratios considered.

Knowing the molar mass allows chemists to calculate the number of moles in a given sample of a substance (and vice versa) by dividing the sample mass by the molar mass. For instance, in calculating the mass of iron (III) nitrate from the mass of iron (III) hydroxide in the problem solution, the molar masses of both compounds were essential. Without accurate molar masses, our stoichiometric calculations would be incorrect, showing the critical role molar mass plays in quantifying aspects of a chemical reaction.

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Most popular questions from this chapter

A 50.00 -mL sample of aqueous \(\mathrm{Ca}(\mathrm{OH})_{2}\) requires \(34.66 \mathrm{mL}\) of a 0.944-M nitric acid for neutralization. Calculate the concentration (molarity) of the original solution of calcium hydroxide.

You are given a \(1.50-g\) mixture of sodium nitrate and sodium chloride. You dissolve this mixture into \(100 \mathrm{mL}\) of water and then add an excess of 0.500 \(M\) silver nitrate solution. You produce a white solid, which you then collect, dry, and measure. The white solid has a mass of 0.64 \(1 \mathrm{g}\). a. If you had an extremely magnified view of the solution (to the atomic- molecular level), list the species you would see (include charges, if any). b. Write the balanced net ionic equation for the reaction that produces the solid. Include phases and charges. c. Calculate the percent sodium chloride in the original unknown mixture.

A \(25.00-\mathrm{mL}\) sample of hydrochloric acid solution requires \(24.16 \mathrm{mL}\) of \(0.106 \mathrm{M}\) sodium hydroxide for complete neutralization. What is the concentration of the original hydrochloric acid solution?

When organic compounds containing sulfur are burned, sulfur dioxide is produced. The amount of \(\mathrm{SO}_{2}\) formed can be determined by the reaction with hydrogen peroxide: $$ \mathrm{H}_{2} \mathrm{O}_{2}(a q)+\mathrm{SO}_{2}(g) \longrightarrow \mathrm{H}_{2} \mathrm{SO}_{4}(a q) $$ The resulting sulfuric acid is then titrated with a standard NaOH solution. A 1.302 -g sample of coal is burned and the \(\mathrm{SO}_{2}\) is collected in a solution of hydrogen peroxide. It took \(28.44 \mathrm{mL}\) of a \(0.1000-M \mathrm{NaOH}\) solution to titrate the resulting sulfuric acid. Calculate the mass percent of sulfur in the coal sample. Sulfuric acid has two acidic hydrogens.

A stream flows at a rate of \(5.00 \times 10^{4}\) liters per second (L/s) upstream of a manufacturing plant. The plant discharges \(3.50 \times 10^{3} \mathrm{L} / \mathrm{s}\) of water that contains \(65.0 \mathrm{ppm}\) HCl into the stream. (See Exercise 123 for definitions.) a. Calculate the stream's total flow rate downstream from this plant. b. Calculate the concentration of HCl in ppm downstream from this plant. c. Further downstream, another manufacturing plant diverts \(1.80 \times 10^{4} \mathrm{L} / \mathrm{s}\) of water from the stream for its own use. This plant must first neutralize the acid and does so by adding lime: $$ \mathrm{CaO}(s)+2 \mathrm{H}^{+}(a q) \longrightarrow \mathrm{Ca}^{2+}(a q)+\mathrm{H}_{2} \mathrm{O}(i) $$ What mass of \(\mathrm{CaO}\) is consumed in an 8.00 -h work day by this plant? d. The original stream water contained \(10.2 \mathrm{ppm} \mathrm{Ca}^{2+} .\) Although no calcium was in the waste water from the first plant, the waste water of the second plant contains \(\mathrm{Ca}^{2+}\) from the neutralization process. If \(90.0 \%\) of the water used by the second plant is returned to the stream, calculate the concentration of \(\mathrm{Ca}^{2+}\) in ppm downstream of the second plant.

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