Complete and balance each acid-base reaction. a. \(\mathrm{H}_{3} \mathrm{PO}_{4}(a q)+\mathrm{NaOH}(a q) \rightarrow\) Contains three acidic hydrogens b. \(\mathrm{H}_{2} \mathrm{SO}_{4}(a q)+\mathrm{Al}(\mathrm{OH})_{3}(s) \rightarrow\) Contains two acidic hydrogens c. \(\mathrm{H}_{2} \mathrm{Se}(a q)+\mathrm{Ba}(\mathrm{OH})_{2}(a q) \rightarrow\) Contains two acidic hydrogens d. \(\mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4}(a q)+\mathrm{NaOH}(a q) \rightarrow\)

Short Answer

Expert verified
a. \(H_{3}PO_{4}(aq) + 3NaOH(aq) \rightarrow Na_{3}PO_{4}(aq) + 3H_{2}O(l)\) b. \(3H_{2}SO_{4}(aq) + 2Al(OH)_{3}(s) \rightarrow Al_{2}(SO_{4})_{3}(aq) + 6H_{2}O(l)\) c. \(H_{2}Se(aq) + Ba(OH)_{2}(aq) \rightarrow BaSe(aq) + 2H_{2}O(l)\) d. \(H_{2}C_{2}O_{4}(aq) + 2NaOH(aq) \rightarrow Na_{2}C_{2}O_{4}(aq) + 2H_{2}O(l)\)

Step by step solution

01

a. Complete and balance the H3PO4 and NaOH reaction:

To complete this reaction, we need to identify the products. When an acid reacts with a base, the resulting products are a salt and water. In this case, phosphoric acid (H3PO4) reacts with sodium hydroxide (NaOH). Their reaction will produce sodium phosphate (Na3PO4) and water (H2O). Next, we must balance the equation. The balanced equation for this reaction is: \[H_{3}PO_{4}(aq) + 3NaOH(aq) \rightarrow Na_{3}PO_{4}(aq) + 3H_{2}O(l)\]
02

b. Complete and balance the H₂SO₄ and Al(OH)₃ reaction:

This reaction will produce aluminum sulfate (Al₂(SO₄)₃) and water (H2O). The balanced equation for this reaction is: \[3H_{2}SO_{4}(aq) + 2Al(OH)_{3}(s) \rightarrow Al_{2}(SO_{4})_{3}(aq) + 6H_{2}O(l)\]
03

c. Complete and balance the H₂Se and Ba(OH)₂ reaction:

This reaction will produce barium selenide (BaSe) and water (H2O). The balanced equation for this reaction is: \[H_{2}Se(aq) + Ba(OH)_{2}(aq) \rightarrow BaSe(aq) + 2H_{2}O(l)\]
04

d. Complete and balance the H₂C₂O₄ and NaOH reaction:

This reaction will produce sodium oxalate (Na₂C₂O₄) and water (H2O). The balanced equation for this reaction is: \[H_{2}C_{2}O_{4}(aq) + 2NaOH(aq) \rightarrow Na_{2}C_{2}O_{4}(aq) + 2H_{2}O(l)\]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Chemical Equation Balancing
Balancing chemical equations is similar to the art of ensuring both sides of a scale weigh the same. In a balanced chemical equation, the number of atoms for each element must be equal on the reactant and product sides. This maintains the law of conservation of mass, which states that mass is neither created nor destroyed in a chemical reaction.

For example, in the reaction of phosphoric acid (H3PO4) with sodium hydroxide (NaOH), we balance the equation by ensuring that there are equal numbers of hydrogen, oxygen, phosphorus, and sodium atoms on both sides. We find that we need three NaOH molecules to balance the three hydrogen atoms in H3PO4, resulting in the balanced reaction: \[H_{3}PO_{4}(aq) + 3NaOH(aq) \rightarrow Na_{3}PO_{4}(aq) + 3H_{2}O(l)\]

Tips for Balancing Equations

  • Start by balancing the atoms of elements that appear only once on each side.
  • Balance hydrogen and oxygen atoms last, as they often appear in multiple compounds.
  • Adjust coefficients, numbers in front of compounds, to balance atoms rather than changing subscripts, which can alter the compound's identity.
Acid-Base Neutralization
Acid-base neutralization is the heart of a titration. Imagine it as a dance between acids and bases where they come together to form water and salt. An acid carries hydrogen ions (H+) while a base come equipped with hydroxide ions (OH-). When they react, they form water (H2O) and an ionic compound known as a salt.

For instance, the neutralization reaction between sulfuric acid (H2SO4) and aluminum hydroxide [Al(OH)3] leads to:\[3H_{2}SO_{4}(aq) + 2Al(OH)_{3}(s) \rightarrow Al_{2}(SO_{4})_{3}(aq) + 6H_{2}O(l)\]Here, we witness each pair of acid and base yielding their ions, which marry to produce the salt aluminum sulfate (Al2(SO4)3) and water.

Neutralization reactions are pivotal in various applications such as antacid tablets combating stomach acid, or environmental strategies to neutralize acidic lake water.
Stoichiometry
Stoichiometry might sound complex, but it's simply the calculation of reactants and products in chemical reactions. It is the recipe for chemistry, providing precise measurements to get just the right outcome. This mathematical method of stoichiometry uses the balanced equation as a basis to compare amounts in moles.

Consider the stoichiometric relationship in the reaction of hydrogen selenide (H2Se) and barium hydroxide (Ba(OH)2), which is described by the equation:\[H_{2}Se(aq) + Ba(OH)_{2}(aq) \rightarrow BaSe(aq) + 2H_{2}O(l)\]The coefficients in the balanced equation tell us that one mole of H2Se reacts with one mole of Ba(OH)2 to produce one mole of BaSe and two moles of water. Stoichiometry helps us predict the amount of each substance needed or formed in a reaction, vital for applications in chemical manufacturing and understanding natural processes.
Salt Formation in Reactions
When we hear 'salt', we often think of the common table salt, but in chemistry, salts are so much more. They are the offspring of acid-base neutralization reactions. A salt is an ionic compound composed of a cation from a base and an anion from an acid.

For example, sodium oxalate (Na2C2O4) is a salt that forms when oxalic acid (H2C2O4) reacts with sodium hydroxide (NaOH), as shown:\[H_{2}C_{2}O_{4}(aq) + 2NaOH(aq) \rightarrow Na_{2}C_{2}O_{4}(aq) + 2H_{2}O(l)\]The sodium ions (Na+) from NaOH replace the hydrogen ions (H+) from oxalic acid, and voilà, we get sodium oxalate. Such salt formation is fundamental in countless products, from soaps and detergents to medications and fertilizers, illustrating the immense practicality of understanding these reactions.

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Most popular questions from this chapter

Assign oxidation states for all atoms in each of the following compounds. a. \(U O_{2}^{2+}\) f. \(\mathrm{Mg}_{2} \mathrm{P}_{2} \mathrm{O}_{7}\) b. \(\mathrm{As}_{2} \mathrm{O}_{3}\) g. \(\mathrm{Na}_{2} \mathrm{S}_{2} \mathrm{O}_{3}\) c. \(\mathrm{NaBiO}_{3}\) h. \(\mathrm{Hg}_{2} \mathrm{Cl}_{2}\) d. \(\mathrm{As}_{4}\) i. \(\quad \mathrm{Ca}\left(\mathrm{NO}_{3}\right)_{2}\) e. \(\mathrm{HAsO}_{2}\)

Saccharin \(\left(\mathrm{C}_{7} \mathrm{H}_{5} \mathrm{NO}_{3} \mathrm{S}\right)\) is sometimes dispensed in tablet form. Ten tablets with a total mass of 0.5894 g were dissolved in water. The saccharin was oxidized to convert all the sulfur to sulfate ion, which was precipitated by adding an excess of barium chloride solution. The mass of BaSO_ obtained was \(0.5032 \mathrm{g} .\) What is the average mass of saccharin per tablet? What is the average mass percent of saccharin in the tablets?

Specify which of the following are oxidation-reduction reactions, and identify the oxidizing agent, the reducing agent, the substance being oxidized, and the substance being reduced. a. \(\mathrm{Cu}(s)+2 \mathrm{Ag}^{+}(a q) \rightarrow 2 \mathrm{Ag}(s)+\mathrm{Cu}^{2+}(a q)\) b. \(\mathrm{HCl}(g)+\mathrm{NH}_{3}(g) \rightarrow \mathrm{NH}_{4} \mathrm{Cl}(s)\) c. \(\mathrm{SiCl}_{4}(l)+2 \mathrm{H}_{2} \mathrm{O}(l) \rightarrow 4 \mathrm{HCl}(a q)+\mathrm{SiO}_{2}(s)\) d. \(\mathrm{SiCl}_{4}(l)+2 \mathrm{Mg}(s) \rightarrow 2 \mathrm{MgCl}_{2}(s)+\mathrm{Si}(s)\) e. \(\mathrm{Al}(\mathrm{OH})_{4}^{-}(a q) \rightarrow \mathrm{AlO}_{2}^{-}(a q)+2 \mathrm{H}_{2} \mathrm{O}(i)\)

A 100.0-mL aliquot of 0.200 \(M\) aqueous potassium hydroxide is mixed with \(100.0 \mathrm{mL}\) of \(0.200 \mathrm{M}\) aqueous magnesium nitrate. a. Write a balanced chemical equation for any reaction that occurs. b. What precipitate forms? c. What mass of precipitate is produced? d. Calculate the concentration of each ion remaining in solution after precipitation is complete.

Consider the reaction between sodium metal and fluorine ( \(\mathbf{F}_{2}\) ) gas to form sodium fluoride. Using oxidation states, how many electrons would each sodium atom lose, and how many electrons would each fluorine atom gain? How many sodium atoms are needed to react with one fluorine molecule? Write a balanced equation for this reaction.

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