Given the following data $$\begin{array}{ll}\mathrm{Fe}_{2} \mathrm{O}_{3}(s)+3 \mathrm{CO}(g) \longrightarrow 2 \mathrm{Fe}(s)+3 \mathrm{CO}_{2}(g) & \Delta H^{\circ}=-23 \mathrm{kJ} \\ 3 \mathrm{Fe}_{2} \mathrm{O}_{3}(s)+\mathrm{CO}(g) \longrightarrow 2 \mathrm{Fe}_{3} \mathrm{O}_{4}(s)+\mathrm{CO}_{2}(g) & \Delta H^{\circ}=-39 \mathrm{kJ} \\ \mathrm{Fe}_{3} \mathrm{O}_{4}(s)+\mathrm{CO}(g) \longrightarrow 3 \mathrm{FeO}(s)+\mathrm{CO}_{2}(g) & \Delta H^{\circ}=18 \mathrm{kJ} \end{array}$$ calculate \(\Delta H^{\circ}\) for the reaction $$\mathrm{FeO}(s)+\mathrm{CO}(g) \longrightarrow \mathrm{Fe}(s)+\mathrm{CO}_{2}(g)$$

Short Answer

Expert verified
The calculated enthalpy change for the desired reaction is \(\Delta H^{\circ}_{\mathrm{FeO}(s)+\mathrm{CO}(g) \longrightarrow \mathrm{Fe}(s)+\mathrm{CO}_{2}(g)} = 9.17 \,\mathrm{kJ}\).

Step by step solution

01

Analyzing the target reaction

Compare the given reactions with the desired reaction. We can see that all the substances in the target reaction are present in the given reactions. We will use the given reactions to extract the necessary information to find the enthalpy change for the target reaction.
02

Manipulate the given reactions

First, we have to manipulate the given reactions to match the target reaction. We can find the desired equation by adding a combination of these reactions. We notice that to cancel out the \(\mathrm{Fe}_{2}\mathrm{O}_{3}\), we need to reverse the direction of the first two reactions. $$-\Delta H^{\circ} = -[\mathrm{Fe}_{2} \mathrm{O}_{3}(s)+3 \mathrm{CO}(g) \longrightarrow 2 \mathrm{Fe}(s)+3 \mathrm{CO}_{2}(g)]$$ $$-\Delta H^{\circ} = -[3 \mathrm{Fe}_{2} \mathrm{O}_{3}(s)+\mathrm{CO}(g) \longrightarrow 2 \mathrm{Fe}_{3} \mathrm{O}_{4}(s)+\mathrm{CO}_{2}(g)]$$ Before we add up these equations, we need to ensure the substances we don't need to cancel each other out. Thus, we can rewrite the equations as: $$\frac{1}{3}\times(-\Delta H^{\circ} = -[\mathrm{Fe}_{2} \mathrm{O}_{3}(s)+3 \mathrm{CO}(g) \longrightarrow 2 \mathrm{Fe}(s)+3 \mathrm{CO}_{2}(g)])$$ $$\frac{1}{2}\times(-\Delta H^{\circ} = -[3 \mathrm{Fe}_{2} \mathrm{O}_{3}(s)+\mathrm{CO}(g) \longrightarrow 2 \mathrm{Fe}_{3} \mathrm{O}_{4}(s)+\mathrm{CO}_{2}(g)])$$ $$\Delta H^{\circ} = [\mathrm{Fe}_{3} \mathrm{O}_{4}(s)+\mathrm{CO}(g) \longrightarrow 3 \mathrm{FeO}(s)+\mathrm{CO}_{2}(g)]$$ Now we can add up these equations getting: $$\mathrm{FeO}(s)+\mathrm{CO}(g) \longrightarrow \mathrm{Fe}(s)+\mathrm{CO}_{2}(g)$$
03

Calculate the enthalpy change for the target reaction

Now that we have obtained the linear combination of the given reactions to get the desired reaction, we can find the enthalpy change for this reaction by summing the enthalpy change of the given reactions after manipulating them. We have: $$\Delta H^{\circ}_{target} = \frac{-1}{3}\times(-23 \,\mathrm{kJ}) + \frac{-1}{2}\times(-39\, \mathrm{kJ}) + 18\, \mathrm{kJ}$$ $$\Delta H^{\circ}_{target} = \frac{23}{3} \,\mathrm{kJ} + \frac{39}{2}\, \mathrm{kJ} - 18\, \mathrm{kJ}$$ Calculating the enthalpy change for the target reaction: $$\Delta H^{\circ}_{target} = 7.67 \,\mathrm{kJ} + 19.5\, \mathrm{kJ} - 18\, \mathrm{kJ} =\boldsymbol{9.17\, \mathrm{kJ}}$$ The calculated enthalpy change for the desired reaction is \(\Delta H^{\circ}_{\mathrm{FeO}(s)+\mathrm{CO}(g) \longrightarrow \mathrm{Fe}(s)+\mathrm{CO}_{2}(g)} = 9.17 \,\mathrm{kJ}\).

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Most popular questions from this chapter

As a system increases in volume, it absorbs \(52.5 \mathrm{J}\) of energy in the form of heat from the surroundings. The piston is working against a pressure of \(0.500 \mathrm{atm}\). The final volume of the system is \(58.0 \mathrm{L}\). What was the initial volume of the system if the internal energy of the system decreased by \(102.5 \mathrm{J} ?\)

A sample of nickel is heated to \(99.8^{\circ} \mathrm{C}\) and placed in a coffeecup calorimeter containing \(150.0 \mathrm{g}\) water at \(23.5^{\circ} \mathrm{C}\). After the metal cools, the final temperature of metal and water mixture is \(25.0^{\circ} \mathrm{C} .\) If the specific heat capacity of nickel is \(0.444 \mathrm{J} /^{\circ} \mathrm{C} \cdot \mathrm{g}\) what mass of nickel was originally heated? Assume no heat loss to the surroundings.

Which of the following processes are exothermic? a. \(\mathrm{N}_{2}(g) \longrightarrow 2 \mathrm{N}(g)\) b. \(\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{H}_{2} \mathrm{O}(s)\) c. \(\mathrm{Cl}_{2}(g) \longrightarrow 2 \mathrm{Cl}(g)\) d. \(2 \mathrm{H}_{2}(g)+\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{H}_{2} \mathrm{O}(g)\) e. \(\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{O}(g)\)

On Easter Sunday, April \(3,1983,\) nitric acid spilled from a tank car near downtown Denver, Colorado. The spill was neutralized with sodium carbonate: $$2 \mathrm{HNO}_{3}(a q)+\mathrm{Na}_{2} \mathrm{CO}_{3}(s) \longrightarrow 2 \mathrm{NaNO}_{3}(a q)+\mathrm{H}_{2} \mathrm{O}(l)+\mathrm{CO}_{2}(g)$$ a. Calculate \(\Delta H^{\circ}\) for this reaction. Approximately \(2.0 \times\) \(10^{4}\) gal nitric acid was spilled. Assume that the acid was an aqueous solution containing \(70.0 \%\) HNO \(_{3}\) by mass with a density of \(1.42 \mathrm{g} / \mathrm{cm}^{3} .\) What mass of sodium carbonate was required for complete neutralization of the spill, and what quantity of heat was evolved? \((\Delta H_{\mathrm{f}}^{\circ}\) for \(\mathrm{NaNO}_{3}(a q)=-467 \mathrm{kJ} / \mathrm{mol})\) b. According to The Denver Post for April \(4,1983,\) authorities feared that dangerous air pollution might occur during the neutralization. Considering the magnitude of \(\Delta H^{\circ}\) what was their major concern?

Explain why oceanfront areas generally have smaller temperature fluctuations than inland areas.

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