Chapter 8: Problem 6
If you put a drinking straw in water, place your finger over the opening, and lift the straw out of the water, some water stays in the straw. Explain.
Chapter 8: Problem 6
If you put a drinking straw in water, place your finger over the opening, and lift the straw out of the water, some water stays in the straw. Explain.
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Get started for freeA hot-air balloon is filled with air to a volume of \(4.00 \times\) \(10^{3} \mathrm{m}^{3}\) at \(745\) torr and \(21^{\circ} \mathrm{C}\). The air in the balloon is then heated to \(62^{\circ} \mathrm{C},\) causing the balloon to expand to a volume of \(4.20 \times 10^{3} \mathrm{m}^{3} .\) What is the ratio of the number of moles of air in the heated balloon to the original number of moles of air in the balloon? (Hint: Openings in the balloon allow air to flow in and out. Thus the pressure in the balloon is always the same as that of the atmosphere.)
A tank contains a mixture of \(52.5 \mathrm{g}\) oxygen gas and \(65.1 \mathrm{g}\) carbon dioxide gas at \(27^{\circ} \mathrm{C}\). The total pressure in the tank is \(9.21\) atm. Calculate the partial pressures of each gas in the container.
In the presence of nitric acid, \(UO\) \(^{2+}\) undergoes a redox process. It is converted to \(\mathrm{UO}_{2}^{2+}\) and nitric oxide (NO) gas is produced according to the following unbalanced equation: $$\begin{aligned}\mathrm{H}^{+}(a q)+\mathrm{NO}_{3}^{-}(a q)+\mathrm{UO}^{2 *}(a q) & \longrightarrow \\\\\mathrm{NO}(g)+& \mathrm{UO}_{2}^{2+}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \end{aligned}$$ If \(2.55 \times 10^{2} \mathrm{mL} \mathrm{NO}(g)\) is isolated at \(29^{\circ} \mathrm{C}\) and \(1.5 \mathrm{atm}\), what amount (moles) of \(UO\) \(^{2+}\) was used in the reaction? (Hint: Balance the reaction by the oxidation states method.)
The oxides of Group \(2 \mathrm{A}\) metals (symbolized by M here) react with carbon dioxide according to the following reaction: $$\mathrm{MO}(s)+\mathrm{CO}_{2}(g) \longrightarrow \mathrm{MCO}_{3}(s)$$ A \(2.85\) \(-\mathrm{g}\) sample containing only \(\mathrm{MgO}\) and \(\mathrm{CuO}\) is placed in a 3.00 -L container. The container is filled with \(\mathrm{CO}_{2}\) to a pressure of \(740 .\) torr at \(20 .^{\circ} \mathrm{C}\). After the reaction has gone to completion, the pressure inside the flask is \(390 .\) torr at \(20 .^{\circ} \mathrm{C}\). What is the mass percent of \(MgO\) in the mixture? Assume that only the \(MgO\) reacts with \(\mathrm{CO}_{2}\)
Methane \(\left(\mathrm{CH}_{4}\right)\) gas flows into a combustion chamber at a rate of \(200 .\) L/min at \(1.50\) atm and ambient temperature. Air is added to the chamber at 1.00 atm and the same temperature, and the gases are ignited. a. To ensure complete combustion of \(\mathrm{CH}_{4}\) to \(\mathrm{CO}_{2}(g)\) and \(\mathrm{H}_{2} \mathrm{O}(g),\) three times as much oxygen as is necessary is reacted. Assuming air is \(21\) mole percent \(\mathrm{O}_{2}\) and \(79\) mole percent \(\mathrm{N}_{2}\), calculate the flow rate of air necessary to deliver the required amount of oxygen. b. Under the conditions in part a, combustion of methane was not complete as a mixture of \(\mathrm{CO}_{2}(g)\) and \(\mathrm{CO}(g)\) was produced. It was determined that \(95.0 \%\) of the carbon in the exhaust gas was present in \(\mathrm{CO}_{2}\). The remainder was present as carbon in \(\mathrm{CO}\). Calculate the composition of the exhaust gas in terms of mole fraction of \(\mathrm{CO}, \mathrm{CO}_{2}, \mathrm{O}_{2}, \mathrm{N}_{2}\) and \(\mathrm{H}_{2} \mathrm{O}\). Assume \(\mathrm{CH}_{4}\) is completely reacted and \(\mathrm{N}_{2}\) is unreacted.
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