Chapter 13: Problem 1
What does it mean to describe a reaction as "reversible"?
Short Answer
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chapter 13: Problem 1
What does it mean to describe a reaction as "reversible"?
These are the key concepts you need to understand to accurately answer the question.
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Get started for freeConsider the equilibrium \(4 \mathrm{NO}_{2}(g)+6 \mathrm{H}_{2} \mathrm{O}(g) \rightleftharpoons 4 \mathrm{NH}_{3}(g)+7 \mathrm{O}_{2}(g)\) (a) What is the expression for the equilibrium constant \(\left(K_{c}\right)\) of the reaction? (b) How must the concentration of \(\mathrm{NH}_{3}\) change to reach equilibrium if the reaction quotient is less than the equilibrium constant? (c) If the reaction were at equilibrium, how would an increase in the volume of the reaction vessel affect the pressure of \(\mathrm{NO}_{2} ?\) (d) If the change in the pressure of \(\mathrm{NO}_{2}\) is 28 torr as a mixture of the four gases reaches equilibrium, how much will the pressure of \(\mathrm{O}_{2}\) change?
If a reaction is reversible, when can it be said to have reached equilibrium?
How can the pressure of water vapor be increased in the following equilibrium? \(\mathrm{H}_{2} \mathrm{O}(l) \rightleftharpoons \mathrm{H}_{2} \mathrm{O}(g) \quad \Delta H=41 \mathrm{kJ}\)
Consider the following reaction at 298 K: \(\mathrm{N}_{2} \mathrm{O}_{4}(g) \rightleftharpoons 2 \mathrm{NO}_{2}(g)\) \(K_{P}=0.142\) What is the standard free energy change at this temperature? Describe what happens to the initial system, where the reactants and products are in standard states, as it approaches equilibrium.
Explain how to recognize the conditions under which changes in volume will affect gas-phase systems at equilibrium.
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