Chapter 13: Problem 28
Write the expression of the reaction quotient for the ionization of HOCN in water.
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These are the key concepts you need to understand to accurately answer the question.
Chapter 13: Problem 28
Write the expression of the reaction quotient for the ionization of HOCN in water.
These are the key concepts you need to understand to accurately answer the question.
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Get started for freeThe equilibrium constant \(\left(K_{c}\right)\) for this reaction is 5.0 at a given temperature. \(\mathrm{CO}(g)+\mathrm{H}_{2} \mathrm{O}(g) \rightleftharpoons \mathrm{CO}_{2}(g)+\mathrm{H}_{2}(g)\) (a) On analysis, an equilibrium mixture of the substances present at the given temperature was found to contain 0.20 mol of \(\mathrm{CO}, 0.30\) mol of water vapor, and \(0.90 \mathrm{mol}\) of \(\mathrm{H}_{2}\) in a liter. How many moles of \(\mathrm{CO}_{2}\) were there in the equilibrium mixture? (b) Maintaining the same temperature, additional \(\mathrm{H}_{2}\) was added to the system, and some water vapor was removed by drying. A new equilibrium mixture was thereby established containing 0.40 mol of \(\mathrm{CO}, 0.30\) mol of water vapor, and 1.2 mol of \(\mathrm{H}_{2}\) in a liter. How many moles of \(\mathrm{CO}_{2}\) were in the new equilibrium mixture? Compare this with the quantity in part (a), and discuss whether the second value is reasonable. Explain how it is possible for the water vapor concentration to be the same in the two equilibrium solutions even though some vapor was removed before the second equilibrium was established.
Write the mathematical expression for the reaction quotient, \(Q_{c}\), for each of the following reactions: (a) \(\mathrm{N}_{2}(g)+3 \mathrm{H}_{2}(g) \rightleftharpoons 2 \mathrm{NH}_{3}(g)\) (b) \(4 \mathrm{NH}_{3}(g)+5 \mathrm{O}_{2}(g) \rightleftharpoons 4 \mathrm{NO}(g)+6 \mathrm{H}_{2} \mathrm{O}(g)\) (c) \(\mathrm{N}_{2} \mathrm{O}_{4}(g)=2 \mathrm{NO}_{2}(g)\) (d) \(\mathrm{CO}_{2}(g)+\mathrm{H}_{2}(g) \rightleftharpoons \mathrm{CO}(g)+\mathrm{H}_{2} \mathrm{O}(g)\) (e) \(\mathrm{NH}_{4} \mathrm{Cl}(s)=\mathrm{NH}_{3}(g)+\mathrm{HCl}(g)\) (f) \(2 \mathrm{Pb}\left(\mathrm{NO}_{3}\right)_{2}(s) \rightleftharpoons 2 \mathrm{PbO}(s)+4 \mathrm{NO}_{2}(g)+\mathrm{O}_{2}(g)\) (g) \(2 \mathrm{H}_{2}(g)+\mathrm{O}_{2}(g)=2 \mathrm{H}_{2} \mathrm{O}(l)\) (h) \(S_{8}(g) \rightleftharpoons 8 S(g)\)
Sodium sulfate 10-hydrate, \(\mathrm{Na}_{2} \mathrm{SO}_{4} \cdot 10 \mathrm{H}_{2} \mathrm{O},\) dehydrates according to the equation \(\mathrm{Na}_{2} \mathrm{SO}_{4} \cdot 10 \mathrm{H}_{2} \mathrm{O}(s) \rightleftharpoons \mathrm{Na}_{2} \mathrm{SO}_{4}(s)+10 \mathrm{H}_{2} \mathrm{O}(g) \quad K_{P}=4.08 \times 10^{-25} \mathrm{at} 25^{\circ} \mathrm{C}\) What is the pressure of water vapor at equilibrium with a mixture of \(\mathrm{Na}_{2} \mathrm{SO}_{4} \cdot 10 \mathrm{H}_{2} \mathrm{O}\) and \(\mathrm{NaSO}_{4} ?\)
A necessary step in the manufacture of sulfuric acid is the formation of sulfur trioxide, \(S O_{3}\), from sulfur dioxide, \(S O_{2},\) and oxygen, \(O_{2}\), shown here. At high temperatures, the rate of formation of \(S O_{3}\) is higher, but the equilibrium amount (concentration or partial pressure) of \(\mathrm{SO}_{3}\) is lower than it would be at lower temperatures. \(2 \mathrm{SO}_{2}(g)+\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{SO}_{3}(g)\) (a) Does the equilibrium constant for the reaction increase, decrease, or remain about the same as the temperature increases? (b) Is the reaction endothermic or exothermic?
Calculate the equilibrium constant at \(25^{\circ} \mathrm{C}\) for each of the following reactions from the value of \(\Delta G^{\circ}\) given. (a) \(\mathrm{I}_{2}(s)+\mathrm{Cl}_{2}(g) \longrightarrow 2 \mathrm{ICl}(g) \quad \Delta G^{\circ}=-10.88 \mathrm{kJ}\) (b) \(\mathrm{H}_{2}(g)+\mathrm{I}_{2}(s) \longrightarrow 2 \mathrm{HI}(g) \quad \Delta G^{\circ}=3.4 \mathrm{kJ}\) (c) \(\mathrm{CS}_{2}(g)+3 \mathrm{Cl}_{2}(g) \longrightarrow \mathrm{CCl}_{4}(g)+\mathrm{S}_{2} \mathrm{Cl}_{2}(g) \quad \Delta G^{\circ}=-39 \mathrm{kJ}\) (d) \(2 \mathrm{SO}_{2}(g)+\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{SO}_{3}(g) \quad \Delta G^{\circ}=-141.82 \mathrm{kJ}\) (e) \(\mathrm{CS}_{2}(g) \longrightarrow \mathrm{CS}_{2}(l) \quad \Delta G^{\circ}=-1.88 \mathrm{kJ}\)
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