Chapter 14: Problem 27
Explain why the neutralization reaction of a weak acid and a strong base gives a weakly basic solution.
Short Answer
Expert verified
The solution is weakly basic because the weak acid partially dissociates, limiting the increase in pH, while the salt resulting from the neutralization can dissociate and act as a weak base, slightly increasing the solution’s pH.
Step by step solution
01
Understand the definition of weak acids and strong bases
Weak acids only partially dissociate in water, meaning they donate protons (H+) to water to a small extent. On the other hand, strong bases fully dissociate in water and produce a large concentration of hydroxide ions (OH-).
02
Discuss neutralization reactions
A neutralization reaction occurs when an acid reacts with a base to produce a salt and water. In the case of a weak acid and a strong base, the weak acid donates a proton to the hydroxide ions from the strong base to form water.
03
Explain the resulting solution
The resulting salt formed from the weak acid and the strong base can often disassociate in water to form its constituent ions. This salt can behave as a weak base as it may bind to protons from water, increasing the pH and yielding a basic solution.
04
Describe the weakly basic nature of the solution
Since the weak acid does not fully donate its protons, and the strong base generates an excess of hydroxide ions, the end solution has a higher concentration of hydroxide ions than hydronium ions (H3O+), resulting in a basic solution but not strongly basic, as most of the strong base's hydroxide ions are neutralized.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Weak Acids
Imagine sipping a soft drink; you might not realize it's an example of a weak acid in action. Weak acids, like the citric acid in your tasty beverage, don't give up all their protons (H+) when they dissolve in water. They're like reluctant hosts at a party, clinging to some of their guests instead of letting them mingle. Scientists describe this behavior by saying weak acids only partially dissociate in water, leading to an equilibrium where only a small fraction of acid molecules release protons into the solution.
Now, why does this matter? It's all about understanding the subtle play between chemical species in an aqueous environment. To paraphrase a famous detective, 'It's elementary, my dear Watson,' because in chemistry, even weak acids have a significant role to play. Assessing their strength involves something called an acid dissociation constant, or Ka, which tells us just how much they're holding back their protons.
Now, why does this matter? It's all about understanding the subtle play between chemical species in an aqueous environment. To paraphrase a famous detective, 'It's elementary, my dear Watson,' because in chemistry, even weak acids have a significant role to play. Assessing their strength involves something called an acid dissociation constant, or Ka, which tells us just how much they're holding back their protons.
Strong Bases
In stark contrast to weak acids, strong bases are akin to social butterflies that can't wait to let go of all their hydroxide ions (OH−). When a strong base hits water, it's like a cannonball dive into a pool; it totally dissociates, leaving no ion behind. Picture a complete surrender of hydroxide ions ready to react with whatever comes their way.
This total dissociation is what makes strong bases so powerful. They're typically compounds like sodium hydroxide or potassium hydroxide, often found in cleaning products for their ability to break down organic substances. When it comes to chemical reactions, their willingness to fully engage with oppositely charged ions can drive significant changes in the chemical landscape of a solution.
This total dissociation is what makes strong bases so powerful. They're typically compounds like sodium hydroxide or potassium hydroxide, often found in cleaning products for their ability to break down organic substances. When it comes to chemical reactions, their willingness to fully engage with oppositely charged ions can drive significant changes in the chemical landscape of a solution.
Acid-Base Neutralization
The dance of acid and base during a neutralization reaction is a riveting spectacle — the acid donates protons while the base eagerly accepts them, like an expert tango of particles. When a weak acid is paired with a strong base, the result is nothing short of chemical poetry. The weak acid, reluctant as it is, donates a proton to the base's abundant hydroxide ions, crafting water in the process.
The reaction doesn't just end with water, though. There's also the creation of a salt, which seems like it should be neutral, but chemistry loves a plot twist. Depending on the parent weak acid and strong base, this salt has the potential to act as a sneaky weak base itself. How's that for keeping you on your toes? The outcome is a solution that's not just a simple H2O puddle, but a dynamic mix, twinkling with basicity.
The reaction doesn't just end with water, though. There's also the creation of a salt, which seems like it should be neutral, but chemistry loves a plot twist. Depending on the parent weak acid and strong base, this salt has the potential to act as a sneaky weak base itself. How's that for keeping you on your toes? The outcome is a solution that's not just a simple H2O puddle, but a dynamic mix, twinkling with basicity.
pH Levels
The 'p' in pH might as well stand for 'personality,' because it's all about the acidity or basicity character of a solution. It's a scale that runs from 0 to 14, with 7 as the neutral middle ground where pure water hangs out. Dipping below 7 gets you into the acid zone, where protons are throwing a party. Climbing above 7, you're in the base camp, where hydroxide ions are hosting the bash.
Now, when a weak acid and a strong base have their neutralization get-together, it's not going to be a perfect balance - the strong base's personality is just more... outgoing. With more hydroxide ions in the mix, the pH leans towards the basic side, often winding up between 7 and 9. Think of pH as the social media platform of the chemical world — it reflects who's making waves, either the hoppin' protons or the hip hydroxide.
Now, when a weak acid and a strong base have their neutralization get-together, it's not going to be a perfect balance - the strong base's personality is just more... outgoing. With more hydroxide ions in the mix, the pH leans towards the basic side, often winding up between 7 and 9. Think of pH as the social media platform of the chemical world — it reflects who's making waves, either the hoppin' protons or the hip hydroxide.