Chapter 3: Problem 95
Using the periodic table, predict whether the following chlorides are ionic or covalent: KCl, \(\mathrm{NCl}_{3}, \mathrm{ICl}, \mathrm{MgCl}_{2}\) \(\mathrm{PCl}_{5},\) and \(\mathrm{CCl}_{4}\)
Short Answer
Expert verified
KCl and \(\mathrm{MgCl}_{2}\) are ionic. \(\mathrm{NCl}_{3}\), \(\mathrm{ICl}\), \(\mathrm{PCl}_{5}\), and \(\mathrm{CCl}_{4}\) are covalent.
Step by step solution
01
Understanding the difference between ionic and covalent bonds
Ionic bonds typically form between metals and non-metals where there is a transfer of electrons, resulting in positive and negative ions. Covalent bonds form between non-metals, where they share electrons.
02
Classifying KCl
Potassium (K) is a metal from group 1 (alkali metals) and chlorine (Cl) is a non-metal. Metals tend to lose electrons and non-metals tend to gain electrons, resulting in an ionic bond for KCl.
03
Classifying \(\mathrm{NCl}_{3}\)
Nitrogen (N) and chlorine (Cl) are both non-metals. Since non-metals form covalent bonds by sharing electrons, \(\mathrm{NCl}_{3}\) is covalent.
04
Classifying \(\mathrm{ICl}\)
Iodine (I) and chlorine (Cl) are both non-metals. Their bond is characterized by the sharing of electrons, which means \(\mathrm{ICl}\) is covalent.
05
Classifying \(\mathrm{MgCl}_{2}\)
Magnesium (Mg) is a metal and chlorine (Cl) is a non-metal. Metals transfer electrons to non-metals forming ionic bonds, so \(\mathrm{MgCl}_{2}\) is ionic.
06
Classifying \(\mathrm{PCl}_{5}\)
Phosphorus (P) and chlorine (Cl) are both non-metals. They will share electrons, forming a covalent bond, making \(\mathrm{PCl}_{5}\) covalent.
07
Classifying \(\mathrm{CCl}_{4}\)
Carbon (C) and chlorine (Cl) are both non-metals. They share electrons when bonding, indicating that \(\mathrm{CCl}_{4}\) is covalent.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Periodic Table
The periodic table is a comprehensive chart that organizes all known elements by increasing atomic number and groups with similar properties. Elements on the left side are typically metals, such as potassium (K) and magnesium (Mg), which are characterized by their tendency to lose electrons and form positive ions. On the right side, nonmetals like nitrogen (N) and chlorine (Cl) are more likely to gain electrons and form negative ions.
The periodic table provides essential information that enables scientists and students to predict the types of chemical bonds that can form between elements. For instance, by looking at the position of an element in the periodic table, we can anticipate whether it will form ionic or covalent bonds when combined with another element.
The periodic table provides essential information that enables scientists and students to predict the types of chemical bonds that can form between elements. For instance, by looking at the position of an element in the periodic table, we can anticipate whether it will form ionic or covalent bonds when combined with another element.
Electron Transfer
Electron transfer is a key concept in chemistry that occurs when an electron moves from one atom to another, leading to the formation of ions. This process is foundational to ionic bonding, which typically involves a metal donating electrons to a nonmetal.
For example, in the formation of magnesium chloride (\t\(\mathrm{MgCl}_{2}\)), the magnesium atom transfers two electrons to two chlorine atoms. The magnesium becomes a positively charged ion (\t\(\mathrm{Mg}^{2+}\)), while each chlorine atom becomes a negatively charged ion (\t\(\mathrm{Cl}^{-}\)). This transfer of electrons leads to an electrostatic attraction between the ions, resulting in an ionic compound.
For example, in the formation of magnesium chloride (\t\(\mathrm{MgCl}_{2}\)), the magnesium atom transfers two electrons to two chlorine atoms. The magnesium becomes a positively charged ion (\t\(\mathrm{Mg}^{2+}\)), while each chlorine atom becomes a negatively charged ion (\t\(\mathrm{Cl}^{-}\)). This transfer of electrons leads to an electrostatic attraction between the ions, resulting in an ionic compound.
Electron Sharing
Electron sharing is at the heart of covalent bonding, which stands in contrast to ionic bonding. In a covalent bond, two nonmetals share pairs of electrons, which allows them to attain stable electronic configurations.
Take nitrogen trichloride (\t\(\mathrm{NCl}_{3}\)) as an example: nitrogen shares three pairs of electrons with three chlorine atoms to form a stable molecule. This electron sharing results in a bond where the electrons are not fully transferred as in ionic bonds but are shared, creating a strong connection between the atoms.
Take nitrogen trichloride (\t\(\mathrm{NCl}_{3}\)) as an example: nitrogen shares three pairs of electrons with three chlorine atoms to form a stable molecule. This electron sharing results in a bond where the electrons are not fully transferred as in ionic bonds but are shared, creating a strong connection between the atoms.
Chemical Bonding
Chemical bonding is the process by which atoms combine to form molecules and compounds. Bonds form due to the attraction between the atoms' nuclei and electrons, and the nature of this attraction determines the type of bond - ionic or covalent.
Ionic bonds result from the electrostatic forces between ions, as seen in potassium chloride (\t\(KCl\)), where potassium loses an electron to chlorine. Covalent bonds result from electron sharing, as seen in carbon tetrachloride (\t\(CCl_{4}\)), where carbon shares electrons with four chlorine atoms. Understanding the differences between these bonds helps predict the properties of compounds, such as melting points, solubility, and electrical conductivity.
Ionic bonds result from the electrostatic forces between ions, as seen in potassium chloride (\t\(KCl\)), where potassium loses an electron to chlorine. Covalent bonds result from electron sharing, as seen in carbon tetrachloride (\t\(CCl_{4}\)), where carbon shares electrons with four chlorine atoms. Understanding the differences between these bonds helps predict the properties of compounds, such as melting points, solubility, and electrical conductivity.
Metallic and Nonmetallic Elements
Metallic and nonmetallic elements display distinct characteristics that influence the type of bonds they form. Metals, found on the left side of the periodic table, are usually shiny, conductive, and malleable. Metals like potassium (K) readily lose electrons and form ionic bonds with nonmetals.
Nonmetals, located on the right side of the table, are diverse in appearance and are typically poor conductors of heat and electricity. Nonmetals such as phosphorus (P) tend to share electrons and form covalent bonds with other nonmetals, like chlorine (Cl), to create molecular compounds like phosphorus pentachloride (\t\(PCl_{5}\)). The differences in electron interactions between metals and nonmetals are key to predicting and understanding the structure and reactivity of various chemical compounds.
Nonmetals, located on the right side of the table, are diverse in appearance and are typically poor conductors of heat and electricity. Nonmetals such as phosphorus (P) tend to share electrons and form covalent bonds with other nonmetals, like chlorine (Cl), to create molecular compounds like phosphorus pentachloride (\t\(PCl_{5}\)). The differences in electron interactions between metals and nonmetals are key to predicting and understanding the structure and reactivity of various chemical compounds.