Chapter 7: Problem 85
A 0.025-g sample of a compound composed of boron and hydrogen, with a molecular mass of 28 amu, bums spontaneously when exposed to air, producing \(0.063 \mathrm{g}\) of \(\mathrm{B}_{2} \mathrm{O}_{3} .\) What are the empirical and molecular formulas of the compound?
Short Answer
Expert verified
The empirical formula of the compound is BH3, and the molecular formula is also BH3.
Step by step solution
01
Calculate moles of B2O3 produced
Calculate the moles of B2O3 formed using its molar mass (69.62 g/mol) and the mass given (0.063 g). Use the formula moles = mass / molar mass.
02
Determine moles of boron in B2O3
Use the mole ratio from B2O3's molecular formula to find the moles of B present in the product. Since one molecule of B2O3 contains two atoms of B, the moles of B will be twice the moles of B2O3 calculated in Step 1.
03
Calculate moles of hydrogen in the compound
Subtract the mass of Boron (calculated by multiplying the moles of B by its atomic mass) from the total mass of the compound to get the mass of Hydrogen. Calculate the moles of Hydrogen by dividing its mass by its atomic mass (1.008 g/mol).
04
Determine the empirical formula
Divide the moles of each element by the smallest number of moles calculated to get the simplest whole number ratio. This gives the empirical formula.
05
Determine the molecular formula
Use the empirical formula's molar mass and the given molecular mass (28 amu) to find the multiple of the empirical formula's mass that equals the molecular mass. Multiply the subscripts in the empirical formula by this multiple to get the molecular formula.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Stoichiometry
Stoichiometry is a branch of chemistry that focuses on the quantitative relationships between reactants and products in a chemical reaction. It serves as a mathematical approach to predicting how much product will form from a given amount of reactants, or conversely, how much reactants are needed to produce a certain amount of product.
For instance, in the given problem, stoichiometry is used when calculating the moles of boric oxide formed during the combustion process. By understanding that reactions proceed according to their stoichiometry, you can derive the starting amounts of the elements involved in the compound by looking at the results of the reaction.
For instance, in the given problem, stoichiometry is used when calculating the moles of boric oxide formed during the combustion process. By understanding that reactions proceed according to their stoichiometry, you can derive the starting amounts of the elements involved in the compound by looking at the results of the reaction.
Practical Application of Stoichiometry
Using the molar mass of a compound (in this case, boric oxide), we convert the mass of the substance to its corresponding number of moles. This process is crucial because chemical reactions depend on the number of moles, not the mass, which provides a universal way to describe quantities in chemistry.Mole Concept
The mole concept is central to understanding stoichiometry and managing the quantitative aspects of chemistry. One mole is defined as the amount of substance that contains as many entities (atoms, molecules, or other particles) as there are atoms in exactly 12 g of pure carbon-12. This number is known as Avogadro's number, approximately equal to \(6.022 \times 10^{23}\) entities.
In our exercise, the mole concept is employed to relate the mass of boric oxide produced to the amount of boron atoms it contains. By knowing the molar mass of the substance, you can convert between mass and moles, allowing the calculation of moles of hydrogen and boron in the original compound based on the product's composition.
\[ \text{moles} = \frac{\text{mass}}{\text{molar mass}} \]
It allows you to establish the ratio of elements in a compound and find the empirical and molecular formulas, which gives insight into the substance's makeup and proportions.
In our exercise, the mole concept is employed to relate the mass of boric oxide produced to the amount of boron atoms it contains. By knowing the molar mass of the substance, you can convert between mass and moles, allowing the calculation of moles of hydrogen and boron in the original compound based on the product's composition.
Calculating Moles
For instance, to calculate moles of a substance, you use the formula:\[ \text{moles} = \frac{\text{mass}}{\text{molar mass}} \]
It allows you to establish the ratio of elements in a compound and find the empirical and molecular formulas, which gives insight into the substance's makeup and proportions.
Chemical Formulas
Chemical formulas represent the composition of substances using symbols and numerical subscripts. They provide a wealth of information about the elements within a compound and their respective ratios. There are two types of chemical formulas commonly discussed: empirical and molecular formulas.
The empirical formula of a compound provides the simplest whole-number ratio of the elements in that compound. In contrast, the molecular formula gives the actual number of atoms of each element in a molecule of the compound. Often, the molecular formula is a whole-number multiple of the empirical formula.
In our case, the empirical formula is determined by dividing the moles of each element by the smallest number of moles calculated. The molecular formula then considers the actual molecular mass of the compound and uses the empirical formula as a foundation for determining the actual number and proportion of atoms in the molecule.
The empirical formula of a compound provides the simplest whole-number ratio of the elements in that compound. In contrast, the molecular formula gives the actual number of atoms of each element in a molecule of the compound. Often, the molecular formula is a whole-number multiple of the empirical formula.
In our case, the empirical formula is determined by dividing the moles of each element by the smallest number of moles calculated. The molecular formula then considers the actual molecular mass of the compound and uses the empirical formula as a foundation for determining the actual number and proportion of atoms in the molecule.
- Empirical formula: Simplified ratio of elements (e.g., CH for benzene).
- Molecular formula: Actual number of atoms in the molecule (e.g., C6H6 for benzene).