What volume of \(0.08892 M\) HNO \(_{3}\) is required to react completely with 0.2352 g of potassium hydrogen phosphate? \(2 \mathrm{HNO}_{3}(a q)+\mathrm{K}_{2} \mathrm{HPO}_{4}(a q) \rightarrow \mathrm{H}_{2} \mathrm{PO}_{4}(a q)+2 \mathrm{KNO}_{3}(a q)\)

Short Answer

Expert verified
First determine the moles of K2HPO4 (\(\frac{0.2352\, g}{174.18\, g/mol}\)), then use stoichiometry (\(2\) moles HNO3 per mole K2HPO4) to find moles of HNO3 required, and finally use the molarity of HNO3 to find the volume needed.

Step by step solution

01

Write down the balanced chemical equation

It's important to start with the balanced chemical equation for the reaction. The equation provided is already balanced: \[2 \mathrm{HNO}_{3}(aq) + \mathrm{K}_{2}\mathrm{HPO}_{4}(aq) \rightarrow \mathrm{H}_{2}\mathrm{PO}_{4}^{-}(aq) + 2 \mathrm{KNO}_{3}(aq)\].
02

Calculate moles of potassium hydrogen phosphate

To find out how many moles of potassium hydrogen phosphate (K2HPO4) are present, use its molar mass and the mass given in the problem. The molar mass of K2HPO4 is \(174.18 g/mol\). Using the formula \[\text{moles} = \frac{\text{mass}}{\text{molar mass}}\], calculate the moles of K2HPO4: \[\text{moles K2HPO4} = \frac{0.2352\, g}{174.18\, g/mol}\].
03

Use the stoichiometry to find moles of HNO3 needed

According to the balanced chemical equation, 2 moles of HNO3 react with 1 mole of K2HPO4. Set up a proportion to find the number of moles of HNO3 needed.\[\text{moles HNO3 required} = 2 \times \text{moles K2HPO4}\].
04

Calculate the volume of HNO3 solution required

Use the concentration of the HNO3 solution to find the volume required to provide the moles of HNO3 you calculated. Using the formula \[\text{volume} = \frac{\text{moles}}{\text{Molarity}}\], calculate the volume of HNO3: \[\text{volume HNO3 required} = \frac{\text{moles HNO3 required}}{0.08892\, M}\].
05

Combine the calculations to find the final answer

Combine the calculations from Steps 2, 3, and 4 to determine the final volume of HNO3 required. First find the moles of K2HPO4, then use the stoichiometry to find moles of HNO3, and finally divide by the molarity of HNO3 to find the volume.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Chemical Reaction Calculations
At the heart of chemistry lie chemical reaction calculations, which are vital for understanding how substances interact and transform. These calculations allow us to predict the amounts of reactants needed to produce a given quantity of product or to determine the quantity of product formed from certain reactants. For instance, in our exercise, we needed to determine what volume of nitric acid (HNO3) would react with a given mass of potassium hydrogen phosphate (K2HPO4).

To perform these calculations, a balanced chemical equation is essential as it provides the ratio of reactants to products, known as the stoichiometry of the reaction. This knowledge serves as a map, guiding us from the amount of one substance to the expected amount of another.
Molar Mass
Molar mass, the bridge between the microscopic world of atoms and the macroscopic world we can measure, is the weight of one mole of a substance, typically expressed in grams per mole (g/mol). This seemingly simple concept is crucial in moving from the mass of a substance to the amount in moles, which is the key to all stoichiometric calculations.

In our exercise, the molar mass of potassium hydrogen phosphate (K2HPO4) allowed us to convert the given mass (0.2352 g) into moles. It's like knowing the price per pound to calculate how much several apples will cost; molar mass tells us the 'price' per mole.
Molarity
Molarity, marked by the symbol M, reflects the concentration of a solution, providing the number of moles of solute per liter of solution. It's an invaluable figure when preparing or working with chemical solutions because it helps us understand the strength of the solution in terms of the amount of substance it contains.

In our example, we worked with a 0.08892 M solution of HNO3. Knowing the molarity enabled us to find the volume of this solution needed to obtain the moles of HNO3 necessary for the reaction. Molarity is akin to a recipe, telling us how much of each ingredient we need to mix to get the desired taste (or in this case, reaction).
Balanced Chemical Equations
Balanced chemical equations are the bedrock of stoichiometry. An equation is balanced when the number of atoms of each element is the same on both sides of the reaction. This balance reflects the conservation of mass principle: atoms are neither created nor destroyed in a chemical reaction. They're simply rearranged.

A balanced chemical equation is like a well-structured musical score, where each note (atom) has its place, ensuring harmony (balance). It tells us how many parts of each reactant interact and how many parts of each product form. For our exercise, the balanced equation dictated the exact ratio of reactants to products, which is essential to calculate how much HNO3 was required for the given amount of K2HPO4.

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Most popular questions from this chapter

Complete and balance the following acid-base equations: (a) A solution of \(\mathrm{HClO}_{4}\) is added to a solution of LiOH. (b) Aqueous \(\mathrm{H}_{2} \mathrm{SO}_{4}\) reacts with \(\mathrm{NaOH}\) (c) \(\mathrm{Ba}(\mathrm{OH})_{2}\) reacts with HF gas.

Write the balanced equation, then outline the steps necessary to determine the information requested in each of the following: (a) The number of moles and the mass of Mg required to react with \(5.00 \mathrm{g}\) of \(\mathrm{HCl}\) and produce \(\mathrm{MgCl}_{2}\) and \(\mathrm{H}_{2}\). (b) The number of moles and the mass of oxygen formed by the decomposition of \(1.252 \mathrm{g}\) of silver(I) oxide. (c) The number of moles and the mass of magnesium carbonate, \(\mathrm{MgCO}_{3}\), required to produce \(283 \mathrm{g}\) of carbon dioxide. (MgO is the other product.) (d) The number of moles and the mass of water formed by the combustion of \(20.0 \mathrm{kg}\) of acetylene, \(\mathrm{C}_{2} \mathrm{H}_{2}\), in an excess of oxygen. (e) The number of moles and the mass of barium peroxide, \(\mathrm{BaO}_{2}\), needed to produce \(2.500 \mathrm{kg}\) of barium oxide, \(\mathrm{BaO}\) \(\left(\mathrm{O}_{2}\right.\) is the other product.)

Silver can be separated from gold because silver dissolves in nitric acid while gold does not. Is the dissolution of silver in nitric acid an acid-base reaction or an oxidation-reduction reaction? Explain your answer.

Calcium cyclamate \(\mathrm{Ca}\left(\mathrm{C}_{6} \mathrm{H}_{11} \mathrm{NHSO}_{3}\right)_{2}\) is an artificial sweetener used in many countries around the world but is banned in the United States. It can be purified industrially by converting it to the barium salt through reaction of the acid \(\mathrm{C}_{6} \mathrm{H}_{11} \mathrm{NHSO}_{3} \mathrm{H}\) with barium carbonate, treatment with sulfuric acid (barium sulfate is very insoluble), and then neutralization with calcium hydroxide. Write the balanced equations for these reactions.

The reaction of \(\mathrm{WCl}_{6}\) with \(\mathrm{Al}\) at \(\sim 400^{\circ} \mathrm{C}\) gives black crystals of a compound containing only tungsten and chlorine. A sample of this compound, when reduced with hydrogen, gives 0.2232 g of tungsten metal and hydrogen chloride, which is absorbed in water. Titration of the hydrochloric acid thus produced requires \(46.2 \mathrm{mL}\) of \(0.1051 \mathrm{M}\) NaOH to reach the end point. What is the empirical formula of the black tungsten chloride?

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