Chapter 9: Problem 3
Explain the difference between heat capacity and specific heat of a substance.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chapter 9: Problem 3
Explain the difference between heat capacity and specific heat of a substance.
These are the key concepts you need to understand to accurately answer the question.
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Get started for freeDuring a recent winter month in Sheboygan, Wisconsin, it was necessary to obtain 3500 kWh of heat provided by a natural gas furnace with \(89 \%\) efficiency to keep a small house warm (the efficiency of a gas furnace is the percent of the heat produced by combustion that is transferred into the house). (a) Assume that natural gas is pure methane and determine the volume of natural gas in cubic feet that was required to heat the house. The average temperature of the natural gas was \(56^{\circ} \mathrm{F} ;\) at this temperature and a pressure of \(1 \mathrm{atm}\) natural gas has a density of 0.681 g/L. (b) How many gallons of LPG (liquefied petroleum gas) would be required to replace the natural gas used? Assume the LPG is liquid propane \(\left[\mathrm{C}_{3} \mathrm{H}_{8}:\right.\) density, \(0.5318 \mathrm{g} / \mathrm{mL}\); enthalpy of combustion, \(2219 \mathrm{kJ} / \mathrm{mol}\) for the formation of \(\left.\mathrm{CO}_{2}(g) \text { and } \mathrm{H}_{2} \mathrm{O}(l)\right]\) and the furnace used to burn the LPG has the same efficiency as the gas furnace. (c) What mass of carbon dioxide is produced by combustion of the methane used to heat the house? (d) What mass of water is produced by combustion of the methane used to heat the house? (e) What volume of air is required to provide the oxygen for the combustion of the methane used to heat the house? Air contains \(23 \%\) oxygen by mass. The average density of air during the month was \(1.22 \mathrm{g} / \mathrm{L}\). (f) How many kilowatt-hours \(\left(1 \mathrm{kWh}=3.6 \times 10^{6} \mathrm{J}\right)\) of electricity would be required to provide the heat necessary to heat the house? Note electricity is \(100 \%\) efficient in producing heat inside a house. (g) Although electricity is 100\% efficient in producing heat inside a house, production and distribution of electricity is not \(100 \%\) efficient. The efficiency of production and distribution of electricity produced in a coal- fired power plant is about 40\%. A certain type of coal provides 2.26 kWh per pound upon combustion. What mass of this coal in kilograms will be required to produce the electrical energy necessary to heat the house if the efficiency of generation and distribution is 40\%?
Which of the following compounds requires the most energy to convert one mole of the solid into separate ions? (a) \(\mathrm{K}_{2} \mathrm{S}\) (b) \(\mathrm{K}_{2} \mathrm{O}\) (c) CaS (d) \(\mathrm{Cs}_{2} \mathrm{S}\) (e) CaO
The addition of 3.15 g of \(\mathrm{Ba}(\mathrm{OH})_{2} \cdot 8 \mathrm{H}_{2} \mathrm{O}\) to a solution of \(1.52 \mathrm{g}\) of \(\mathrm{NH}_{4} \mathrm{SCN}\) in \(100 \mathrm{g}\) of water in a calorimeter caused the temperature to fall by \(3.1^{\circ} \mathrm{C} .\) Assuming the specific heat of the solution and products is \(4.20 \mathrm{J} / \mathrm{g}^{\circ} \mathrm{C}\) calculate the approximate amount of heat absorbed by the reaction, which can be represented by the following equation: $$\mathrm{Ba}(\mathrm{OH})_{2} \cdot 8 \mathrm{H}_{2} \mathrm{O}(s)+2 \mathrm{NH}_{4} \mathrm{SCN}(a q) \longrightarrow \mathrm{Ba}(\mathrm{SCN})_{2}(a q)+2 \mathrm{NH}_{3}(a q)+10 \mathrm{H}_{2} \mathrm{O}(I)$$
Which compound in each of the following pairs has the larger lattice energy? Note: \(\mathrm{Mg}^{2+}\) and \(\mathrm{Li}^{+}\) have similar radii; O \(^{2-}\) and \(\mathrm{F}^{-}\) have similar radii. Explain your choices. (a) MgO or MgSe (b) LiF or MgO (c) \(\mathrm{Li}_{2} \mathrm{O}\) or \(\mathrm{LiCl}\) (d) Li_se or MgO
Does the standard enthalpy of formation of \(\mathrm{H}_{2} \mathrm{O}(g)\) differ from \(\Delta H^{\circ}\) for the reaction \(2 \mathrm{H}_{2}(g)+\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{H}_{2} \mathrm{O}(g) ?\)
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