Hydrogen fluoride, HF, can be made from the reaction

H2(g)+F2(g)2HF(g)

In one experiment, 0.10 mol of role="math" localid="1654926984654" H2(g)and 0.050 mol of F2(g)are added to a 0.50-L f

lask. Write a reaction table for this process.

Short Answer

Expert verified

The ICE table for the reaction is obtained as follows:

Step by step solution

01

Step 1: what is reaction table

Thereaction table is a spreadsheet format that contains all numerical and algebraic data relevant to the problem and allows for the development of a consistent set of analytical and computational procedures inside a single calculational framework. We can use the approach to detect common ideas, evaluate issues, arrange computations, make logical conclusions, identify distracters, validate results, and move forward with confidence and precision to a solution.

02

Construction of reaction table

Rewrite the reaction as follows:

H2(g)+F2(g)2HF(g)

The number of moles of H2is 0.10 mol and the number of moles of F2is 0.050 mol. The volume of the flask is 0.50L.

H2=0.010mol50L=0.20MF2=0.050mol0.50L=0.10M

Assume x (M) of and x (M) of dissociates and construct ICE table as follows.

Thus, the ICE table for the reaction is obtained.

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Most popular questions from this chapter

Le Châtelier's principle is related ultimately to the rates of the forward and reverse steps in a reaction. Explain (a) why an increase in reactant concentration shifts the equilibrium position to the right but does not change K; (b) why a decrease in V shifts the equilibrium position toward fewer moles of gas but does not change K; (c) why a rise in T shifts the equilibrium position of an exothermic reaction toward reactants and also changes K; and (d) why a rise in temperature of an endothermic reaction from T1to T2results in K2 being larger thanK1 .

Consider the following reaction:

3Fe(s)+4H2O(g)Fe3O4(s)+4H2(g)

(a) What is the apparent oxidation state ofFe in Fe3O4 ?

(b) Actually, Fe has two oxidation states in Fe3O4. What are they?

(c) At 900°C,Kcfor the reaction is 5.1. If 0.050molofH2O(g) and 0.100mol ofFe(s) are placed in a1.0L container at900°C , how many grams of Fe3O4 are present at equilibrium?

Note: The synthesis of ammonia is a major process throughout the industrialized world. Problems 17.99 to 17.105 refer to various aspects of this all-important reaction:

N2(g)+3H2(g)2NH3(g)   ΔHrxn°=91.8kJ

Predict the effect of decreasing the temperature on the amounts of reactants in the following reactions:

(a) C2H2(g)+H2O(g)CH3CHO(g)ΔHrxn0=-151kj

(b) CH3CH2OH(I)+O2(g)CH3CO2H(I)+HO2(g)ΔHrxn0=-451kj

(c) 2c2H4(g)+O2(g)2CH3CHO(g)(exothermic) (d)N2O42NO2(g)(endothermic)

An inorganic chemist places 1 mol of BrCl in container A and 0.5 mol of Br2 and 0.5 mol of Cl2 in container B. She seals the containers and heats them to 3000C. With time, both containers hold identical mixtures of BrCl, Br2, and Cl2.

(a) Write a balanced equation for the reaction in container A.

(b) Write the reaction quotient, Q, for this reaction.

(c) How do the values of Qin A and in B compare over time?

(d) Explain on the molecular level how it is possible for both containers to end up with identical mixtures.

You are a member of a research team of chemists discussing the plans to operate an ammonia processing plant: N2(g)+3H2(g)2NH3(g)

(a) The plant operates at close to 700 K, at which Kpis role="math" localid="1654929481926" 1.00×10-4, and employs the stoichiometric 1/3 ratio of N2/H2. At equilibrium, the partial pressure of NH3is 50atm. Calculate the partial pressures of each reactant and Ptotal.

(b) One member of the team suggests the following: since the partial pressure of H2is cubed in the reaction quotient, the plant could produce the same amount of NH3if the reactants were in a 1/6 ratio of N2/H2and could do so at a lower pressure, which would cut operating costs. Calculate the partial pressure of each reactant and Ptotalunder these conditions, assuming an unchanged partial pressure of 50. atm for NH3. Is the suggestion valid?

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