Gaseous ammonia was introduced into a sealed container and heated to a certain temperature:

2NH3(g)֏N2(g)+3H2(g)

At equilibrium, [NH3]=0.0225M,[N2]=0.114M,and[H2]=0.342M. Calculate Kc for the reaction at this temperature.

Short Answer

Expert verified

The value of the equilibrium constant (Kc)for the reaction at a certain temperature is 9.01.

Step by step solution

01

Step 1:Write the equilibrium constant

The equilibrium constantKc is the constant that depends on the concentrations of reactants and products.

For a general chemical reaction,

aA+bB֏cC+dD

The equilibrium constant Kcis given as,

Kc=CcDdAaBb

Here, a, b, c, and dare the stoichiometric coefficients.

02

Step2:Calculate Kc

Consider the following reaction;

2NH3g֏N2g+3H2g

The equilibrium constant Kcfor this reaction is given as,

Kc=N2H23NH32

From the given data,

NH3=0.0225MN2=0.114MH2=0.342M

Substitute the concentration of N2,H2,andNH3to calculate the equilibrium constant Kcas follows:

role="math" localid="1654923012345" Kc=N2H23NH32=0.1140.34230.02252=0.004560.000506=9.01

Thus, the value of the equilibrium constant Kcfor the reaction at a certain temperature is 9.01.

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Most popular questions from this chapter

When ammonia is made industrially, the mixture of N2, H2 andNH3 that emerges from the reaction chamber is far from equilibrium. Why does the plant supervisor use reaction conditions that produce less than the maximum yield of ammonia?

You are a member of a research team of chemists discussing the plans to operate an ammonia processing plant: N2(g)+3H2(g)2NH3(g)

(a) The plant operates at close to 700 K, at which Kpis role="math" localid="1654929481926" 1.00×10-4, and employs the stoichiometric 1/3 ratio of N2/H2. At equilibrium, the partial pressure of NH3is 50atm. Calculate the partial pressures of each reactant and Ptotal.

(b) One member of the team suggests the following: since the partial pressure of H2is cubed in the reaction quotient, the plant could produce the same amount of NH3if the reactants were in a 1/6 ratio of N2/H2and could do so at a lower pressure, which would cut operating costs. Calculate the partial pressure of each reactant and Ptotalunder these conditions, assuming an unchanged partial pressure of 50. atm for NH3. Is the suggestion valid?

Using CH4and steam as a source ofH2forNH3synthesis requires high temperatures. Rather than burningCH4separately to heat the mixture, it is more efficient to inject someO2into the reaction mixture. All of theH2is thus released for the synthesis, and the heat of reaction for the combustion ofCH4helps maintain the required temperature. Imagine the reaction occurring in two steps:

2CH4(g)+O2(g)2CO(g)+4H2(g)Kp=9.34×1028at1000KCO(g)+H2O(g)CO2(g)+H2(g)Kp=1.374at1000K

(a) Write the overall equation for the reaction of methane, steam, and oxygen to form carbon dioxide and hydrogen.

(b) What isKpfor the overall reaction?

(c) What isKcfor the overall reaction?

(d) A mixture of2.0molof CH4,1.0molof,O2 and2.0molof steam with a total pressure of 30atm reacts at 1000K at constant volume. Assuming that the reaction is complete and the ideal gas law is a valid approximation, what is the final pressure?

Consider the formation of ammonia in two experiments.

  1. To a 1.00-L container at727oC1.30mol of N2and 1.65molofH2are added. At equilibrium, 0.100molofNH3 is present. Calculate the equilibrium concentrations of N2andH2, and find Kcfor the reaction: 2NH3(g)N2(g)+3H2(g)
  2. In a different 1.00-L container at the same temperature, equilibrium is established with 8.34×10-2molofNH3,1.50molofN2,and1.25molofH2 present. CalculateKc for the reaction:NH3(g)N2(g)+32H2(g)
  3. (c) What is the relationship between the Kc values in parts (a) and (b) ? Why aren't these values the same?

Sodium bicarbonate undergoes thermal decomposition according to the reaction

2NaHCO3(s)Na2CO3(s)+CO2(g)+H2O(g)

How does the equilibrium position shift as a result of each of the following disturbances? (a) 0.20atmof argon gas is added.

(b) NaHCO3(s)is added.

(c) Mg(CIO4)2(s)is added as a drying agent to removeH2O.

(d) Dry ice is added at constant T.

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