What is the difference between the equilibrium position and the equilibrium constant of a reaction? Which changes as a result of a change in reactant concentration?

Short Answer

Expert verified

The equilibrium position describes reaction equilibrium qualitatively while the equilibrium constant describes equilibrium quantitatively.

The equilibrium position changes with change in reactant concentration.

Step by step solution

01

Chemical reactions

The process of converting a substance (reactant) into another substance (product) with different chemical identities is called a chemical reaction.

A chemical reaction can be reversible or irreversible.

If the reaction involves the formation of a lower energy product from a high energy reactant, the excess energy is released in the form of heat. These reactions are called exothermic. If the reaction involves heat absorption by reactants, it is considered endothermic.

02

Dynamic equilibrium

In a reversible reaction, the forward and backward reactions occur simultaneously. The rate of each reaction initially depends on the reactant concentration and conditions. After a certain time, the forward reaction rate becomes equal to that of the backward reaction. This is called a dynamic equilibrium state.

Therefore, the amount of products formed in an equilibrium state will be equal to that broken down into reactants. Once a reaction attains an equilibrium state, there will be no further change in the concentration of reactants or products, and this is called equilibrium concentrations.

03

Equilibrium position and equilibrium constant

The dynamic equilibrium of a reversible chemical reaction can be described qualitatively using the equilibrium position. It defines the moment at which the forward and backward reaction rate becomes equal.

The ratio of the equilibrium concentration of products to that of the reactants is called the equilibrium constant. Therefore, it describes the reaction equilibrium quantitatively. The equilibrium constant is a constant value for a reaction at a particular temperature.

The equilibrium constant K can be calculated as:

K=ProuductsReactantatequilibrium

The equilibrium position is a set of reactant and product concentrations that describe equilibrium. Therefore, when the reactant concentration is changed, the concentrations at which the reactants reach equilibrium change. Therefore, the equilibrium position changes with reactant concentration.

The equilibrium constant is the ratio of concentrations. When the initial reactant concentration changes, the reactant concentrations at equilibrium change, causing a subsequent change in product concentration. Therefore, the ratio of concentrations and equilibrium constant do not change.

Therefore, the equilibrium position changes with a change in reactant concentration.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free