The dynamic equilibrium of a reversible chemical reaction can be described qualitatively using the equilibrium position. It defines the moment at which the forward and backward reaction rate becomes equal.
The ratio of the equilibrium concentration of products to that of the reactants is called the equilibrium constant. Therefore, it describes the reaction equilibrium quantitatively. The equilibrium constant is a constant value for a reaction at a particular temperature.
The equilibrium constant K can be calculated as:
The equilibrium position is a set of reactant and product concentrations that describe equilibrium. Therefore, when the reactant concentration is changed, the concentrations at which the reactants reach equilibrium change. Therefore, the equilibrium position changes with reactant concentration.
The equilibrium constant is the ratio of concentrations. When the initial reactant concentration changes, the reactant concentrations at equilibrium change, causing a subsequent change in product concentration. Therefore, the ratio of concentrations and equilibrium constant do not change.
Therefore, the equilibrium position changes with a change in reactant concentration.