What species are in the buffer region of a weak acid–strong base titration? How are they different from the species at the equivalence point? How are they different from the species in the buffer region of a weak base–strong acid titration?

Short Answer

Expert verified

The conjugate base of a weak acid HA isA-. The weak acid and the strong base are used in equal proportions. The conjugate acid of a weak base and the weak base are BH+/B.

Step by step solution

01

Define equivalence point

In a titration, the equivalence point is reached when the amount of titrant administered is sufficient to totally neutralise the analyte solution.

02

Explanation

The weak acid and its conjugate base HA/A-reside in the buffer zone of a weak acid-strong base titration. When a weak acid combines with a strong base, such as NaOH, this is what happens.

HA + NaOHNa++H2O +A-

The term "equivalent point" refers to the presence of an equal amount of weak acid and strong base. As a result, all HAreacts with NaOH. As a result, only Na+and A-will exist.

The weak base and its conjugate acid BH+/Bexist in the buffer area of a weak base-strong acid titration. When a weak base reacts with a strong acid, such as HCl, this is what happens.

B + HClBH++ Cl-

Therefore, the conjugate base of a weak acid HA/A-and the conjugate acid of a weak base BH+/B.

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Most popular questions from this chapter

Write the ion-product expressions forsilver carbonate;

barium fluoride; copper (II)sulphide.

Scenes A to D represent tiny portions of 0.10M aqueous solutions of a weak acid HA (red and blue; Ka=4.5×10-5), its conjugate base A-(red), or a mixture of the two (only these species are shown):

(a) Which scene(s) show(s) a buffer?

(b) What is thepHof each solution?

(c) Arrange the scenes in sequence, assuming that they represent stages in a weak acid-strong base titration.

(d) Which scene represents the titration at its equivalence point?

Which compound in each pair is more soluble in water?

(a) Strontium sulphate or barium chromate

(b) Calcium carbonate or copper(II)carbonate

(c) Barium iodate or silver chromate

Find the solubility of Cr(OH)3in a buffer of pH 13.0 [ Kspof Cr(OH)3=6.3×10-31;Kfof Cr(OH)4-=8.0×1029].

Quantitative analysis of Cl-ion is often performed by a titration with silver nitrate, using sodium chromate as an indicator. As standardized AgNO3is added, both white AgCl and red role="math" localid="1663261461482" Ag2CrO4 precipitate, but so long as someCl-remains, the Ag2CrO4redissolves as the mixture is stirred. When the red color is permanent, the equivalence point has been reached.

(a) Calculate the equilibrium constant for the reaction

data-custom-editor="chemistry" 2AgCl(s)+CrO42-(aq)Ag2CrO4(s)+2Cl-(aq)

(b) Explain why the silver chromate redissolves.

(c) If 25.00cm3 of 0.1000MNaClis mixed with 25.00cm3of 0.1000MAgNO3, what is the concentration of Ag+remaining in solution? Is this sufficient to precipitate any silver chromate?

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