Write the ion-product expressions for

(a)lead(II)iodide;(b)strontium sulfate;(c)cadmium sulfide.

Short Answer

Expert verified

The ion-product expression of the compounds is,

aLead(II) iodide: Ksp =Pb2 +I-2bStrontium sulfate: Ksp =Sr2 +SO42 -.cCadmium sulfide: Ksp =Cd2 +S2 -

Step by step solution

01

Concept Introduction

The Qsp-ion-product expression is obtained by multiplying the concentrations of ions generated by dissolution of a chemical. When a solution is saturated, the Qsp value is referred to as the Ksp value (solubility-product constant).

MX2>>M2++2X-

We do not include the solid and liquid states in the equations

Ksp =[M2 +][X-]2

02

Obtaining ion-product expression for LeadIodide

Let us obtain the ion-product expression forlead (II) iodide.

The formula for lead (II) iodide is PbI2.

PbI2(s)Pb2+(aq)+2I-(aq)

We squared I-because we have 2 mols of in the equation.

Therefore, the ion-product expression for leadlocalid="1663304374574" (II)iodide is Ksp =Pb2 +I-2.

03

Obtaining ion-product expression for Strontium Sulfate

Let us obtain the ion-product expression for strontium sulphate.

The formula for silver cyanide is SrSO4.

localid="1663305249992" SrSO4(s)Sr2+(aq)+SO42-(aq)

Ksp =Sr2 +SO42 -

Therefore, the ion-product expression for strontium sulphate islocalid="1663304658017" [Sr2 +][SO42 -].

04

Obtaining ion-product expression for Cadmium Sulfide

Let us obtain the ion-product expression for cadmium sulfide.

The formula for cadmium sulfide is CdS.

localid="1663305263200" CdS(s)Cd2+(aq)+S2-(aq)Ksp=Cd2+S2-

Therefore, the ion-product expression for cadmium sulfide is [Cd2+][S2-].

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Most popular questions from this chapter

Amino acids [general formula NH2CH(R)COOH]can be considered polypro tic acids. In many cases, the R group contains additional amine and carboxyl groups.

(a) Can an amino acid dissolved in pure water have a protonated localid="1663345833873" COOH group and an unprotonated localid="1663345865389" NH2group

localid="1663345870225" (KXofCOOHgroup=4.47×10-3;KbofNH2group=6.03×10-3y?

Use glycine, localid="1663345879880" NH3CH3COOH, to explain why.

(b) Calculate localid="1663345908281" [+NH3CH2COO-y+NH3CH2COOH]atpH5.5.

(c) The R group of lysine is localid="1663345894686" -CH2CH2CH2CH2NH2(pKb=3.47)Draw the structure of lysine at .localid="1663345916050" pHphysiological localid="1663345902202" pH(-7),andpH13.

(d) Thelocalid="1663345947279" Rgroup of glutamic acid localid="1663345920800" -CH2CH2COOH(pKa=4.07).of the forms of glutamic acid that are shown below, which predominates at,localid="1663345941655" (1)localid="1663345993071" pH1(2) localid="1663345925494" physaiologicalpHH(-7),

and (3) localid="1663345936358" pH13?

Calculate the pHduring the titration of 40.00mLofHClwithsolution after the following additions of base:

(a) 0mL.

(b) 25.00mL.

(c)39.00mL.

(d)39.90mL.

(e)40.00mL.

(f)40.10mL.

(g)50.00mL.

Find the pH of a buffer that consists of 1.3M sodium phenolate (C6H5ONa) and 1.2M phenol (C6H5OH) (pKaof phenol=10.00)?

What is the component concentration ratio, [BrO-]/[HBrO],of a buffer that has a pH of7.95(KaofHBrO=2.3×10-9)?

EDTA binds metal ions to form complex ions (see Problem), so it is used to determine the concentrations of metal ions in solution:

Mn +(aq) + EDTA4 -(aq)MEDTAn - 4(aq)

A 50.0 - mLsample of 0.048 M Co2 +is titrated with 0.050 M EDTA4 -.Find [Co2 +]and [EDTA4 -]after.

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