(a) What is the difference between an average rate and an instantaneous rate? (b) What is the difference between an initial rate and an instantaneous rate?

Short Answer

Expert verified

The answer is,

(a) The average rate can be defined as the rate of a reaction in a particular interval of time and instantaneous rate can be defined as the rate of a reaction at a particular instant of time.

(b) The initial rate is the rate at the initial stage of the reaction and instantaneous rate can be defined as the rate of a reaction at a particular instant of time.

Step by step solution

01

Rate of a reaction

The rate of a reaction is the speed at which the reactants undergo transformation to the products at a constant temperature. The rate of a reaction is depended on many factors like temperature, pressure, surface area, catalysts, etc.

02

Subpart (a)

The average rate can be defined as the rate of a reaction in a particular interval of time and instantaneous rate can be defined as the rate of a reaction at a particular instant of time. These two concepts are different with the difference in the time considered.

03

Subpart (b)

The initial rate is the rate at the initial stage of the reaction and instantaneous rate can be defined as the rate of a reaction at a particular instant of time. Both are different in the sense that instantaneous rate can be taken at the initial stage of the reaction also.

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Most popular questions from this chapter

Consider the following organic reaction, in which one halogen replaces another in an alkyl halide:

CH3CH2Br+KlCH3CH2l+KBr

In acetone, this particular reaction goes to completion because KI is soluble in acetone but KBr is not. In the mechanism, I approach the carbon opposite to the Br (see Figure 16.19, withl-

instead of OH- ). After Br- has been replaced by l-and precipitates as KBr, other I ions react with the ethyl iodide by the same mechanism.

(a) If we designate the carbon bonded to the halogen as C-1, what are the shapes around C-1 and the hybridization of C-1 in ethyl iodide?

(b) In the transition state, one of the two lobes of the unhybridized 2p orbital of C-1 overlaps a p orbital of I, while the other lobe overlaps a p orbital of Br. What are the shape around C-1 and the hybridization of C-1 in the transition state?

(c) The deuterated reactant, CH3CHDBr(where D is deuterium, 2 H), has two optical isomers because C-1 is chiral. If the reaction is run with one of the isomers, the ethyl iodide is not optically active. Explain

Give the individual reaction orders for all substances and the overall reaction order from the following rate law:

Rate=k[BrO3-][Br-][H+]2

For the reaction , [C] vs. time is plotted:

How do you determine each of the following?

(a) The average rate over the entire experiment

(b) The reaction rate at time x

(c) The initial reaction rate

(d) Would the values in parts (a), (b) and (c) be different if you plotted [D] vs. time? Explain.

Iodide ion reacts with chloromethane to displace chloride ion in a common organic substitution reaction:

I-+CH3CICH3I+CI-

(a) Draw a wedge-bond structure of chloroform and indicate the most effective direction of I-attack.

(b) The analogous reaction with 2-chlorobutane [Figure P16.107(b)] results in a major change in specific rotation as measured by polarimetry. Explain, showing a wedge-bond structure of the product.

(c) Under different conditions, 2-chlorobutane loses CI-in a rate-determining step to form a planar intermediate [Figure P16.107(c)]. This cationic species reacts with HI and then loses H to form a product that exhibits no optical activity. Explain, showing a wedge-bond structure.

Give two reasons to measure initialrates in a kinetic study.

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