Explain in detail why a catalyst is used to produce SO3.

Short Answer

Expert verified

The major reason a catalyst is used to produce SO3 is to enhance the yield of SO3.

Step by step solution

01

Concept Introduction

The chemical molecule SO3 stands for sulphur trioxide. Sulfur oxide has been called "unquestionably the most important economically." As a precursor of sulfuric acid, it is manufactured on a large scale. Gaseous monomer, crystalline trimer, and solid polymer are all examples of sulphur trioxide.

02

Explanation

At normal temperature, the oxidation ofSO2to SO3is a slow and exothermic reaction.

SO2(g)+12O2(g)SO3(g)ΔHo=-99kJ

We can improve the yield by altering the temperature, raising the pressure (since there are more moles of gas on the left than on the right), and manipulating the concentrations (adding more O2, eliminating SO3).

Increasing the temperature would increase the frequency of SO2-O2collisions, and thus the rate of creation of SO3. However, because the reaction enthalpy is exothermic, lowering the temperature of the mixture would cause the equilibrium to shift to the right, increasing the yield of SO3.

As a result, a catalyst is required in this case - a material that aids in the establishment of equilibrium by lowering the activation energy. The equilibrium is attained faster and at a lower temperature when V2O5or inert silica is used as a catalyst.

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