The allene molecule has the following Lewis structure:

Must all four hydrogen atoms lie in the same plane? If not, what is the spatial relationship among them? Why?

Short Answer

Expert verified

The four hydrogens do not lie in the same plane. They are perpendicular to each other.

Step by step solution

01

Bonding between the central atom and the terminal atom

We know that the π bond is formed due to sidewise overlapping of the p orbital. Thus for the formation of π bond the p orbitals need to be in the same plane. The central carbon in the allene molecule is sp hybridized. This means that it has two p orbitals for forming π bond. But the p orbitals will be perpendicular to each other. As a result when the terminal carbons will form π bond with the p orbitals of the central carbon, the bonds formed will be perpendicular to each other.

02

:Spatial arrangement of the four hydrogens

Theπ bonds formed will be perpendicular to each other. The sp hybrid orbitals will be perpendicular to the p orbitals. The terminal carbons are sp2 hybridised and will have trigonal planar geometry. Therefore the two hydrogen on the left will be perpendicular to the two hydrogen on the left.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Use the oxidation number method to balance the following equations by placing coefficients in the blanks. Identify the reducing and oxidizing agents:

(a)_KOH(aq)+_H2O2(aq)+_Cr(OH)3(s)_K2CrO4(aq)+_H2O(l)(b)_MnO4(aq)+_ClO2(aq)+_H2O(l)_MnO2(s)+_ClO4(aq)+OH(aq)(c)_KMnO4(aq)+_Na2SO3(aq)+_H2O(l)_MnO2(s)+_Na2SO4(aq)+_KOH(aq)(d)_CrO42(aq)+_HSnO2(aq)+_H2O(l)_CrO2(aq)+_HSnO3(aq)+OH(aq)(e)_KMnO4(aq)+_NaNO2(aq)+_H2O(l)_MnO2(s)+_NaNO3(aq)+_KOH(aq)(f)_I(aq)+_O2(g)+_H2O(l)_I2(s)+_OH(aq)

Ammonia is produced by the millions of tons annually for use as a fertilizer. It is commonly made from N2 and H2 by the Haber process. Because the reaction reaches equilibrium before going completely to product, the stoichiometric amount of ammonia is not obtained. At a particular temperature and pressure, 10.0 g of H2 reacts with 20.0 g of N2 to form ammonia. When equilibrium is reached, 15.0 g of NH3 has formed.

(a) Calculate the percent yield.

(b) How many moles of N2 and H2 are present at equilibrium?

Sodium peroxide (Na2O2) is often used in self-contained breathing devices, such as those used in fire emergencies, because it reacts with exhaled CO2 to form Na2CO3 and O2. How many liters of respired air can react with 80.0 g of Na2O2 if each liter of respired air contains 0.0720 g of CO2?

The net ionic equation for the aqueous neutralization reaction between acetic acid and sodium hydroxide is different from that for the reaction between hydrochloric acid and sodium hydroxide. Explain by writing balanced net ionic equations.

In which of the following equations does sulfuric acid act as an oxidizing agent? In which does it act as an acid? Explain.

(a)4H+(aq)+SO42-(aq)+2NaI(s)2Na+(aq)+I2(s)+SO2(g)+2H2O(l)(b)BaF2(s)+2H+(aq)+SO42-(aq)2HF(aq)+BaSO4(s)

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free