For each of the following molecules, indicate the hybridization requested and whether or not the electrons will be delocalized: (a) ozone (\({{\rm{O}}_{\rm{3}}}\)) central \({\rm{O}}\) hybridization (b) carbon dioxide (\({\rm{C}}{{\rm{O}}_{\rm{2}}}\)) central \({\rm{C}}\) hybridization (c) nitrogen dioxide (\({\rm{N}}{{\rm{O}}_{\rm{2}}}\)) central \({\rm{N}}\) hybridization (d) phosphate ion (\({\rm{P}}{{\rm{O}}_{\rm{4}}}^{{\rm{3 - }}}\)) central \({\rm{P}}\) hybridization.

Short Answer

Expert verified

(a)\({\rm{s}}{{\rm{p}}^{\rm{2}}}\)with electrons delocalized.

(b)\({\rm{sp}}\)with electrons not delocalized.

(c)\({\rm{s}}{{\rm{p}}^{\rm{2}}}\)with electrons delocalized.

(d) \({\rm{s}}{{\rm{p}}^{\rm{3}}}\) with electrons delocalized.

Step by step solution

01

Define molecule

A molecule is the smallest unit of a substance that holds the compound's chemical characteristics. Molecules are made up of atoms arranged in groups.

02

Subpart (a)

Ozone (\({{\rm{O}}_{\rm{3}}}\)): In a trigonal planar structure, the oxygen atom is surrounded by three zones of electron density. In a trigonal planar electron pair geometry, the hybridization is \({\rm{s}}{{\rm{p}}^{\rm{2}}}\), and the electrons are delocalized.

03

Subpart (b)

Carbon dioxide (\({\rm{C}}{{\rm{O}}_{\rm{2}}}\)): The carbon atom is surrounded by two electron density zones that are arranged in a linear pattern. In a linear electron pair geometry, the hybridization is \({\rm{sp}}\), and the electrons are not delocalized.

Carbon dioxide

04

Subpart (c)

Nitrogen dioxide (\({\rm{N}}{{\rm{O}}_{\rm{2}}}\)): In a trigonal planar structure, the core nitrogen atom is surrounded by three zones of electron density. In a trigonal planar electron pair geometry, the hybridization is \({\rm{s}}{{\rm{p}}^{\rm{2}}}\), and the electrons are delocalized.

Nitrogen dioxide molecule

05

Subpart (d)

Phosphate ion (\({\rm{P}}{{\rm{O}}_{\rm{4}}}^{{\rm{3 - }}}\)): In a tetrahedral structure, the core phosphorus atom is surrounded by four zones of electron density. In a tetrahedral electron pair geometry, the hybridization is \({\rm{s}}{{\rm{p}}^{\rm{3}}}\) and the electrons are delocalized

Phosphate ion

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Most popular questions from this chapter

A friend tells you \({{\rm{N}}_{\rm{2}}}\)has three \({\rm{\pi }}\)bonds due to overlap of the three p-orbitals on each N atom. Do you agree?

If molecular orbitals are created by combining five atomic orbitals from atom A and five atomic orbitals from atom B combine, how many molecular orbitals will result?

Identify the hybridization of each carbon atom in the following molecule. (The arrangement of atoms is given; you need to determine how many bonds connect each pair of atoms.)

Predict the valence electron molecular orbital configurations for the following, and state whether they will be stable or unstable ions.

(a) \({\rm{N}}{{\rm{a}}_{\rm{2}}}^{{\rm{2 + }}}\)

(b) \({\rm{M}}{{\rm{g}}_{\rm{2}}}^{{\rm{2 + }}}\)

(c) \({\rm{A}}{{\rm{l}}_{\rm{2}}}^{{\rm{2 + }}}\)

(d) \({\rm{S}}{{\rm{i}}_{\rm{2}}}^{{\rm{2 + }}}\)

(e) \({\rm{P}}_{\rm{2}}^{{\rm{2 + }}}\)

(f) \({{\rm{S}}_{\rm{2}}}^{{\rm{2 + }}}\)

(g) \({{\rm{F}}_{\rm{2}}}^{{\rm{2 + }}}\)

(h) \({\rm{A}}{{\rm{r}}_{\rm{2}}}^{{\rm{2 + }}}\)

Strike-anywhere matches contain a layer of \({\rm{KCl}}{{\rm{O}}_{\rm{3}}}\) and a layer of \({{\rm{P}}_{\rm{4}}}{{\rm{S}}_{\rm{3}}}\). The heat produced by the friction of striking the match causes these two compounds to react vigorously, which sets fire to the wooden stem of the match. \({\rm{KCl}}{{\rm{O}}_{\rm{3}}}\) contains the \({\rm{Cl}}{{\rm{O}}_{\rm{3}}}^{\rm{ - }}\) ion. \({{\rm{P}}_{\rm{4}}}{{\rm{S}}_{\rm{3}}}\) is an unusual molecule with the skeletal structure.

  1. Write Lewis structures for \({{\rm{P}}_{\rm{4}}}{{\rm{S}}_{\rm{3}}}\) and the \({\rm{Cl}}{{\rm{O}}_{\rm{3}}}^{\rm{ - }}\) ion.
  2. Describe the geometry about the \({\rm{P}}\) atoms, the \({\rm{S}}\) atom, and the \({\rm{Cl}}\) atom in these species.
  3. Assign a hybridization to the \({\rm{P}}\) atoms, the \({\rm{S}}\)atom, and the \({\rm{Cl}}\) atom in these species.
  4. Determine the oxidation states and formal charge of the atoms in \({{\rm{P}}_{\rm{4}}}{{\rm{S}}_{\rm{3}}}\) and the \({\rm{Cl}}{{\rm{O}}_{\rm{3}}}^{\rm{ - }}\) ion.

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