Predict which of the following compounds are ionic and which are covalent, based on the location of their constituent atoms in the periodic table:

(a) \({\rm{C}}{{\rm{l}}_{\rm{2}}}{\rm{CO}}\) (b) \({\rm{MnO}}\) (c) \({\rm{NC}}{{\rm{l}}_{\rm{3}}}\) (d) \({\rm{CoB}}{{\rm{r}}_{\rm{2}}}\) (e) \({{\rm{K}}_{\rm{2}}}{\rm{S}}\) (f) \({\rm{CO}}\) (g) \({\rm{Ca}}{{\rm{F}}_{\rm{2}}}\) (h) \({\rm{HI}}\) (i) \({\rm{CaO}}\) (j) \({\rm{IBr}}\) (k) \({\rm{C}}{{\rm{O}}_{\rm{2}}}\) .

Short Answer

Expert verified

The ionic compounds are: \({\rm{MnO, CoB}}{{\rm{r}}_{\rm{2}}}{\rm{, }}{{\rm{K}}_{\rm{2}}}{\rm{S, Ca}}{{\rm{F}}_{\rm{2}}}\) and \({\rm{CaO}}\).

The covalent compounds are: \({\rm{C}}{{\rm{l}}_{\rm{2}}}{\rm{CO, NC}}{{\rm{l}}_{\rm{3}}}{\rm{, CO, HI, IBr}}\) and \({\rm{C}}{{\rm{O}}_{\rm{2}}}\).

Step by step solution

01

Define Chemical Bonding 

A chemical bond is a long-term attraction between atoms, ions, or molecules that allows chemical compounds to form.

02

Predicting that the ions are ionic or covalent?

Based on the location of the elements in the periodic table: If the elements in a compound are close to one another in the periodic table, the bond is more likely to be covalent, but if the elements are far apart, the bond is more likely to be ionic.

Now, based on the above reasoning, we may conclude that:

Ionic compounds include\({\rm{MnO, CoB}}{{\rm{r}}_{\rm{2}}}{\rm{, }}{{\rm{K}}_{\rm{2}}}{\rm{S, Ca}}{{\rm{F}}_{\rm{2}}}\), and\({\rm{CaO}}\), whereas covalent compounds include\({\rm{C}}{{\rm{l}}_{\rm{2}}}{\rm{CO, NC}}{{\rm{l}}_{\rm{3}}}{\rm{, CO, HI, IBr}}\), and\({\rm{C}}{{\rm{O}}_{\rm{2}}}\).

Therefore, Ionic include \({\rm{MnO, CoB}}{{\rm{r}}_{\rm{2}}}{\rm{, }}{{\rm{K}}_{\rm{2}}}{\rm{S, Ca}}{{\rm{F}}_{\rm{2}}}\), and \({\rm{CaO}}\), as well as covalent compounds are \({\rm{C}}{{\rm{l}}_{\rm{2}}}{\rm{CO, NC}}{{\rm{l}}_{\rm{3}}}{\rm{, CO, HI, IBr}}\), and \({\rm{C}}{{\rm{O}}_{\rm{2}}}\).

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Most popular questions from this chapter

Use the simulation (http://openstaxcollege.org/l/16MolecPolarity) to perform the following exercises for a real molecule. You may need to rotate the molecules in three dimensions to see certain dipoles. (a) Sketch the bond dipoles and molecular dipole (if any) for O3. Explain your observations. (b) Look at the bond dipoles for NH3. Use these dipoles to predict whether N or H is more electronegative. (c) Predict whether there should be a molecular dipole for NH3 and, if so, in which direction it will point. Check the molecular dipole box to test your hypothesis.

Identify the molecules with a dipole moment:

  1. \({\rm{S}}{{\rm{F}}_{\rm{4}}}\)
  2. \({\rm{C}}{{\rm{F}}_{\rm{4}}}\)
  3. \({\rm{C}}{{\rm{l}}_{\rm{2}}}{\rm{CCB}}{{\rm{r}}_{\rm{2}}}\)
  4. \({\rm{C}}{{\rm{H}}_{\rm{3}}}{\rm{Cl}}\)
  5. \({{\rm{H}}_{\rm{2}}}{\rm{CO}}\)

What feature of a Lewis structure can be used to tell if a molecule’s (or ion’s) electron-pair geometry and molecular structure will be identical?

As a general rule, \({\rm{M}}{{\rm{X}}_{\rm{n}}}\) molecules (where \({\rm{M}}\) represents a central atom and \({\rm{X}}\) represents terminal atoms; \({\rm{n = 2 - 5}}\)) are polar if there is one or more lone pairs of electrons on \({\rm{M}}\). \({\rm{N}}{{\rm{H}}_{\rm{3}}}\) (\({\rm{M = N, X = H, n = 3}}\)) is an example. There are two molecular structures with lone pairs that are exceptions to this rule. What are they?

Sodium nitrite, which has been used to preserve bacon and other meats, is an ionic compound. Write the resonance forms of the nitrite ion, \({\rm{NO}}_{\rm{2}}^{\rm{ - }}\).

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