Which of the following molecules or ions contain polar bonds? (a) \({{\rm{S}}_{\rm{8}}}\) (b) \({{\rm{S}}_{\rm{8}}}\) (c) \({{\rm{O}}_{\rm{2}}}^{{\rm{2 - }}}\) (d) \({\rm{N}}{{\rm{O}}_{\rm{3}}}^{\rm{ - }}\) (e) \({\rm{C}}{{\rm{O}}_{\rm{2}}}\) (f) \({{\rm{H}}_{\rm{2}}}{\rm{S}}\) (g) \({\rm{B}}{{\rm{H}}_{\rm{4}}}^{\rm{ - }}\) .

Short Answer

Expert verified

The values which have non-polar bonds are:\({{\rm{O}}_{\rm{3}}}{\rm{ , }}{{\rm{S}}_{\rm{8}}}\)and\({{\rm{O}}_{\rm{2}}}^{{\rm{2 - }}}\).

The values which have polar bonds are: \({\rm{N}}{{\rm{O}}_{\rm{3}}}^{\rm{ - }}{\rm{ , C}}{{\rm{O}}_{\rm{2}}}{\rm{ , }}{{\rm{H}}_{\rm{2}}}{\rm{S}}\) and \({\rm{B}}{{\rm{H}}_{\rm{4}}}^{\rm{ - }}\) .

Step by step solution

01

Define Chemical Bonding

A chemical bond is an attraction between atoms, ions, or molecules that allows chemical compounds to form.

02

Finding which molecules or ions contain polar bonds?

The concept applied in this topic is that compounds having a single kind of element will have non-polar bonds since the electronegativity difference will be zero.

As a result of the foregoing reasoning,\({{\rm{O}}_{\rm{3}}}{\rm{ , }}{{\rm{S}}_{\rm{8}}}\), and\({{\rm{O}}_{\rm{2}}}^{{\rm{2 - }}}\)have nonpolar bonds, whereas\({\rm{N}}{{\rm{O}}_{\rm{3}}}^{\rm{ - }}{\rm{ , C}}{{\rm{O}}_{\rm{2}}}{\rm{ , }}{{\rm{H}}_{\rm{2}}}{\rm{S}}\), and\({\rm{B}}{{\rm{H}}_{\rm{4}}}^{\rm{ - }}\)have polar bonds.

Therefore, the values having non-polar bonds are:\({{\rm{O}}_{\rm{3}}}{\rm{ , }}{{\rm{S}}_{\rm{8}}}\)and\({{\rm{O}}_{\rm{2}}}^{{\rm{2 - }}}\).

The values having polar bonds are: \({\rm{N}}{{\rm{O}}_{\rm{3}}}^{\rm{ - }}{\rm{ , C}}{{\rm{O}}_{\rm{2}}}{\rm{ , }}{{\rm{H}}_{\rm{2}}}{\rm{S}}\) and \({\rm{B}}{{\rm{H}}_{\rm{4}}}^{\rm{ - }}\) .

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Most popular questions from this chapter

Which compound in each of the following pairs has the larger lattice energy? Note: \({\rm{B}}{{\rm{a}}^{{\rm{2 + }}}}\) and \({{\rm{K}}^{\rm{ + }}}\) have similar radii; \({{\rm{S}}^{{\rm{2 - }}}}\) and \({\rm{C}}{{\rm{l}}^{\rm{ - }}}\) have similar radii. Explain your choices.

(a) \({{\rm{K}}_{\rm{2}}}{\rm{O}}\) or \({\rm{N}}{{\rm{a}}_{\rm{2}}}{\rm{O}}\)

(b) \({{\rm{K}}_{\rm{2}}}{\rm{S}}\) or \({\rm{BaS}}\)

(c) \({\rm{KCl}}\) or \({\rm{BaS}}\)

(d) \({\rm{BaS}}\) or \({\rm{BaC}}{{\rm{l}}_{\rm{2}}}\)

Two arrangements of atoms are possible for a compound with a molar mass of about\({\rm{45 g/mol}}\)that contains\({\rm{52}}{\rm{.2 \% C, 13}}{\rm{.1 \% H}}\), and\({\rm{34}}{\rm{.7 \% O}}\)by mass. Write the Lewis structures for the two molecules.

Use the simulation (http://openstaxcollege.org/l/16MolecPolarity) to perform the following exercises for a two-atom molecule: (a) Adjust the electronegativity value so the bond dipole is pointing toward B. Then determine what the electronegativity values must be to switch the dipole so that it points toward A. (b) With a partial positive charge on A, turn on the electric field and describe what happens. (c) With a small partial negative charge on A, turn on the electric field and describe what happens. (d) Reset all, and then with a large partial negative charge on A, turn on the electric field and describe what happens.

Write Lewis structures for the following: (a) \({\rm{CI}}{{\rm{F}}_{\rm{3}}}\) (b) \({\rm{PC}}{{\rm{I}}_{\rm{5}}}\) (c) \({\rm{B}}{{\rm{F}}_{\rm{3}}}\) (d) \({\rm{P}}{{\rm{F}}_{\rm{6}}}^{\rm{ - }}\) .

Does a cation gain protons to form a positive charge or does it lose electrons?

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