Write Lewis structures for the following: (a) \({\rm{CI}}{{\rm{F}}_{\rm{3}}}\) (b) \({\rm{PC}}{{\rm{I}}_{\rm{5}}}\) (c) \({\rm{B}}{{\rm{F}}_{\rm{3}}}\) (d) \({\rm{P}}{{\rm{F}}_{\rm{6}}}^{\rm{ - }}\) .

Short Answer

Expert verified

The Lewis structure for the following are:

Step by step solution

01

Define Chemical Bonding

A chemical bond is formed between atoms, ions, or molecules that allows formation of chemical compounds.

02

Concept

The following are the steps to drawing a Lewis structure:

(1) First, determine the total number of valence electrons, then deduct one electron for each positive charge if it is a cation, or add one electron for each negative charge if it is an anion.

(2) Now, arrange the atoms around the core atom to form a skeletal structure for the molecule. The least electronegative atom is typically chosen as the center atom. Connect each atom to the core atom with a single bond now.

(3) Now, on all atoms save the center atom, distribute the remaining electrons as lone pairs to complete their octet. (Except for hydrogen, which only takes two electrons to complete its duplet.)

(4) Now, arrange the remaining electrons around the central atom.

(5) Now, if any atom's octet is not full, draw several bonds with the central atom correspondingly.

03

Writing the Lewis structure

(a) The Lewis structure of the value \({\rm{CI}}{{\rm{F}}_{\rm{3}}}\) is:


04

Writing the Lewis structure

(b) The Lewis structure of the value \({\rm{PC}}{{\rm{I}}_{\rm{5}}}\) is:


05

Writing the Lewis structure

(c) The Lewis structure of the value \({\rm{B}}{{\rm{F}}_{\rm{3}}}\) is:


06

Writing the Lewis structure

(d) The Lewis structure of the value \({\rm{P}}{{\rm{F}}_{\rm{6}}}^{\rm{ - }}\) is:


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Most popular questions from this chapter

The reaction of a metal, \({\rm{M}}\), with a halogen, \({{\rm{X}}_{\rm{2}}}\), proceeds by an exothermic reaction as indicated by this equation: \({\rm{M(s) + }}{{\rm{X}}_{\rm{2}}}{\rm{(g)}} \to {\rm{M}}{{\rm{X}}_{\rm{2}}}{\rm{(s)}}\). For each of the following, indicate which option will make the reaction more exothermic. Explain your answers.

(a) a large radius vs. a small radius for \({{\rm{M}}^{{\rm{ + 2}}}}\)

(b) a high ionization energy vs. a low ionization energy for \({\rm{M}}\)

(c) an increasing bond energy for the halogen

(d) a decreasing electron affinity for the halogen

(e) an increasing size of the anion formed by the halogen

In terms of the bonds present, explain why acetic acid, \(C{H_3}C{O_2}H\), contains two distinct types of carbon-oxygen bonds, whereas the acetate ion, formed by loss of a hydrogen ion from acetic acid, only contains one type of carbon-oxygen bond. The skeleton structures of these species are shown:

Question: Using the standard enthalpy of formation data in Appendix G, determine which bond is stronger: the \({\rm{P - Cl}}\) bond in \({\rm{PC}}{{\rm{l}}_{\rm{3}}}{\rm{(g)}}\) or in \({\rm{PC}}{{\rm{l}}_{\rm{5}}}{\rm{(g)}}\)?

From its position in the periodic table, determine which atom in each pair is more electronegative: (a)\({\rm{N or P}}\)(b)\({\rm{N or Ge}}\)(c)\({\rm{S or F}}\)(d)\({\rm{Cl or S}}\)(e)\({\rm{H or C}}\)(f)\({\rm{Se or P}}\)(g)\({\rm{C or Si}}\).

Use the simulation (http://openstaxcollege.org/l/16MolecPolarity) to perform the following exercises for a real molecule. You may need to rotate the molecules in three dimensions to see certain dipoles. (a) Sketch the bond dipoles and molecular dipole (if any) for O3. Explain your observations. (b) Look at the bond dipoles for NH3. Use these dipoles to predict whether N or H is more electronegative. (c) Predict whether there should be a molecular dipole for NH3 and, if so, in which direction it will point. Check the molecular dipole box to test your hypothesis.

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