Question- Determine the empirical and molecular formula for chrysotile asbestos. Chrysotile has the following percent composition: 28.03% Mg, 21.60% Si, 1.16% H, and 49.21% O. The molar mass for chrysotile is 520.8g/mol.

Short Answer

Expert verified

The molecular formula for chrysotile asbestos is Mg6Si4H6O16 and the empirical formula is Mg3Si2H3O8.

Step by step solution

01

Step 1- Given data

Percent composition of Mg-28.03%

Percent composition of Si- 21,60%

Percent composition of H- 1.16%

Percent composition of O-49.21%

02

Step 2- Calculating moles

The molar mass of Mg = 24g

The molar mass of Si = 28g

The molar mass of H = 1g

The molar mass of oxygen = 16g

Moles of Mg = 28.03/24 = 1.167mol

Moles of Si = 21.60/28 = 0.77mol

Moles of H = 1.16/1 = 1.16mol

Moles of O = 49.21/16 = 3.07mol

Dividing moles by the smallest number i.e 0.77

Moles of Mg = 1.5 mol

Moles of Si = 1mol

Moles of H = 1.5mol

Moles of O = 3.9

Now, the empirical formula will be

Mg1.5Si1H1.5O3.9

Multiplying by 2 to make it a whole number

= Mg3Si2H3O8

03

Step 3- Writing molecular formula

The molecular mass of the empirical formula

= (3 x 24) +( 2 x 28 )+ (3 x 1) +( 8 x 16)

= 259g

Given mass = 520.8g

N = given mass/empirical formula mass

= 520.8g/259g = 2

Now multiplying n to the empirical formula to get the molecular formula

Therefore, the molecular formula = Mg6Si4H6O16

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