Use cell notation to describe the galvanic cell where copper(II) ions are reduced to copper metal and zinc metal is oxidized to zinc ions.

Short Answer

Expert verified

The cell notation is \({\mathop{\rm Zn}\nolimits} (s)\left| {{\rm{Z}}{{\rm{n}}^{2 + }}(aq) | |{\rm{C}}{{\rm{u}}^{2 + }}(aq)} \right|{\rm{Cu}}(s).\)

Step by step solution

01

Define the balanced chemical reactions

In electrochemistry, a Galvanic cellis a kind of electrochemical cell in which the current is produced using a redox reaction. Redox reactions involve oxidation as well as reduction. A galvanic cell consists of two half cells. In the one-half cell, oxidation occurs. This half-cell acts as the anode. In the other half cell, reduction occurs, This half-cell is termed as the cathode. These two half cells work together and constitute an electrochemical cell.

02

Determine the Balance equation

Anode (oxidation): \(\quad {\rm{Zn}}(s) \to {\rm{Z}}{{\rm{n}}^{2 + }}(aq) + 2{{\rm{e}}^ - }\)

Cathode (reduction): \({\rm{C}}{{\rm{u}}^{2 + }}(aq) + 2{{\rm{e}}^ - } \to {\rm{Cu}}(s)\)

Overall: \(\quad {\rm{Zn}}(s) + {\rm{C}}{{\rm{u}}^{2 + }}(aq \to {\rm{Z}}{{\rm{n}}^{2 + }}(aq) + {\rm{Cu}}(s)\)

Using cell notation: \({\mathop{\rm Zn}\nolimits} (s)\left| {{\rm{Z}}{{\rm{n}}^{2 + }}(aq) | |{\rm{C}}{{\rm{u}}^{2 + }}(aq)} \right|{\rm{Cu}}(s).\)

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Most popular questions from this chapter

Aluminium\(\left( {{\bf{E}}_{{\bf{A}}{{\bf{l}}^{{\bf{3 + }}}}{\bf{/Al}}}^{\bf{^\circ }}{\bf{ = - 2}}{\bf{.07\;V}}} \right)\) is more easily oxidized than iron \(\left( {{\bf{E}}_{{\bf{F}}{{\bf{e}}^{\bf{3}}}}^{\bf{^\circ }}{\bf{/F}}{{\bf{e}}^{\bf{ - }}}{\bf{ = - 0}}{\bf{.477\;V}}} \right){\bf{,}}\) and yet when both are exposed to the environment, untreated aluminium has very good corrosion resistance while the corrosion resistance of untreated iron is poor. Explain this observation.

List some things that are typically considered when selecting a battery for a new application.

The mass of three different metal electrodes, each from a different galvanic cell, were determined before andafter the current generated by the oxidation-reduction reaction in each cell was allowed to flow for a few minutes.The first metal electrode, given the label A, was found to have increased in mass; the second metal electrode, giventhe label B, did not change in mass; and the third metal electrode, given the label C, was found to have lost mass.

Make an educated guess as to which electrodes were active and which were inert electrodes, and which wereanode(s) and which were the cathode(s)

Aluminium metal can be made from aluminium ions by electrolysis. What is the half-reaction at the cathode? What mass of aluminium metal would be recovered if a current of 2.50 × 103 A passed through the solution for 15.0 minutes? Assume the yield is 100%

Given the following cell notations, determine the species oxidized, species reduced, and the oxidizing agent and reducing agent, without writing the balanced reactions

a. \({\rm{Mg}}(s)\left| {{\rm{M}}{{\rm{g}}^{2 + }}(aq) || {\rm{C}}{{\rm{u}}^{2 + }}(aq)} \right|{\rm{Cu}}(s)\)

b.\({\rm{Ni}}(s)\left| {{\rm{N}}{{\rm{i}}^{2 + }}(aq) || {\rm{A}}{{\rm{g}}^ + }(aq)} \right|{\rm{Ag}}(s)\)

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