Question: We have seen an introductory definition of an acid: An acid is a compound that reacts with water and increases the amount of hydronium ion present. In the chapter on acids and bases, we saw two more definitions of acids: a compound that donates a proton (a hydrogen ion, \({H^ + }\)) to another compound is called a Brønsted-Lowry acid, and a Lewis acid is any species that can accept a pair of electrons. Explain why the introductory definition is a macroscopic definition, while the Brønsted-Lowry definition and the Lewis definition are microscopic definitions.

Short Answer

Expert verified

The atomic particles or subatomic levels that cannot be seen through the naked eye are called microscopic definition.

Therefore, the Bronsted- Lowry definition and the Lewis definition are microscopic definitions.

The particles or things that can be seen directly are called macroscopic definitions.

We can measure and calculate the change in the concentration of\({{\rm{H}}_3}{{\rm{O}}^ + }\)ion, therefore, the introductory definition of an acid is a macroscopic definition.

Step by step solution

01

Define the Bronsted-Lowry acid and Lewis acid:

Protons that are donated from one compound to another are called Bronsted-Lowry acid.

Electron pairs that are accepted by the substance are called Lewis acid.

02

Determine the acids that belong to the microscopic and macroscopic definitions:

Hence, the atomic particles or subatomic levels like protons and electrons that cannot be visible to the naked eye directly are called microscopic particles.

Since the Bronsted-Lowry acid and Lewis acid depends upon the protons and electrons, they belong to the microscopic definition.

Thus, the particles or things that can be easily seen directly by direct observations of physical properties are called macroscopic particles.

Since we can measure and calculate the change in the concentration of\(\)\({{\rm{H}}_3}{{\rm{O}}^ + }\)ion, the introductory definition of an acid belongs to the macroscopic definition.

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Most popular questions from this chapter

The following question is taken from a Chemistry Advanced Placement Examination and is used with the permission of the Educational Testing Service. Solve the following problem:

MgF2 (S) ⇌ Mg2+(aq) + 2F- (aq)

In a saturated solution of MgF2 at 18 °C, the concentration ofMg2+is 1.21×10-3 M.

The equilibrium is represented by the preceding equation.

(a) Write the expression for the solubility-product constant, Ksp, and calculate its value at 18 °C.

(b) Calculate the equilibrium concentration of Mg2+ in 1.000 L of saturated MgF2solution at 18 °C to which 0.100 mol of solid KF has been added. The KF dissolves completely. Assume the volume change is negligible.

(c) Predict whether a precipitate of MgF­2 will form whensolution of 100.0mL of a 3.00 ×10-3 -M Mg(NO3)2 is mixed with 200.0 mL of a 2.00 × 10–3 -M solution of NaF at 18 °C. Show the calculations to support your prediction.

(d) At 27 °C the concentration of Mg2+ in a saturated solution of MgF2 is 1.17×10-3 M. Is the dissolving of MgF2 in water an endothermic or an exothermic process? Give an explanation to support your conclusion.

Question: What are the concentrations of Ag+, CN, and Ag (CN)2 in a saturated solution of AgCN?

Question: Calculate the equilibrium concentration of Zn2+ in a 3.0 M solution of\(Zn(CN)_4^{2 - }\) .

Question:Boric acid, H3BO3, is not a Brønsted-Lowry acid but a Lewis acid.

(a) Write an equation for its reaction with water.

(b) Predict the shape of the anion thus formed.

(c) What is the hybridization on the boron consistent with the shape you have predicted?

Assuming that no equilibria other than dissolution are involved, calculate the concentrations of ions in a saturated solution of each of the following (see Appendix J for solubility products).

(a) TlCl

(b) \(Ba{F_2}\)

(c) \(A{g_2}Cr{O_4}\)

(d) \(Ca{C_2}{O_4} \times {H_2}O\)

(e) The mineral anglesite, \(PbS{O_4}\)

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