Question:Hydrogen is prepared commercially by the reaction of methane and water vapor at elevated temperatures. \(C{H_4}(g) + {H_2}O(g) \rightleftharpoons 3{H_2}(g) + CO(g)\)

Short Answer

Expert verified

The reaction of the elevated temperatures \(K = 6.28\)

Step by step solution

01

Define Hydrogen atom

A hydrogen atom is an atom of the chemical element hydrogen. The electrically neutral atom contains a single positively charged proton and a single negatively charged electron bound to the nucleus by the Coulomb force. Atomic hydrogen constitutes about 75% of the baryonic mass of the universe

02

The reaction of equilibrium constant reaction

We need to calculate equilibrium constant for following reaction:

\(C{H_4}(g) + {H_2}O(g) \to 3{H_2}(g) + CO(g)\)

this is a reverse reaction so it should be written with a double arrow. Equilibrium constant is calculated like this:

\(K = \frac{{c\left( {{H_2}} \right)_{eq}^3 \cdot c{{(CO)}_{eq}}}}{{c{{\left( {C{H_4}} \right)}_{eq}} \cdot c{{\left( {{H_2}O} \right)}_{eq}}}}\)

03

Solving the concentration of the compound \({C_{eq}}\) 

\(\begin{array}{*{20}{c}}{c{{\left( {{H_2}} \right)}_{eq}} = 1.15M}\\{c{{(CO)}_{eq}} = 0.126M}\\{c{{\left( {C{H_4}} \right)}_{eq}} = 0.126M}\\{c{{\left( {{H_2}O} \right)}_{eq}} = 0.242M}\end{array}\)

The constant equation\(\begin{array}{*{20}{c}}{K = \frac{{{{1.15}^3} \cdot 0.126}}{{0.126 \cdot 0.242}}}\\{K = 6.28}\end{array}\)

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

What is the pressure of \(BrCl\) in an equilibrium mixture of \(C{l_2}\), \(B{r_2}\), and \(BrCl\) if the pressure of \(C{l_2}\) in the mixture is \(0.115atm\)and the pressure of \(B{r_2}\) in the mixture is \(0.450atm\)?

\(C{l_2}(g) + B{r_2}(g) \rightleftharpoons 2BrCl(g)\)

\({K_P} = 4.7 \times 1{0^{ - 2}}\)

Which of the systems described in Exercise 13.15 give homogeneous equilibria? Which give heterogeneous equilibria?

(a) \(C{H_4}(g) + C{l_2}\rightleftharpoons C{H_3}CI(g) + HCI(g)\)

(b)\({N_2}(g) + {O_2}(g)\rightleftharpoons 2NO(g)\)

(c)\(2S{O_2}(\;g) + {O_2}(\;g)\rightleftharpoons 2S{O_3}(\;g)\)

(d)\(BaS{O_3}(s)\rightleftharpoons BaO(s) + S{O_2}(g)\)

(e) \({P_4}(g) + 5{O_2}(g)\rightleftharpoons{P_4}{O_{10}}(s)\)

(f)\(B{r_2}(\;g)\rightleftharpoons 2Br(g)\)

(g) \(C{H_4}(g) + 2{O_2}(g)\rightleftharpoons C{O_2}(g) + 2{H_2}O(l)\)

(h) \(CuS{O_4} \times 5{H_2}O(s)\rightleftharpoons CuS{O_4}(s) + 5{H_2}O(g)\)

A student solved the following problem and found \(\left[ {{N_2}{O_4}} \right] = 0.16M\)at equilibrium. How could this student recognize that the answer was wrong without reworking the problem? The problem was: What is the equilibrium concentration of \(\left[ {{N_2}{O_4}} \right]\) in a mixture formed from a sample of \(N{O_2}\) with a concentration of \(0.10M\)?

\(2N{O_2}(g) \rightleftharpoons {N_2}{O_4}(g)\)

\({K_c} = 160\)

Question:What is the value of the equilibrium constant at \(50{0^o}C\) for the formation of \(N{H_3}\)according to the following equation? N2(g) + 3H2(g) ⇌ 2NH3(g)

An equilibrium mixture of \(N{H_3}(g)\) \({H_2}(g)\) and \({N_2}(g)\) at \(50{0^o}C\) was found to contain\(1.35M{H_2},1.15M{N_2}\)and \(4.12\)\( \times 1{0^{ - 1}}MN{H_3}\)

What are the concentrations of \(PC{l_5}\), \(PC{l_3}\), and \(C{l_2}\) in an equilibrium mixture produced by the decomposition of a sample of pure \(PC{l_5}\) with \([PC{l_5}] = 2.00M?\) \(PC{l_5}(g) \rightleftharpoons PC{l_3}(g) + {\mathbf{C}}{{\mathbf{l}}_{\mathbf{2}}}(g)\,\,\,\,\,\,\,\;{\mathbf{Kc}} = {\mathbf{0}}.{\mathbf{0}}211\)

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free