Question: Using the postulates of the kinetic molecular theory, explain why a gas uniformly fills a container of any shape.

Short Answer

Expert verified

The first postulate of the kinetic molecular theory suggests that gas molecules collide with walls of a container and fills a container of any shape.

Step by step solution

01

Concept Introduction

The following postulates, or assumptions, underpin the kinetic molecular theory.

  • Gases consist of a vast number of particles, which acts like hard, spherical objects moving in a random manner.
  • These particles travel in a straight line until they clash with another particle or a container's walls.
  • The space between the particles is substantially smaller than the size of the particles. As a result, the majority of a gas's volume is empty space.
  • No attraction exists between gas particles or between the particles and a container's walls.
  • When a gas particle collides with another particle or with the ground, none of its energy is wasted.
02

Postulate of Kinetic Molecular Theory

From the first postulate of the kinetic molecular theory, gas molecules are in continuous motion, traveling in straight lines and changing directions only when they collide with other molecules or with the walls of a container. Gas molecules in a container constantly collide with each other and with the walls of a container, due to which they change their direction, and these collisions are completely random due to which the gas molecules distribute uniformly. It can also fill a container of any shape. Therefore, gases fill a container completely.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Question: Answer the following questions:

(a) If \({\rm{XX}}\) behaved as an ideal gas, what would its graph of \({\rm{Z}}\) vs. \({\rm{P}}\) look like?

(b) For most of this chapter, we performed calculations treating gases as ideal. Was this justified?

(c) What is the effect of the volume of gas molecules on \({\rm{Z}}\)? Under what conditions is this effect small? When is it large? Explain using an appropriate diagram.

(d) What is the effect of intermolecular attractions on the value of \({\rm{Z}}\)? Under what conditions is this effect small? When is it large? Explain using an appropriate diagram.

(e) In general, under what temperature conditions would you expect \({\rm{Z}}\) to have the largest deviations from the \({\rm{Z}}\) for an ideal gas?

The pressure of a sample of gas is measured at sea level with a closed-end manometer. The liquid in the manometer is mercury. Determine the pressure of the gas in: (a) torr (b) Pa (c) bar.


In addition to the data found in Figure \({\rm{9}}{\rm{.13}}\), what other information do we need to find the mass of the sample of air used to determine the graph?

Question: Under which of the following sets of conditions does a real gas behave most like an ideal gas, and for which conditions is a real gas expected to deviate from ideal behaviour? Explain.

(a) high pressure, small volume

(b) high temperature, low pressure

(c) low temperature, high pressure

Question:A 1-L sample of CO initially at STP is heated to 5460C, and its volume is increased to 2-L. (a) What effect do these changes have on the number of collisions of the molecules of the gas per unit area of the container wall? (b) What is the effect on the average kinetic energy of the molecules? (c) What is the effect on the root mean square speed of the molecules?

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free