Determine which of the two diagrams here (both for the same reaction) involves a catalyst, and identify the activation energy for the catalyzed reaction:

Short Answer

Expert verified

A catalysed process with an activation energy of roughly 70 kJ is shown in diagram (b).

Step by step solution

01

Rate of a Reaction 

The rate of reaction may be defined as the speed of the reactant reacting to obtaina product in a particular reaction at a particular time. The concentration of the reactant and product are represented into mole/L.

\({\bf{Rate = k}}{\left( {\bf{A}} \right)^{\bf{m}}}{\left( {\bf{B}} \right)^{\bf{n}}}^{}\)

02

Catalysed and Un-catalysed Reaction

Catalysed reaction has a lower activation energy because there is an enzyme present in the reaction. Un-catalysed reaction has a higher activation energy because there is no enzyme present in the reaction

03

Explanation

The only difference between a catalysed reaction and an un-catalysed reaction is that the activation energy is different. There is no effect on the. Catalysis is the process of increasing the rate of a chemical reaction by adding a substance Catalysed reactions have a lower activation energy (rate-limiting free energy of activation) than the corresponding un-catalysed reaction, resulting in a higher reaction.\(\)

\(\begin{aligned}{}\left( {\bf{a}} \right){\bf{\;Ea = 90 - 75 = 25 KJ}}\\\left( {\bf{b}} \right){\bf{Ea = 80 - 75 = 5 KJ}}\end{aligned}\) \(\)

Catalysed reaction with an activation energy of about 70 kJshown in Diagram (b)

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Most popular questions from this chapter

For the past 10 years, the unsaturated hydrocarbon 1,3-butadiene \(\left( {{\bf{C}}{{\bf{H}}_{\bf{2}}}{\bf{ = CH - CH = C}}{{\bf{H}}_{\bf{2}}}} \right)\) has ranked 38th among the top 50 industrial chemicals. It is used primarily for the manufacture of synthetic rubber. An isomer exists also as cyclobutene:

The isomerization of cyclobutene to butadiene is first-order, and the rate constant has been measured as \({\bf{2}}{\bf{.0 \times 1}}{{\bf{0}}^{{\bf{ - 4}}}}{{\bf{s}}^{{\bf{ - 1}}}}\) at 150 \({\bf{^\circ C}}\) in a 0.53-L flask. Determine the partial pressure of cyclobutene and its concentration after 30.0 minutes if an isomerization reaction is carried out at 150 \({\bf{^\circ C}}\) with an initial pressure of 55 torr.

The element Co exists in two oxidation states, Co(II) and Co(III), and the ions form many complexes. The rate at which one of the complexes of Co(III) was reduced by Fe(II) in water was measured. Determine the activation energy of the reaction from the following data:

Temperature(K)

k(s-1)

293

0.054

298

0.100

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Does the following data fit a second-order rate law?

Trial

Time(s)

(A) (M)

1

5

0.952

2

10

0.625

3

15

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20

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5

25

0.308

6

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0.230

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