If the rate of decomposition of ammonia, \({\bf{N}}{{\bf{H}}_{\bf{3}}}\), at 1150 K is \(2.10 \times 1{0^{ - 6}}mol/L/s\), what is the rate of production of nitrogen and hydrogen?

Short Answer

Expert verified

The rate of production of nitrogen and hydrogen \(1.05 \times 1{0^{ - 6}}mol/L/s\), \({{\bf{N}}_{\bf{2}}}\) and \(3.15 \times 1{0^{ - 6}}mol/L/s\), \({{\bf{H}}_{\bf{2}}}\).

Step by step solution

01

Rate of a Reaction

The rate of the reaction is the rate of the reaction or how fast or slow reaction can happen. The reaction involves the reactant which are bound to give product at a certain period of time.

02

Explanation

One may determine after using the stoichiometry of the reaction,

\(\begin{aligned} - 1/2 \Delta \left( {N{H_3}} \right)/\Delta t = 1/3 \Delta \left( {{N_2}} \right)/\Delta t = \Delta \left( {{H_2}} \right)/\Delta t,\\\begin{aligned}{{20}{l}} {Rate of disappearance N{H_3} = - 1/2 \Delta \left( {N{H_3}} \right) / \Delta t}\\{Rate of Formation of {N_2} = 1/3 \Delta \left( {{N_2}} \right) / \Delta t}\\{Rate of formation of {H_2} = \Delta \left( {{H_2}} \right) / \Delta t}\end{aligned}\end{aligned}\)

Therefore:

Rate of Production of \({{\bf{N}}_{\bf{2}}}\)

\(\begin{aligned}1/2 \times 2.10 \times 1{0^{ - 6}}mol {\left( {Ls} \right)^{ - 1}} = \Delta ({N_2})/\Delta t\\\Delta ({N_2})/\Delta t = 1.05 \times 1{0^{ - 6}}mol {\left( {Ls} \right)^{ - 1}}\end{aligned}\)

Rate of production of \({{\bf{H}}_{\bf{2}}}\)

\(\begin{aligned}\Delta ({H_2})/\Delta t = 3 \times 2.10 \times 1{0^{ - 6}}mol {\left( {Ls} \right)^{ - 1}}/ 2\\\Delta ({H_2})/\Delta t = 3.10 1{0^{ - 6}}mol {\left( {Ls} \right)^{ - 1}}\end{aligned}\)

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Iodine-131 is a radioactive isotope that is used to diagnose and treat some forms of thyroid cancer. Iodine-131 decays to xenon-131 according to the equation:I-131⟶Xe-131 + electron. The decay is first-order with a rate constant of 0.138 d−1. All radioactive decay is first order. How many days will it take for 90% of the iodine−131 in a 0.500 M solution of this substance to decay to Xe-131?

An elevated level of the enzyme alkaline phosphatase (ALP) in the serum is an indication of possible liver or bone disorder. The level of serum ALP is so low that it is very difficult to measure directly. However, ALP catalyzes a number of reactions, and its relative concentration can be determined by measuring the rate of one of these reactions under controlled conditions. One such reaction is the conversion of p-nitrophenyl phosphate (PNPP) to p-nitrophenoxide ion (PNP) and phosphate ion. Control of temperature during the test is very important; the rate of the reaction increases 1.47 times if the temperature changes from 30 °C to 37 °C. What is the activation energy for the ALP–catalyzed conversion of PNPP to PNP and phosphate?

Radioactive phosphorus is used in the study of biochemical reaction mechanisms because phosphorus atoms are components of many biochemical molecules. The location of the phosphorus (and the location of the molecule it is bound in) can be detected from the electrons (beta particles) it produces:

\(\begin{aligned}{l}_{{\bf{15}}}^{{\bf{32}}}{\bf{P}} \to _{{\bf{16}}}^{{\bf{32}}}{\bf{S + }}{{\bf{e}}^{\bf{ - }}}\\{\bf{rate = 4}}{\bf{.85 \times 1}}{{\bf{0}}^{{\bf{ - 2}}}}\,{\bf{da}}{{\bf{y}}^{{\bf{ - 1}}}}{{\bf{(}}^{{\bf{32}}}}{\bf{p)}}\end{aligned}\)

What is the instantaneous rate of production of electrons in a sample with a phosphorus concentration of \({\bf{0}}{\bf{.0033 M}}\)?

Hydrogen iodide, HI, decomposes in the gas phase to produce hydrogen, H2, and iodine, I2. The value of the rate constant, k, for the reaction was measured at several different temperatures, and the data are shown here:

Temperature(K)

k(M-1s-1)

555

6.23*10-7

575

2.42*10-6

645

1.44*10-4

700

2.01*10-3

What is the value of the activation energy (in kJ/mol) for this reaction?

Pure ozone decomposes slowly to oxygen,\({\bf{2}}{{\bf{O}}_{\bf{3}}}{\bf{(g)}} \to {\bf{3}}{{\bf{O}}_{\bf{2}}}{\bf{(g)}}\). Use the data provided in a graphical method and determine the order and rate constant of the reaction.

Time(hr)

0

2.0x103

7.6x 104

1.00x104

1.23x104

1.43x104

1.70x104

(O3) (M)

1.0x10-5

4.98x10-6

2.07x10-6

1.66x10-6

1.39x10-6

1.22x10-6

1.05x10-6

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free