If the initial concentration of butadiene is 0.0200 M, what is the concentration remaining after 20.0 min?

Short Answer

Expert verified

The concentration remaining after 20.0 min is 0.0196 mol/L.

Step by step solution

01

Rate of a Reaction

The rate of reaction may be defined as the speed of the reactant reacting to obtain a product in a particular reaction at a particular time. The concentration of the reactant and product are represented into mole/L.

Rate\({\bf{ = }}\,{\bf{k}}{\left( {\bf{A}} \right)^{\bf{m}}}{\left( {\bf{B}} \right)^{\bf{n}}}\)

02

Second-Order Reaction            \(\)

The second-order reaction depends on the one concentration having rate law,

\({\bf{Rate = k}}{\left( {\bf{A}} \right)^{\bf{2}}}\)

For second-order reactions, the rate equation is:

\({\bf{1 / }}\left( {\bf{A}} \right){\bf{ = kt + 1 / }}{\left( {\bf{A}} \right)_{\bf{0}}}\)

03

Explanation

For a second-order reaction, we have:

\({\bf{1 / }}\left( {\bf{A}} \right){\bf{ = kt + 1 / }}{\left( {\bf{A}} \right)_{\bf{0}}}\)

\({\left( {\bf{A}} \right)_{\bf{0}}}\)= 0.020 mol/L,

k = \({\bf{5}}{\bf{.76 \times 1}}{{\bf{0}}^{{\bf{ - 2}}}}{\bf{L}}{\left( {{\bf{molmin}}} \right)^{{\bf{ - 1}}}}\),

And t = 20.0 min.

\(\begin{aligned}{{}{}}{{\bf{1 / }}\left( {\bf{A}} \right){\bf{ = }}\left( {{\bf{5}}{\bf{.76 \times 1}}{{\bf{0}}^{{\bf{ - 2}}}}{\bf{L}}{{\left( {{\bf{molmin}}} \right)}^{{\bf{ - 1}}}}} \right){\bf{ }}\left( {{\bf{20 min}}} \right){\bf{ + 1 /0}}{\bf{.020 mol/L}}}\\{{\bf{1 / }}\left( {\bf{A}} \right){\bf{ = 0}}{\bf{.1152 + 50}}{\bf{.00}}}\\{{\bf{1 / }}\left( {\bf{A}} \right){\bf{ = 50}}{\bf{.1152}}}\\{{\bf{\;}}\,\,\,\,\,\,\left( {\bf{A}} \right){\bf{ = 1 / 50}}{\bf{.1152}}}\\{\,\,\,\,\,\,\left( {\bf{A}} \right){\bf{ = 0}}{\bf{.0196 mol/L}}}\end{aligned}\)

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

What is the half-life for the decomposition of NOCl when the concentration of NOCl is 0.15 M? The rate constant for this second-order reaction is \({\bf{8}}{\bf{.0 \times 1}}{{\bf{0}}^{{\bf{ - 8}}}}\)L/mol/s.

Nitrosyl chloride, NOCl, decomposes to NO and \({\bf{C}}{{\bf{l}}_{\bf{2}}}\).

\({\bf{2NOCl(g)}} \to {\bf{2NO(g) + C}}{{\bf{l}}_{\bf{2}}}{\bf{(g)}}\)

Determine the rate law, the rate constant, and the overall order for this reaction from the following data:

Account for the relationship between the rate of a reaction and its activation energy.

Iodine-131 is a radioactive isotope that is used to diagnose and treat some forms of thyroid cancer. Iodine-131 decays to xenon-131 according to the equation:I-131⟶Xe-131 + electron. The decay is first-order with a rate constant of 0.138 d−1. All radioactive decay is first order. How many days will it take for 90% of the iodine−131 in a 0.500 M solution of this substance to decay to Xe-131?

Given the following reactions and the corresponding rate laws, in which of the reactions might the elementary reaction and the overall reaction be the same?\(\begin{aligned}{\rm{(a) C}}{{\rm{l}}_2}{\rm{ + CO }} \to {\rm{ C}}{{\rm{l}}_2}{\rm{CO}}\\{\rm{rate = }}k{{\rm{(C}}{{\rm{l}}_2}{\rm{)}}^{\frac{3}{2}}}{\rm{(CO)}}\\{\rm{(b) PC}}{{\rm{l}}_3}{\rm{ + C}}{{\rm{l}}_{\rm{2}}}{\rm{ }} \to {\rm{ PC}}{{\rm{l}}_{\rm{5}}}\\{\rm{rate = }}k{\rm{(PC}}{{\rm{l}}_{\rm{3}}}{\rm{) (C}}{{\rm{l}}_{\rm{2}}}{\rm{)}}\\{\rm{(c) 2NO + }}{{\rm{H}}_{\rm{2}}}{\rm{ }} \to {\rm{ }}{{\rm{N}}_{\rm{2}}}{\rm{ + }}{{\rm{H}}_{\rm{2}}}{\rm{O}}\\{\rm{rate = }}k{\rm{(NO)(}}{{\rm{H}}_{\rm{2}}}{\rm{)}}\\{\rm{(d) 2NO + }}{{\rm{O}}_{\rm{2}}}{\rm{ }} \to {\rm{ 2N}}{{\rm{O}}_{\rm{2}}}\\{\rm{rate = }}k{{\rm{(NO)}}^{\rm{2}}}{\rm{(}}{{\rm{O}}_{\rm{2}}}{\rm{)}}\\{\rm{(e) NO + }}{{\rm{O}}_{\rm{3}}}{\rm{ }} \to {\rm{ N}}{{\rm{O}}_{\rm{2}}}{\rm{ + }}{{\rm{O}}_{\rm{2}}}\\{\rm{rate = }}k{\rm{(NO)(}}{{\rm{O}}_{\rm{3}}}{\rm{)}}\end{aligned}\)

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free