What is the half-life for the decomposition of NOCl when the concentration of NOCl is 0.15 M? The rate constant for this second-order reaction is \({\bf{8}}{\bf{.0 \times 1}}{{\bf{0}}^{{\bf{ - 8}}}}\)L/mol/s.

Short Answer

Expert verified

Half-life periods may be defined as the time period at which half the concentration of reactant converts into the product. The half-life period of the second-order decomposition of the NOCl is 93750000 years which has a rate constant \({\bf{8}}{\bf{.0 \times 1}}{{\bf{0}}^{{\bf{ - 8}}}}\)L/mol/s.

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Step by step solution

01

Reaction Rate

The reaction involved the effective collision of two reactants to produce the desired products. Reactions can be natural, which occur in the surrounding environment, whereas it can be artificially done in the laboratory to form a desired required product.

The reaction rate can be defined as the speed of reaction to produce the products. The reaction rate can be slow, fast or moderate. The reaction can take less than a millisecond to produce products, or it can take years to produce the desired product.

The half-life period can be defined as the time period at which half the concentration of the reactants gets converted into a product.

02

Explanation

The half-life period of the second-order decomposition of the NOCl is:

\({\bf{Half - life period = }}\frac{{\left( {\bf{A}} \right){\bf{^\circ }}}}{{{\bf{2k}}}}\)

Where \(\left( {\bf{A}} \right){\bf{^\circ }}\) = initial concentration of reactant

K = Rate constant

Initial concentration of reactant,\(\left( {\bf{A}} \right){\bf{^\circ }}\) =0.15 M

Rate constant for the decomposition of NOCl =\({\bf{8}}{\bf{.0 \times 1}}{{\bf{0}}^{{\bf{ - 8}}}}\) L/mol/s

\({\bf{Half - life period = }}\frac{{{\bf{0}}{\bf{.15}}}}{{{\bf{2 \times }}\left( {{\bf{8}}{\bf{.0 \times 1}}{{\bf{0}}^{{\bf{ - 8}}}}{\bf{yea}}{{\bf{r}}^{{\bf{ - 1}}}}} \right)}}\)

Half-life period = 93750000 years.

Therefore, the half-life period of the second-order decomposition of the NOCl is 93750000 years which has a rate constant is \({\bf{8}}{\bf{.0 \times 1}}{{\bf{0}}^{{\bf{ - 8}}}}\)L/mol/s.

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Most popular questions from this chapter

The reaction of \({\bf{CO}}\) with \({\bf{C}}{{\bf{l}}_{\bf{2}}}\) gives phosgene \(\left( {{\bf{COC}}{{\bf{l}}_{\bf{2}}}} \right)\), a nerve gas that was used in World War I. Use the mechanism shown here to complete the following exercises:(fast, \({{\bf{k}}_{\bf{1}}}\) represents the forward rate constant, \({k_{ - {\bf{1}}}}\)the reverse rate constant)\({\bf{CO}}\left( g \right){\rm{ }} + {\rm{ }}{\bf{Cl}}\left( g \right) \to {\bf{COCl}}\left( g \right)\)(slow, \({k_{\bf{2}}}\) the rate constant)\({\bf{COCl}}\left( g \right){\rm{ }} + {\rm{ }}{\bf{Cl}}\left( g \right) \to {\bf{COC}}{{\bf{l}}_{\bf{2}}}\left( g \right)\)(fast,\({k_{\bf{3}}}\)the rate constant)(a) Write the overall reaction.(b) Identify all intermediates.(c) Write the rate law for each elementary reaction.(d) Write the overall rate law expression.

Compare the functions of homogeneous and heterogeneous catalysts.

Use the provided initial rate data to derive the rate law for the reaction whose equation is: \({\bf{OC}}{{\bf{l}}^ - }\)(aq) + \({{\bf{I}}^ - }\)(aq) ⟶OI(aq) +\({\bf{C}}{{\bf{l}}^ - }\)(aq)

Trial

(\({\bf{OC}}{{\bf{l}}^ - }\)) (mol/L)

(\({{\bf{I}}^ - }\)) (mol/L)

Initial Rate (mol/L/s)

1.

0.0040

0.0020

0.00184

2.

0.0020

0.0040

0.00092

3.

0.0020

0.0020

0.00046

Determine the rate law expression and the value of the rate constant k with appropriate units for this reaction.

Consider this scenario and answer the following questions: Chlorine atoms resulting from decomposition of chlorofluoromethanes, such as \({\bf{CC}}{{\bf{l}}_{\bf{2}}}{{\bf{F}}_{\bf{2}}}\), catalyse the decomposition of ozone in the atmosphere. One simplified mechanism for the decomposition is:

\(\begin{aligned}{}{{\bf{O}}_{\bf{3}}}\overset{sunlight}{\rightarrow}{}{{\bf{O}}_{\bf{2}}}{\rm{ }} + {\rm{ }}{\bf{O}}\\{{\bf{O}}_{\bf{3}}}{\rm{ }} + {\rm{ }}{\bf{Cl}}\to {{\bf{O}}_{\bf{2}}}{\rm{ }} + {\rm{ }}{\bf{ClO}}\\{\bf{ClO}}{\rm{ }} + {\rm{ }}{\bf{O}}\to {\bf{Cl}}{\rm{ }} + {\rm{ }}{{\bf{O}}_{\bf{2}}}\end{aligned}\)

(a) Explain why chlorine atoms are catalysts in the gas-phase transformation:

\({\bf{2}}{{\bf{O}}_{\bf{3}}}\mathop {}\limits^{}\to {\bf{3}}{{\bf{O}}_{\bf{2}}}\)

(b) Nitric oxide is also involved in the decomposition of ozone by the mechanism: Is NO a catalyst for the decomposition? Explain your answer.

\(\begin{aligned}{}{{\bf{O}}_{\bf{3}}}\overset{sunlight}{\rightarrow}{\rm{ }}{{\bf{O}}_{\bf{2}}}{\rm{ }} + {\rm{ }}{\bf{O}}\\{{\bf{O}}_{\bf{3}}}{\rm{ }} + {\rm{ }}{\bf{NO}}\rightarrow {\bf{N}}{{\bf{O}}_{\bf{2}}}{\rm{ }} + {\rm{ }}{{\bf{O}}_{\bf{2}}}\\{\bf{N}}{{\bf{O}}_{\bf{2}}}{\rm{ }} + {\rm{ }}{\bf{O}}\rightarrow {\bf{NO}}{\rm{ }} + {\rm{ }}{{\bf{O}}_{\bf{2}}}\end{aligned}\)

Ozone decomposes to oxygen according to the equation\({\bf{2}}{{\bf{O}}_{\bf{3}}}{\bf{(g)}} \to {\bf{3}}{{\bf{O}}_{\bf{2}}}{\bf{(g)}}\). Write the equation that relates the rate expressions for this reaction in terms of the disappearance of\({{\bf{O}}_{\bf{3}}}\)and the formation of oxygen.

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