Chemical reactions occur when reactants collide. What are two factors that may prevent a collision from producing a chemical reaction?

Short Answer

Expert verified

Collision theory is a theory that is used to predict the rates of chemical reactions, particularly those involving gases. The collision theory holds that for a reaction to take place, the reacting species (atoms or molecules) must come into contact with one another.

Collision theory is founded on the following premises:

The reacting species must collide in such a way that contact between the atoms that will become bonded together in the product is possible.

The collision must have enough energy to allow mutual penetration of the valence of the reacting species. Shells, allowing electrons to rearrange and form new bonds (and new chemical species).

Step by step solution

01

Reaction of carbon monoxide with oxygen

Carbon monoxide is a pollutant that is produced during the combustion of hydrocarbon fuels. Automobiles have catalytic converters that use a catalyst to carry out this reaction to reduce this pollutant. It is also a byproduct of gunpowder combustion that causes muzzle flash in many firearms. At high temperatures and pressure, the reaction is spontaneous if sufficient amounts of carbon monoxide and oxygen are present.

The collision of two molecules is the first step in the gas-phase reaction of carbon monoxide and oxygen:

\({\bf{CO}}\left( {\bf{g}} \right){\bf{ + }}{{\bf{O}}_{\bf{2}}}\left( {\bf{g}} \right) \to {\bf{C}}{{\bf{O}}_{\bf{2}}}\left( {\bf{g}} \right){\bf{ + O}}\left( {\bf{g}} \right)\)

In the primary case, the oxygen aspect of the carbon monoxide molecule collides with the oxygen molecule.

02

Formation of carbon dioxide

In the second case, the carbon aspect of the carbon monoxide molecule collides with the oxygen molecule. The second case truly favors the formation of carbon dioxide (O = C = O), which has a crucial carbon atom bonded to 2 oxygen atoms. This is an easy example of ways critical collision orientation is in generating the favored response product. Two possible collisions between carbon monoxide and oxygen molecules. The orientation of the colliding molecules influences whether or not a reaction between the two molecules occurs.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

What is the rate equation for the elementary termolecular reaction A + 2B⟶products? For 3A⟶products?

The rate constant for the radioactive decay of 14C is \({\bf{1}}{\bf{.21 \times 1}}{{\bf{0}}^{{\bf{ - 4}}}}{\bf{ yea}}{{\bf{r}}^{{\bf{ - 1}}}}\). The products of the decay are nitrogen atoms and electrons (beta particles): \(\begin{aligned}{}_{\bf{6}}^{{\bf{14}}}{\bf{C}} \to _{\bf{6}}^{{\bf{14}}}{\bf{N + }}{{\bf{e}}^{\bf{ - }}}\\{\bf{rate = k(}}_{\bf{6}}^{{\bf{14}}}{\bf{C)}}\end{aligned}\).

What is the instantaneous rate of production of N atoms in a sample with a carbon-14 content of \({\bf{ 6}}{\bf{.5 \times 1}}{{\bf{0}}^{{\bf{ - 9 }}}}{\bf{M}}\)?

:How does an increase in temperature affect rate of reaction? Explain this effect in terms of the collision theory of the reaction rate

The rate constant at 325°C for the decomposition reaction \({{\bf{C}}_{\bf{4}}}{{\bf{H}}_{\bf{8}}} \to {\bf{2}}{{\bf{C}}_{\bf{2}}}{{\bf{H}}_{\bf{4}}}\)is 6.1 × 10−8 s−1, and the activation energy is 261 kJ per mole of\({{\bf{C}}_{\bf{4}}}{{\bf{H}}_{\bf{8}}}\). Determine the frequency factor for the reaction.

Consider the following reaction in aqueous solution:

\(\)

\({\bf{5B}}{{\bf{r}}^ - }\left( {aq} \right) + BrO_3^ - \left( {aq} \right) + 6{H^ + }\left( {aq} \right) \to 3B{r_2}\left( {aq} \right) + 3{H_2}O\left( l \right)\)

If the rate of disappearance of Br (aq) at a particular moment during the reaction is 3.5 × 10−4 M s −1, what is the rate of appearance of\({\bf{B}}{{\bf{r}}_{\bf{2}}}\)(aq) at that moment?

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free