Account for the relationship between the rate of a reaction and its activation energy.

Short Answer

Expert verified

The rate of reaction depends upon the activation energy; as the activation energy is high reaction rate is low, whereas if the activation energy is low, the reaction rate is high.

Step by step solution

01

Reaction Rate

The reaction involved the effective collision of two reactants to produce the desired products. Reactions can be natural, which occur in the surrounding environment, whereas it can be artificially done in the laboratory to form the desired product.

The reaction rate can be defined as the reaction speed to produce the products. The reaction rate can be slow, fast or moderate. The reaction can take less than a millisecond to produce products, or it can take years to produce the desired product.

02

Activation Energy

'Activation energy' term was used by Svante Arrhenius, a Swedish scientist, in the year 1889. The activation energy can be defined as the threshold energy (which is called the minimum amount of energy) after which the reaction takes place. A chemical reaction can take place because of the effective collision of the two or more reactants, which produces energy more than the threshold energy (minimum energy).

The unit of the Activation energy is Joule or kcal/mole.

03

Relation between Activation energy and Reaction rate

The rate of the reaction depends upon the Activation energy. As the activation energy is high, then the reaction rate is low, whereas if the activation energy is low, then the reaction rate is high. Activation energy can be defined as the “barrier” which is crossed by the reactant to produce products.

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Most popular questions from this chapter

The half-life of a reaction of compound A to give compounds D and E is 8.50 min when the initial concentration of A is 0.150 mol/L. How long will it take for the concentration to drop to 0.0300 mol/L if the reaction is (a) first order with respect to A or (b) second order with respect to A?

:How does an increase in temperature affect rate of reaction? Explain this effect in terms of the collision theory of the reaction rate

Given the following reactions and the corresponding rate laws, in which of the reactions might the elementary reaction and the overall reaction be the same?\(\begin{aligned}{\rm{(a) C}}{{\rm{l}}_2}{\rm{ + CO }} \to {\rm{ C}}{{\rm{l}}_2}{\rm{CO}}\\{\rm{rate = }}k{{\rm{(C}}{{\rm{l}}_2}{\rm{)}}^{\frac{3}{2}}}{\rm{(CO)}}\\{\rm{(b) PC}}{{\rm{l}}_3}{\rm{ + C}}{{\rm{l}}_{\rm{2}}}{\rm{ }} \to {\rm{ PC}}{{\rm{l}}_{\rm{5}}}\\{\rm{rate = }}k{\rm{(PC}}{{\rm{l}}_{\rm{3}}}{\rm{) (C}}{{\rm{l}}_{\rm{2}}}{\rm{)}}\\{\rm{(c) 2NO + }}{{\rm{H}}_{\rm{2}}}{\rm{ }} \to {\rm{ }}{{\rm{N}}_{\rm{2}}}{\rm{ + }}{{\rm{H}}_{\rm{2}}}{\rm{O}}\\{\rm{rate = }}k{\rm{(NO)(}}{{\rm{H}}_{\rm{2}}}{\rm{)}}\\{\rm{(d) 2NO + }}{{\rm{O}}_{\rm{2}}}{\rm{ }} \to {\rm{ 2N}}{{\rm{O}}_{\rm{2}}}\\{\rm{rate = }}k{{\rm{(NO)}}^{\rm{2}}}{\rm{(}}{{\rm{O}}_{\rm{2}}}{\rm{)}}\\{\rm{(e) NO + }}{{\rm{O}}_{\rm{3}}}{\rm{ }} \to {\rm{ N}}{{\rm{O}}_{\rm{2}}}{\rm{ + }}{{\rm{O}}_{\rm{2}}}\\{\rm{rate = }}k{\rm{(NO)(}}{{\rm{O}}_{\rm{3}}}{\rm{)}}\end{aligned}\)

If the rate of decomposition of ammonia, \({\bf{N}}{{\bf{H}}_{\bf{3}}}\), at 1150 K is \(2.10 \times 1{0^{ - 6}}mol/L/s\), what is the rate of production of nitrogen and hydrogen?

Go to the PhET Reactions & Rates interactive. Use the Single Collision tab to represent how the collision between monatomic oxygen (O) and carbon monoxide (CO) results in the breaking of one bond and the formation of another. Pull back on the red plunger to release the atom and observe the results. Then, click on “Reload Launcher” and change to “Angled shot” to see the difference.

  1. What happens when the angle of the collision is changed?
  2. Explain how this is relevant to rate of reaction.
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