For each of the following pairs of reaction diagrams, identify which of the pairs iscatalyzed:

Short Answer

Expert verified

(a) Reaction diagram (b) is a catalyzed reaction.

(b) Reaction diagram (b) is a catalyzed reaction.

Step by step solution

01

Definition of Catalyst

Catalysts are substances which increase the rate of the reaction without getting used up by themselves while decreasing the activation energy of the reaction.

  • A catalyst increases the rate of reaction.
  • Catalyst accelerates the rate of a reaction by decreasing the activation energy.
  • Catalysts may provide different reaction mechanisms involving extra steps in the reaction and lower the activation energy, simultaneously increasing the reaction rate.
  • Catalyst is regenerated during the reaction.
02

(a) Reaction diagram (b) uses a catalyst

  1. The two reaction diagrams depict the same reaction, one with a catalyst and another without a catalyst.
  2. The two reaction diagrams depict a two-step reaction mechanism involving two transition states.
  3. We can also notice an intermediate species between the two transition states.
  4. But a small change is observed in the second transition state, which is lower in diagram (b) than in diagram (a). This indicates the presence of a catalyst in diagram (b).
03

(b) Reaction diagram (b) uses a catalyst 

  1. The two reaction diagrams depict the same reaction, one with a catalyst and another without a catalyst.
  2. The two reaction diagrams depict two-step reaction mechanisms involving two transition states.
  3. But a small change is observed in the first transition state, which is lower in diagram (b) than in diagram (a). This indicates the presence of a catalyst in diagram (b).

Thus, the reaction diagram (b) is catalyzed among both pairs of the reaction diagrams (a) and (b).

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

What is the half-life for the first-order decay of phosphorus-32?\(_{{\bf{15}}}^{{\bf{32}}}{\bf{P}} \to _{{\bf{16}}}^{{\bf{32}}}{\bf{S + }}{{\bf{e}}^{\bf{ - }}}\)The rate constant for the decay is\({\bf{4}}{\bf{.85 \times 1}}{{\bf{0}}^{{\bf{ - 2}}}}{\bf{da}}{{\bf{y}}^{{\bf{ - 1}}}}\).

Iodine-131 is a radioactive isotope that is used to diagnose and treat some forms of thyroid cancer. Iodine-131 decays to xenon-131 according to the equation:I-131⟶Xe-131 + electron. The decay is first-order with a rate constant of 0.138 d−1. All radioactive decay is first order. How many days will it take for 90% of the iodine−131 in a 0.500 M solution of this substance to decay to Xe-131?

The decomposition of acetaldehyde is a second-order reaction with a rate constant of \({\bf{4}}{\bf{.71 \times 1}}{{\bf{0}}^{{\bf{ - 8 }}}}{\bf{L mo}}{{\bf{l}}^{{\bf{ - 1}}}}{\bf{ s}}{{\bf{ }}^{{\bf{ - 1}}}}\). What is the instantaneous rate of decomposition of acetaldehyde in a solution with a concentration of \({\bf{5}}{\bf{.55 \times 1}}{{\bf{0}}^{{\bf{ - 4}}}}{\bf{M}}\)?

The element Co exists in two oxidation states, Co(II) and Co(III), and the ions form many complexes. The rate at which one of the complexes of Co(III) was reduced by Fe(II) in water was measured. Determine the activation energy of the reaction from the following data:

Temperature(K)

k(s-1)

293

0.054

298

0.100

For the reaction\({\bf{A}} \to {\bf{B + C}}\), the following data were obtained at 30 °C:

  1. What is the order of the reaction with respect to (A), and what is the rate law?
  2. What is the rate constant?
See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free