Chapter 10: Q10.4-58 E (page 589)
Determine the phase changes that carbon dioxide undergoes as the pressure changes if the temperature is held at −50°C? If the temperature is held at −40°C? At 20°C?
Short Answer
If the temperature is constant at\(\left( {{\rm{ - 5}}{{\rm{0}}^{\rm{^\circ }}}{\rm{C}}} \right){\rm{,C}}{{\rm{O}}_{\rm{2}}}\)will be:
- gaseous if the pressure is approximately 10-700 kPa
- liquid if the pressure is approximately\({\rm{700 - 200,000kPa}}\)
-solid if the pressure is higher than\({\rm{200,000kPa}}\)
If the temperature is constant at\(\left( {{\rm{ - 4}}{{\rm{0}}^{\rm{^\circ }}}{\rm{C}}} \right){\rm{,C}}{{\rm{O}}_{\rm{2}}}\)will be:
- gaseous if the pressure is approximately 10-1000 kPa
- liquid if the pressure is approximately\({\rm{1000 - 400,000kPa}}\)
-solid if the pressure is higher than\({\rm{400,000kPa}}\)
If the temperature is constant at\(\left( {{\rm{2}}{{\rm{0}}^{\rm{^\circ }}}{\rm{C}}} \right){\rm{,C}}{{\rm{O}}_{\rm{2}}}\)will be:
- gaseous if the pressure is approximately\({\rm{10 - 9000kPa}}\)
- liquid if the pressure is approximately\({\rm{9000 - 900,000}}\,{\rm{kPa}}\)
-solid if the pressure is higher than\({\rm{900,000}}\,{\rm{kPa}}\)