Determine the oxidation state of the elements in the following compounds:

(a)\(NaI\)

(b)\(GdC{l_3}\)

(c)\(LiN{O_3}\)

(d)\({H_2}Se\)

(e)\(M{g_2}Si\)

(f)\(Rb{O_2}\), rubidium superoxide

(g)\(HF\)

Short Answer

Expert verified

Oxidation state of the abovementioned elements:

  1. \(Na\left( { + 1} \right),I\left( { - 1} \right)\)
  2. \(Gd\left( { + 3} \right),Cl\left( { - 1} \right)\)
  3. \(Li\left( { + 1} \right),N\left( { + 5} \right),O\left( { - 2} \right)\)
  4. \(H\left( { + 1} \right),Se\left( { - 2} \right)\)
  5. \(Mg\left( { + 2} \right),Si\left( { - 4} \right)\)
  6. \(Rb\left( { + 1} \right),O\left( { - \frac{1}{2}} \right)\)
  7. \(H\left( { + 1} \right),F\left( { - 1} \right)\)

Step by step solution

01

Determine oxidation states in part (a)

Consider the iodine oxidation number (-1) in (a).

Hence the oxidation state of sodium \(\left( x \right)\)is +1.

\(\begin{aligned}{}x - 1 &= 0\\x &= + 1\end{aligned}\)

02

Determine oxidation states in part (b)

Consider the chlorine oxidation number(-1) in (b).

The oxidation state of gadolinium\(\left( x \right)\) is calculated as below:

\(\begin{aligned}{}3 \times \left( { - 1} \right) + x& = 0\\x &= + 3\end{aligned}\)

Hence the oxidation state of gadolinium is +3.

03

Determine oxidation states in part (c)

Consider theoxidation number of oxygen (-2) and lithium (+1) in (c).

The oxidation state of nitrogen\(\left( x \right)\) is as calculated below:

\(\begin{aligned}{l}1 \times ( + 1) + 3 \times ( - 2) + x &= 0\\x &= + 5\end{aligned}\)

Hence the oxidation state of nitrogen is +5.

04

Determine oxidation states in part (d)

Consider the oxidation number of hydrogen (+1) in compound (d).

The oxidation number of selenium \(\left( x \right)\)is therefore -2.

\(\begin{aligned}{}2 \times ( + 1) + x &= 0\\x &= - 2\end{aligned}\)

05

Determine oxidation states in part (e)

Consider the oxidation number of magnesium (+2) in (e).

The oxidation number of silicon\(\left( x \right)\)is therefore - 4.

\(\begin{aligned}{}2 \times ( + 2) + x &= 0\\x &= - 4\end{aligned}\)

06

Determine oxidation states in part (f)

Consider the oxidation number of oxygen (-1/2) for superoxide in(f).

The oxidation number of rubidium \(\left( x \right)\)is therefore +1.

\(\begin{aligned}{}2 \times ( - \frac{1}{2}) + x & = 0\\x &= + 1\end{aligned}\)

07

Determine oxidation states in part (g)

Consider the oxidation number of fluorine, which is always -1.

Therefore, the oxidation number of hydrogen\(\left( x \right)\)has to be +1.

\(\begin{aligned}{}1 \times ( - 1) + x &= 0\\x &= + 1\end{aligned}\)

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Most popular questions from this chapter

The reaction of WCl6 with Al at ~4000C gives black crystals of a compound containing only tungsten and chlorine. A sample of this compound, when reduced with hydrogen, gives 0.2232 g of tungsten metal and hydrogen chloride, which is absorbed in water. Titration of the hydrochloric acid thus produced requires 46.2 mL of 0.1051 M NaOH to reach the end point. What is the empirical formula of the black tungsten chloride?

Identify the atoms that are oxidized and reduced, the change in the oxidation state for each, and the oxidizing and reducing agents in each of the following equations:

(a)\(Mg\left( s \right) + NiC{l_2}\left( {aq} \right) \to MgC{l_2}\left( {aq} \right) + Ni\left( s \right)\)

(b)\(PC{l_3}\left( l \right) + C{l_2}\left( g \right) \to PC{l_5}\left( s \right)\)

(c)\({C_2}{H_4}\left( g \right) + 3{O_2}\left( g \right) \to 2C{O_2}\left( g \right) + 2{H_2}O\left( g \right)\)

(d)\(Zn\left( s \right) + {H_2}S{O_4}\left( {aq} \right) \to ZnS{O_4}\left( {aq} \right) + {H_2}\left( g \right)\)

(e) \(2{K_2}{S_2}{O_3}\left( s \right) + {I_2}\left( s \right) \to {K_2}{S_4}{O_6}\left( s \right) + 2KI\left( s \right)\)

(f) \(3Cu\left( s \right) + 8HN{O_3}\left( {aq} \right) \to 3Cu{\left( {N{O_3}} \right)_2}\left( {aq} \right) + 2NO\left( g \right) + 4{H_2}O\left( l \right)\)

What volume of a 0.00945 M solution of potassium hydroxide would be required to titrate 50.00 mL of a sample of acid rain with a H2SO4 concentration of 1.23×10-4M

\({{\rm{H}}_2}{\rm{S}}{{\rm{O}}_{4({\rm{aq}})}}{\rm{ + 2KO}}{{\rm{H}}_{({\rm{aq}})}}{\rm{ }} \to {\rm{ }}{{\rm{K}}_2}{\rm{S}}{{\rm{O}}_{4({\rm{aq}})}}{\rm{ + 2}}{{\rm{H}}_2}{{\rm{O}}_{{\rm{(l)}}}}\)

Outline the steps needed to solve the following problem, then do the calculations. Ether,\({\left( {{C_2}{H_5}} \right)_2}O\), which was originally used as an anesthetic but has been replaced by safer and more effective medications, is prepared by the reaction of ethanol with sulfuric acid.\(2{C_2}{H_5}OH + {H_2}S{O_4} \to \left( {{C_2}{H_5}} \right)2O + {H_2}S{O_4} \cdot {H_2}O\)What is the percent yield of ether if 1.17 L (d = 0.7134 g/mL) is isolated from the reaction of 1.500 L of C2H5OH (d = 0.7894 g/mL)?

Complete and balance the following acid-base equations:

(a) A solution ofHClO4 is added to a solution of LiOH

(b) AqueousH2SO4 reacts withNaOH

(c)Ba(OH)2reacts withHF gas.

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