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Chapter 19: Q.7E (page 1092)
Which of the following elements is most likely to form an oxide with the formula\(M{O_3}\): Zr, Nb, or Mo?
\(Mo\), is most likely to form an oxide with the formula \(M{O_3}\).
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Predict whether the carbonate ligand \(C{O_3}^2\)- will coordinate to a metal center as a monodentate, bidentate, or tridentate ligand.
How many cubic feet of air at a pressure of 760 torr and 0 °C is required per ton of \(F{e_2}{O_3}\)to convert that \(F{e_2}{O_3}\)into iron in a blast furnace? For this exercise, assume air is 19% oxygen by volume.
Describe the electrolytic process for refining copper.
Sketch the structures of the following complexes. Indicate any cis, trans, and optical isomers.
\(\begin{aligned}{}(a)\left( {Pt{{\left( {{H_2}O} \right)}_2}B{r_2}} \right)\\(b)\left( {Pt\left( {N{H_3}} \right)(py)(Cl)(Br)} \right)\\(c)\left( {Zn{{\left( {N{H_3}} \right)}_3}Cl} \right)\\(d){\left( {Pt{{\left( {N{H_3}} \right)}_3}Cl} \right)^ + }\\(e)\left( {Ni{{\left( {{H_2}O} \right)}_4}C{l_2}} \right)\\(f){\left( {Co{{\left( {{C_2}{O_4}} \right)}_2}C{l_2}} \right)^{3 - }}\end{aligned}\)
How many unpaired electrons are present in each of the following?
\(\begin{aligned}{}(a){\left( {Co{F_6}} \right)^{3 - }}(highspin)\\(b){\left( {Mn{{(CN)}_6}} \right)^{3 - }}(lowspin)\\(c){\left( {Mn{{(CN)}_6}} \right)^{4 - }}(lowspin)\\(d){\left( {MnC{l_6}} \right)^{4 - }}(highspin)\\(e){\left( {RhC{l_6}} \right)^{3 - }}(lowspin)\end{aligned}\)
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