Write the ionization expression and the \(K_{b}\) expression for \(0.1 M\) aqueous solutions of the following bases. (a) \(\mathrm{F}^{-}\) (b) \(\mathrm{HCO}_{3}^{-}\) (c) \(\mathrm{CN}^{-}\)

Short Answer

Expert verified
Question: Determine the ionization reactions and the \(K_b\) expressions for the following bases in water: F⁻, \(\mathrm{HCO}_{3}^{-}\), and \(\mathrm{CN}^{-}\). Answer: a) For F⁻, the ionization reaction is given by \(\mathrm{F}^{-} + \mathrm{H}_{2}\mathrm{O} \rightleftharpoons \mathrm{HF} + \mathrm{OH}^{-}\), with \(K_{b} = \frac{[\mathrm{HF}][\mathrm{OH}^{-}]}{[\mathrm{F}^{-}]}\). b) For \(\mathrm{HCO}_{3}^{-}\), the ionization reaction is given by \(\mathrm{HCO}_{3}^{-} + \mathrm{H}_{2}\mathrm{O} \rightleftharpoons \mathrm{H}_{2}\mathrm{CO}_{3} + \mathrm{OH}^{-}\), with \(K_{b} = \frac{[\mathrm{H}_{2}\mathrm{CO}_{3}][\mathrm{OH}^{-}]}{[\mathrm{HCO}_{3}^{-}]}\). c) For \(\mathrm{CN}^{-}\), the ionization reaction is given by \(\mathrm{CN}^{-} + \mathrm{H}_{2}\mathrm{O} \rightleftharpoons \mathrm{HCN} + \mathrm{OH}^{-}\), with \(K_{b} = \frac{[\mathrm{HCN}][\mathrm{OH}^{-}]}{[\mathrm{CN}^{-}]}\).

Step by step solution

01

a) F⁻ ionization and \(K_{b}\) expression

Step 1: Write the ionization reaction in water for F⁻ \(\mathrm{F}^{-} + \mathrm{H}_{2}\mathrm{O} \rightleftharpoons \mathrm{HF} + \mathrm{OH}^{-}\) Step 2: Write the \(K_{b}\) expression for the ionization For the equilibrium reaction, the \(K_{b}\) expression can be written as: \(K_{b} = \frac{[\mathrm{HF}][\mathrm{OH}^{-}]}{[\mathrm{F}^{-}]}\) #a)end#
02

b) \(\mathrm{HCO}_{3}^{-}\) ionization and \(K_{b}\) expression

Step 1: Write the ionization reaction in water for \(\mathrm{HCO}_{3}^{-}\) \(\mathrm{HCO}_{3}^{-} + \mathrm{H}_{2}\mathrm{O} \rightleftharpoons \mathrm{H}_{2}\mathrm{CO}_{3} + \mathrm{OH}^{-}\) Step 2: Write the \(K_{b}\) expression for the ionization For the equilibrium reaction, the \(K_{b}\) expression can be written as: \(K_{b} = \frac{[\mathrm{H}_{2}\mathrm{CO}_{3}][\mathrm{OH}^{-}]}{[\mathrm{HCO}_{3}^{-}]}\) #b)end#
03

c) \(\mathrm{CN}^{-}\) ionization and \(K_{b}\) expression

Step 1: Write the ionization reaction in water for \(\mathrm{CN}^{-}\) \(\mathrm{CN}^{-} + \mathrm{H}_{2}\mathrm{O} \rightleftharpoons \mathrm{HCN} + \mathrm{OH}^{-}\) Step 2: Write the \(K_{b}\) expression for the ionization For the equilibrium reaction, the \(K_{b}\) expression can be written as: \(K_{b} = \frac{[\mathrm{HCN}][\mathrm{OH}^{-}]}{[\mathrm{CN}^{-}]}\) #c)end# By following these steps, we have determined the ionization reactions and the \(K_b\) expressions for aqueous solutions of the bases F⁻, \(\mathrm{HCO}_{3}^{-}\), and \(\mathrm{CN}^⁻\).

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