Chapter 13: Problem 63
Write the ionization expression and the \(K_{b}\) expression for \(0.1 M\) aqueous solutions of the following bases. (a) \(\mathrm{F}^{-}\) (b) \(\mathrm{HCO}_{3}^{-}\) (c) \(\mathrm{CN}^{-}\)
Chapter 13: Problem 63
Write the ionization expression and the \(K_{b}\) expression for \(0.1 M\) aqueous solutions of the following bases. (a) \(\mathrm{F}^{-}\) (b) \(\mathrm{HCO}_{3}^{-}\) (c) \(\mathrm{CN}^{-}\)
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Get started for freeAscorbic acid, \(\mathrm{H}_{2} \mathrm{C}_{6} \mathrm{H}_{6} \mathrm{O}_{6}\), also known as vitamin \(\mathrm{C}\), is present in many citrus fruits. It is a diprotic acid with the following \(K_{\mathrm{a}}\) values: \(K_{\mathrm{al}}=7.9 \times 10^{-5}\); \(K_{\mathrm{a} 2}=1.6 \times 10^{-12}\). What is the \(\mathrm{pH}\) of a \(0.63 \mathrm{M}\) solution of ascorbic acid? Estimate \(\left[\mathrm{HC}_{6} \mathrm{H}_{6} \mathrm{O}_{6}^{-}\right]\) and \(\left[\mathrm{C}_{6} \mathrm{H}_{6} \mathrm{O}_{6}{ }^{2-}\right]\).
Calculate \(\left[\mathrm{H}^{+}\right]\) and \(\left[\mathrm{OH}^{-}\right]\) in solutions with the following \(\mathrm{pH}\). (a) \(9.0\) (b) \(3.20\) (c) \(-1.05\) (d) \(7.46\)
Rank the following solutions in order of increasing \(\left[\mathrm{H}^{+}\right]\). \(\begin{array}{llll}0.1 & M \mathrm{HBr}, & 0.1 \mathrm{M} \mathrm{HF}, & 0.1 \mathrm{MHCHO}_{2} & 0.1 \mathrm{MHCN}\end{array}\)
At \(25^{\circ} \mathrm{C}\), a \(0.20 \mathrm{M}\) solution of methylamine \(\left(\mathrm{CH}_{3} \mathrm{NH}_{2}\right)\) is \(5.0 \%\) ionized. What is \(K_{b}\) for methylamine?
According to the Bronsted-Lowry theory, which of the following would you expect to act as an acid? Which as a base? (a) \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{NH}_{3}{ }^{+}\) (b) \(\mathrm{HClO}\) (c) \(\mathrm{CN}^{-}\)
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