Chapter 15: Problem 30
Follow the directions of Question 29 for (a) \(\mathrm{Mo}^{3+}\) (b) \(\mathrm{Pd}^{4+}\)
Chapter 15: Problem 30
Follow the directions of Question 29 for (a) \(\mathrm{Mo}^{3+}\) (b) \(\mathrm{Pd}^{4+}\)
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Get started for free\(\mathrm{MnF}_{6}{ }^{2-}\) has a crystal field splitting energy, \(\Delta_{0}\) of \(2.60 \times 10^{2} \mathrm{~kJ} / \mathrm{mol}\). What is the wavelength responsible for this energy?
Consider three complexes of \(\mathrm{Ag}^{+}\) and their formation constants, \(K_{\mathrm{f}}\) $$\begin{array}{ll}\hline \text { Complex lon } & K_{\mathrm{f}} \\\\\hline \mathrm{Ag}\left(\mathrm{NH}_{3}\right)_{2}+ & 1.6 \times 10^{7} \\ \mathrm{Ag}(\mathrm{CN})_{2}^{-} & 5.6 \times 10^{18} \\\\\mathrm{AgBr}_{2}^{-} & 1.3 \times 10^{7} \\ \hline\end{array}$$ Which statements are true? (a) \(\mathrm{Ag}\left(\mathrm{NH}_{3}\right)_{2}{ }^{+}\) is more stable than \(\mathrm{Ag}(\mathrm{CN})_{2}^{-}\). (b) Adding a strong acid \(\left(\mathrm{HNO}_{3}\right)\) to a solution that is \(0.010 \mathrm{M}\) in \(\mathrm{Ag}\left(\mathrm{NH}_{3}\right)_{2}^{+}\) will tend to dissociate the complex ion into \(\mathrm{Ag}^{+}\) and \(\mathrm{NH}_{4}^{+} .\) (c) Adding a strong acid \(\left(\mathrm{HNO}_{3}\right)\) to a solution that is \(0.010 \mathrm{M}\) in \(\mathrm{AgBr}_{2}^{-}\) will tend to dissociate the complex ion into \(\mathrm{Ag}^{+}\) and \(\mathrm{Br}^{-} .\) (d) To dissolve AgI, one can add either \(\mathrm{NaCN}\) or \(\mathrm{HCN}\) as a source of the cyanide-complexing ligand. Fewer moles of NaCN would be required. (e) Solution \(A\) is \(0.10 M\) in \(B r^{-}\) and contains the complex ion \(\mathrm{AgBr}_{2}^{-}\). Solution B is \(0.10 M\) in \(\mathrm{CN}^{-}\) and contains the complex ion \(\mathrm{Ag}(\mathrm{CN})_{2}-\). Solution B will have more particles of complex ion per particle of \(\mathrm{Ag}^{+}\) than solution \(\mathrm{A}\).
Oxyhemoglobin is red, and hemoglobin is blue. Use Le Châtelier's principle to explain why venous blood is blue and arterial blood is bright red.
WEB Indicate whether each of the following is true or false. If the statement is false, correct it. (a) The coordination number of iron(III) in \(\mathrm{Fe}\left(\mathrm{NH}_{3}\right)_{4}(\mathrm{en})^{3+}\) is 5 . (b) \(\mathrm{Ni}(\mathrm{CN})_{6}^{4-}\) is expected to absorb at a longer wavelength than \(\mathrm{Ni}\left(\mathrm{NH}_{3}\right)_{6}{ }^{2+}\)
There are four iron atoms in each hemoglobin molecule. The mass percent of iron in a hemoglobin molecule is \(0.35 \%\). Estimate the molar mass of hemoglobin.
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