Chapter 16: Problem 9
Fill in the blanks in the following table. (a) \(\mathrm{CoCO}_{3}\) (b) \(\mathrm{LaF}_{3}\) (c) \(\mathrm{Ba}_{3}\left(\mathrm{PO}_{4}\right)_{2}\)
Chapter 16: Problem 9
Fill in the blanks in the following table. (a) \(\mathrm{CoCO}_{3}\) (b) \(\mathrm{LaF}_{3}\) (c) \(\mathrm{Ba}_{3}\left(\mathrm{PO}_{4}\right)_{2}\)
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Get started for freeA solution is made up by adding \(0.925 \mathrm{~g}\) of silver(I) nitrate and \(6.25 \mathrm{~g}\) of magnesium nitrate to enough water to make \(375 \mathrm{~mL}\) of solution. Solid sodium carbonate is added without changing the volume of the solution. (a) Which salt, \(\mathrm{Ag}_{2} \mathrm{CO}_{3}\) or \(\mathrm{MgCO}_{3}\), will precipitate first? (b) What is the concentration of the carbonate ion when the first salt starts to precipitate?
Consider the following solubility data for calcium oxalate \(\left(\mathrm{Ca} \mathrm{C}_{2} \mathrm{O}_{4}\right)\) : $$ \begin{aligned} &K_{s p} \text { at } 25^{\circ} \mathrm{C}=4 \times 10^{-9} \\ &K_{s p} \text { at } 95^{\circ} \mathrm{C}=1 \times 10^{-8} \end{aligned} $$ Five hundred mL of a saturated solution is prepared at \(95^{\circ} \mathrm{C}\). How many milligrams of \(\mathrm{CaC}_{2} \mathrm{O}_{4}\) will precipitate when the solution is cooled to \(25^{\circ} \mathrm{C}\) ? (Assume that supersaturation does not take place.)
Write an overall net ionic equation and calculate \(K\) for the reaction where \(\mathrm{CuCl}\left(K_{s p}=1.9 \times 10^{-7}\right)\) is dissolved by \(\mathrm{NaCN}\) to form \(\left[\mathrm{Cu}(\mathrm{CN})_{2}\right]^{-}\) \(\left(K_{f}=1.0 \times 10^{16}\right)\).
Cadmium(II) chloride is added to a solution of potassium hydroxide with a \(\mathrm{pH}\) of \(9.62 .\left(K_{\mathrm{sp}} \mathrm{Cd}(\mathrm{OH})_{2}=2.5 \times 10^{-14}\right)\) (a) At what concentration of \(\mathrm{Cd}^{2+}\) does a precipitate first start to form? (b) Enough cadmium(II) chloride is added to make [Cd \(\left.^{2+}\right]=\) \(0.0013 M\). What is the \(\mathrm{pH}\) of the resulting solution? (c) What percentage of the original hydroxide ion is left in solution?
Predict what effect each of the following has on the position of the equilibrium $$ \mathrm{PbCl}_{2}(s) \rightleftharpoons \mathrm{Pb}^{2+}(a q)+2 \mathrm{Cl}^{-}(a q) \quad \Delta H=23.4 \mathrm{~kJ} $$ (a) addition of \(1 \mathrm{M} \mathrm{Pb}\left(\mathrm{NO}_{3}\right)_{2}\) solution (b) increase in temperature (c) addition of \(\mathrm{Ag}^{+}\), forming \(\mathrm{AgCl}\) (d) addition of \(1 M\) hydrochloric acid
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