Chapter 19: Problem 41
Which has the larger binding energy, fluorine- 19 or oxygen-17?
Chapter 19: Problem 41
Which has the larger binding energy, fluorine- 19 or oxygen-17?
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Get started for freeTo determine the \(K_{s p}\) value of \(\mathrm{Hg}_{2} \mathrm{I}_{2}\), a solid sample is used, in which some of the iodine is present as radioactive I-131. The count rate of the sample is \(5.0 \times 10^{11}\) counts per minute per mole of \(\mathrm{I}\). An excess amount of \(\mathrm{Hg}_{2} \mathrm{I}_{2}(s)\) is placed in some water, and the solid is allowed to come to equilibrium with its respective ions. A 150.0-mL sample of the saturated solution is withdrawn and the radioactivity measured at 33 counts per minute. From this information, calculate the \(K_{s p}\) value for \(\mathrm{Hg}_{2} \mathrm{I}_{2}\).
The cleavage of ATP (adenosine triphosphate) to ADP (adenosine diphosphate) and \(\mathrm{H}_{3} \mathrm{PO}_{4}\) may be written as follows: It is interesting to determine which bond (the \(\mathrm{P}-\mathrm{O}\) bond marked a or the \(\mathrm{O}\) - \(\mathrm{P}\) bond marked \(\mathbf{b}\) ) is cleaved by hydrolysis (reaction with water). (a) Outline an experiment (using radioactivity) that can be used to determine where the cleavage results. (b) Describe the results that would lead you to conclude that cleavage results at a, (c) Describe the results that would lead you to conclude that cleavage results at \(\mathbf{b}\). Results show that the cleavage occurs at \(\mathrm{b}\).
A rock from an archaeological dig was found to contain \(0.255 \mathrm{~g}\) of Pb-206 per gram of U-238. Assume that the rock did not contain any Pb-206 at the time of its formation and that U-238 decayed only to Pb-206. How old is the rock? (For \(\mathrm{U}-238, t_{1 / 2}=4.5 \times 10^{9} \mathrm{y}\).)
It is possible to estimate the activation energy for fusion by calculating the energy required to bring two deuterons close enough to one another to form an alpha particle. This energy can be obtained by using Coulomb's law in the form \(E=8.99 \times 10^{9} q_{1} q_{2} / r\), where \(q_{1}\) and \(q_{2}\) are the charges of the deuterons \(\left(1.60 \times 10^{-19} \mathrm{C}\right), r\) is the radius of the He nucleus, about \(2 \times 10^{-15} \mathrm{~m}\), and \(E\) is the energy in joules. (a) Estimate \(E\) in joules per alpha particle. (b) Using the equation \(E=m v^{2} / 2\), estimate the velocity (meters per second) each deuteron must have if a collision between the two of them is to supply the activation energy for fusion \((m\) is the mass of the deuteron in kilograms).
Carbon from a cypress beam obtained from the tomb of an ancient Egyptian king gave \(9.2\) disintegrations/minute of \(C-14\) per gram of carbon. Carbon from living material gives \(15.3\) disintegrations/min of C-14 per gram of carbon. Carbon-14 has a half-life of 5730 years. How old is the beam?
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