Two basic laws of chemistry are the law of conservation of mass and the law of constant composition. Which of these laws (if any) do the following statements illustrate? (a) Lavoisier found that when mercury(II) oxide, \(\mathrm{HgO}\), decomposes, the total mass of mercury(Hg) and oxygen formed equals the mass of mercury(II) oxide decomposed. (b) Analysis of the calcium carbonate found in the marble mined in Carrara, Italy, and in the stalactites of the Carlsbad Caverns in New Mexico gives the same value for the percentage of calcium in calcium carbonate. (c) Hydrogen occurs as a mixture of two isotopes, one of which is twice as heavy as the other.

Short Answer

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(a) When mercury(II) oxide decomposes, the total mass of mercury and oxygen formed is equal to the mass of mercury(II) oxide decomposed. (b) The percentage of calcium in calcium carbonate is the same in marble mined from Italy and in stalactites in the Carlsbad Caverns of New Mexico. (c) Hydrogen occurs as a mixture of two isotopes with different masses. Answer: (a) Law of Conservation of Mass (b) Law of Constant Composition (c) Neither

Step by step solution

01

Statement (a) analysis

This statement states that when mercury(II) oxide, \(\mathrm{HgO}\), decomposes, the total mass of mercury (Hg) and oxygen formed is equal to the mass of mercury(II) oxide decomposed. This implies that the mass of reactants is equal to the mass of products, which aligns with the Law of Conservation of Mass.
02

Statement (b) analysis

This statement states that the percentage of calcium in calcium carbonate is the same regardless of whether it is found in marble mined in Carrara, Italy, or in the stalactites of the Carlsbad Caverns in New Mexico. This means that the proportions of elements in this compound are constant and don't vary depending on their source, which conforms to the Law of Constant Composition.
03

Statement (c) analysis

This statement states that hydrogen occurs as a mixture of two isotopes with different masses. This information is related to the isotopes of an element and their abundance but does not demonstrate a relation between either the conservation of mass in a chemical reaction or the constant proportion of elements found in compounds. Hence, it does not illustrate either the Law of Conservation of Mass or the Law of Constant Composition.

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