Chapter 20: Problem 4
Write a balanced equation to represent the roasting of copper(I) sulfide to form "blister copper"
Chapter 20: Problem 4
Write a balanced equation to represent the roasting of copper(I) sulfide to form "blister copper"
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Get started for freeTaking \(K_{\text {ip }} \mathrm{PbCl}_{2}=1.7 \times 10^{-5}\) and assuming \(\left[\mathrm{Cl}^{-}\right]=0.20 \mathrm{M}\), calculate the concentration of \(\mathrm{Pb}^{2+}\) at equilibrium.
Iron(II) can be oxidized to iron(III) by permanganate ion in acidic solution. The permanganate ion is reduced to manganese(II) ion. (a) Write the oxidation half-reaction, the reduction half-reaction, and the overall redox equation. (b) Calculate \(E^{\circ}\) for the reaction. (c) Calculate the percentage of Fe in an ore if a \(0.3500-\mathrm{g}\) sample is dissolved and the \(\mathrm{Fe}^{2+}\) formed requires for titration \(55.63 \mathrm{~mL}\) of a \(0.0200 \mathrm{M}\) solution of \(\mathrm{KMnO}_{4}\)
Write a balanced redox equation for the reaction of mercury with aqua regia, assuming the products include \(\mathrm{HgCl}_{4^{2-}}\) and \(\mathrm{NO}_{2}(g)\).
A \(0.500-\mathrm{g}\) sample of zinc-copper alloy was treated with dilute hydrochloric acid. The hydrogen gas evolved was collected by water displacement at \(27^{\circ} \mathrm{C}\) and a total pressure of \(755 \mathrm{~mm} \mathrm{Hg}\). The volume of the water displaced by the gas is \(105.7 \mathrm{~mL}\). What is the percent composition, by mass, of the alloy? (Vapor pressure of \(\mathrm{H}_{2} \mathrm{O}\) at \(27^{\circ} \mathrm{C}\) is \(26.74 \mathrm{~mm} \mathrm{Hg}\).) Assume only the zinc reacts.
Using Table \(20.4\), calculate, for the disproportionation of \(\mathrm{Au}^{+}\), (a) \(K\). (b) the concentration of \(\mathrm{Au}^{+}\) in equilibrium with \(0.10 \mathrm{M} \mathrm{Au}^{3+}\).
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