Chapter 21: Problem 2
Name the following compounds. (a) \(\mathrm{HBrO}_{3}\) (b) KIO (c) \(\mathrm{NaClO}_{2}\) (d) \(\mathrm{NaBrO}_{4}\)
Chapter 21: Problem 2
Name the following compounds. (a) \(\mathrm{HBrO}_{3}\) (b) KIO (c) \(\mathrm{NaClO}_{2}\) (d) \(\mathrm{NaBrO}_{4}\)
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Get started for freeThe equilibrium constant at \(25^{\circ} \mathrm{C}\) for the reaction $$\mathrm{Br}_{2}(l)+\mathrm{H}_{2} \mathrm{O} \rightleftharpoons \mathrm{H}^{+}(a q)+\mathrm{Br}^{-}(a q)+\mathrm{HBrO}(a q)$$ is \(1.2 \times 10^{-9} .\) This is the system present in a bottle of "bromine water." Assuming that HBrO does not ionize appreciably, what is the pH of the bromine water?
The average concentration of bromine (as bromide) in seawater is \(65 \mathrm{ppm} .\) Calculate (a) the volume of seawater \(\left(d=64.0 \mathrm{lb} / \mathrm{ft}^{3}\right)\) in cubic feet required to produce one kilogram of liquid bromine. (b) the volume of chlorine gas in liters, measured at \(20^{\circ} \mathrm{C}\) and \(762 \mathrm{~mm}\) \(\mathrm{Hg}\), required to react with this volume of sea water.
Write a balanced net ionic equation for the reaction of sulfuric acid with (a) \(\mathrm{CaCO}_{3}(s)\) (b) a solution of \(\mathrm{NaOH}\). (c) Cu; assume the \(\mathrm{SO}_{4}{ }^{2-}\) ion is reduced to \(\mathrm{SO}_{2}\).
Choose the strongest acid from each group. (a) \(\mathrm{HClO}, \mathrm{HBrO}, \mathrm{HIO}\) (b) \(\mathrm{HIO}, \mathrm{HIO}_{3}, \mathrm{HIO}_{4}\) (c) \(\mathrm{HIO}, \mathrm{HBrO}_{2}, \mathrm{HBrO}_{4}\)
Explain why (a) acid strength increases as the oxidation number of the central non- metal atom increases. (b) nitrogen dioxide is paramagnetic. (c) the oxidizing strength of an oxoanion is inversely related to \(\mathrm{pH}\). (d) sugar turns black when treated with concentrated sulfuric acid.
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