Chapter 15: Problem 17
Explain the meaning of the orientation factor in the collision model.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chapter 15: Problem 17
Explain the meaning of the orientation factor in the collision model.
These are the key concepts you need to understand to accurately answer the question.
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Get started for freeThe half-life for the radioactive decay of \(\mathrm{C}-14\) is 5730 years and is inde- pendent of the initial concentration. How long does it take for 25\(\%\) of the C-14 atoms in a sample of \(C-14\) to decay? If a sample of C-14 initially contains 1.5 mmol of C-14, how many millimoles are left after 2255 years?
Geologists can estimate the age of rocks by their uranium- \(238 \mathrm{con}-\) tent. The uranium is incorporated in the rock as it hardens and then decays with first-order kinetics and a half-life of 4.5 billion years. A rock contains 83.2\(\%\) of the amount of uranium-238 that it contained when it was formed. (The amount that the rock contained when it was formed can be deduced from the presence of the decay products of \(U-238 . )\) How old is the rock?
What is the general two-step mechanism by which most enzymes work?
The previous exercise shows how the first-order integrated rate law is derived from the first-order differential rate law. Begin with the sec- ond-order differential rate law and derive the second-order integrated rate law.
The desorption of a single molecular layer of \(n\) -butane from a single crystal of aluminum oxide is found to be first order with a rate constant of 0.128\(/ \mathrm{s}\) at 150 \(\mathrm{K}\) . \begin{equation} \begin{array}{l}{\text { a. What is the haff-life of the desorption reaction? }} \\ {\text { b. If the surface is initially completely covered with } n \text { -butane at }} \\ {150 \mathrm{K}, \text { how long will it take for } 25 \% \text { of the molecules to desorb? For }} \\ {50 \% \text { to desorb? }}\\\\{\text { c. If the surface is initially completely covered, what fraction will remain }} \\ {\text { covered after } 10 \text { s? After } 20 \mathrm{s?}}\end{array} \end{equation}
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