Chapter 12: Problem 58
Replacement of aluminum ions in kaolinite with magnesium ions yields a compound with the formula Mg3Si2O5(OH)4. Assign an oxidation state to each element in this compound.
Short Answer
Expert verified
Oxidation states: Mg = +2, Si = +4, O = -2 in O5 and -2 in OH, H = +1 in OH. The sum of the oxidation states for all elements in the compound Mg3Si2O5(OH)4 is zero, indicating neutrality.
Step by step solution
01
Understanding the Compound Formula
The given formula is Mg3Si2O5(OH)4. Kaolinite has aluminum ions replaced by magnesium ions. Each element in the formula represents an atom with its subscript indicating the number of atoms of that element.
02
Understanding oxidation states
In any compound, the sum of the oxidation states of all the atoms equals the overall charge of the compound. For a neutral compound, like Mg3Si2O5(OH)4, the sum of all oxidation states must equal zero.
03
Assigning oxidation states to oxygen and hydrogen
Oxygen typically has an oxidation state of -2 except in peroxides. Hydrogen typically has an oxidation state of +1 except when bonded to metals where it can be -1. In hydroxide, OH groups, oxygen is -2 and hydrogen is +1.
04
Determining the oxidation state of magnesium
Magnesium is a group 2 metal which typically has an oxidation state of +2.
05
Determining the oxidation state of silicon
Silicon in compounds usually has an oxidation state of +4, especially in silicon-oxygen compounds like silicates.
06
Calculating the total oxidation state
Sum the oxidation states: 3 Mg (+2 each) + 2 Si (+4 each) + 5 O (-2 each) + 4(OH) (-1 for H and -2 for O each). Set this sum equal to zero since the compound is neutral and solve for any unknown oxidation states.
07
Confirming the sum of oxidation states equals zero
Substitute the known oxidation states and confirm that the sum equals zero: (3)(+2) + (2)(+4) + (5)(-2) + 4[(+1) + (-2)] = 0.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Oxidation State Determination
Understanding how to determine oxidation states is a fundamental aspect of redox chemistry, and it's crucial for interpreting reactions and predicting the behavior of compounds. Oxidation states, also known as oxidation numbers, are a bookkeeping system used in chemistry to keep track of electrons during chemical reactions, particularly redox reactions.
In the exercise, we looked at the compound Mg3Si2O5(OH)4. To determine the oxidation state of each element, we adhere to certain rules: oxygen usually has an oxidation state of -2, and hydrogen is typically +1. For metals like magnesium, which is in group 2 of the periodic table, the common oxidation state is +2. Silicon, when bound with oxygen, as in silicates, often has an oxidation state of +4.
By knowing these conventions and the fact that the sum of oxidation states in a neutral compound equals zero, we can assign the correct states to each element. It's a matter of balancing the charges, ensuring that the algebraic sum matches the overall charge of the molecule. This method is a foundational skill in chemistry as it applies to balancing redox equations, understanding electrochemistry, and decoding the nuances of chemical reactions.
In the exercise, we looked at the compound Mg3Si2O5(OH)4. To determine the oxidation state of each element, we adhere to certain rules: oxygen usually has an oxidation state of -2, and hydrogen is typically +1. For metals like magnesium, which is in group 2 of the periodic table, the common oxidation state is +2. Silicon, when bound with oxygen, as in silicates, often has an oxidation state of +4.
By knowing these conventions and the fact that the sum of oxidation states in a neutral compound equals zero, we can assign the correct states to each element. It's a matter of balancing the charges, ensuring that the algebraic sum matches the overall charge of the molecule. This method is a foundational skill in chemistry as it applies to balancing redox equations, understanding electrochemistry, and decoding the nuances of chemical reactions.
Chemical Formulas and Composition
Chemical formulas serve as the shorthand of chemistry; they provide important information about the type and number of atoms present in a compound. For example, in the formula Mg3Si2O5(OH)4, we can see that this compound contains magnesium, silicon, oxygen, and hydrogen in precise ratios.
These ratios are not arbitrary. They reflect the structure of the compound and how different atoms bond to achieve stability. In our exercise, the presence of the OH group indicates that hydroxide ions are part of the compound's structure. Interpreting chemical formulas correctly is essential, as it informs us about the substance's composition and helps us in tasks like assigning oxidation states or understanding the potential reactivity of the compound.
These ratios are not arbitrary. They reflect the structure of the compound and how different atoms bond to achieve stability. In our exercise, the presence of the OH group indicates that hydroxide ions are part of the compound's structure. Interpreting chemical formulas correctly is essential, as it informs us about the substance's composition and helps us in tasks like assigning oxidation states or understanding the potential reactivity of the compound.
Redox Chemistry Education
The term 'redox' is short for reduction-oxidation, which describes all chemical reactions in which the oxidation states of atoms are changed. These processes are a cornerstone of chemical education, highlighting how electrons are transferred between substances.
Educating students about redox reactions starts with a thorough understanding of oxidation states and how to determine them. It also involves teaching about balancing redox reactions, electrochemical cells, and everyday applications like batteries and corrosion. Redox chemistry education strives not only to instill theoretical knowledge but also to develop practical skills in students, enabling them to perform titrations, use redox indicators, and navigate complex systems where redox reactions play a critical role.
Educating students about redox reactions starts with a thorough understanding of oxidation states and how to determine them. It also involves teaching about balancing redox reactions, electrochemical cells, and everyday applications like batteries and corrosion. Redox chemistry education strives not only to instill theoretical knowledge but also to develop practical skills in students, enabling them to perform titrations, use redox indicators, and navigate complex systems where redox reactions play a critical role.