Chapter 13: Problem 79
Calculate the osmotic pressure of a solution containing 24.6 g of glycerin(C3H8O3) in 250.0 mL of solution at 298 K.
Short Answer
Expert verified
The osmotic pressure of the glycerin solution is calculated by first determining the molarity of the solution and then applying the osmotic pressure equation (\( \Pi = MRT \)).
Step by step solution
01
Calculate the molar mass of glycerin (C3H8O3)
To find the molar mass of glycerin, sum the atomic masses of all the atoms in a molecule of glycerin. The atomic masses are C (12.01 g/mol), H (1.008 g/mol), and O (16.00 g/mol). With three carbon atoms, eight hydrogen atoms, and three oxygen atoms, the molar mass is calculated as follows:\( Molar\text{ }Mass = 3 \times 12.01\text{ }g/mol + 8 \times 1.008\text{ }g/mol + 3 \times 16.00\text{ }g/mol \).
02
Calculate the number of moles of glycerin
Use the molar mass from Step 1 to convert the given mass of glycerin to moles using the formula:\( \text{Moles} = \frac{\text{mass}}{\text{molar mass}} \).
03
Convert the volume to liters
Since the volume of the solution is given in milliliters, convert it to liters by dividing by 1000. This is needed because osmotic pressure is usually expressed concerning liters.
04
Calculate the molarity of the solution
Molarity (M) is the concentration of the solute in moles per liter of solution. It is calculated using the formula:\( M = \frac{\text{moles of solute}}{\text{volume of solution in liters}} \).
05
Apply the formula for osmotic pressure
Osmotic pressure ((\Pi ) can be calculated using the formula (\( \Pi = MRT \)), where ( M ) is the molarity of the solution, ( R ) is the ideal gas constant (0.0821 L·atm/K·mol), and ( T ) is the temperature in Kelvin.
06
Calculate the osmotic pressure
Plug in the values for the molarity (( M ), the ideal gas constant (( R ), and the temperature (( T ) into the osmotic pressure equation to get the osmotic pressure.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Molar Mass of Glycerin
Understanding the molar mass of a compound is crucial in chemistry for converting between grams and moles, a fundamental concept in stoichiometry. Glycerin, or C3H8O3, is composed of carbon (C), hydrogen (H), and oxygen (O) atoms. The molar mass represents the sum of the atomic masses of each atom in a single molecule of a substance.
For glycerin:
For glycerin:
- Carbon has an atomic mass close to 12.01 g/mol.
- Hydrogen's atomic mass is about 1.008 g/mol.
- Oxygen has an atomic mass of approximately 16.00 g/mol.
Molarity Formula
In chemistry, the molarity of a solution is defined as the number of moles of solute per liter of solution. It's the most commonly used measure of solution concentration. The formula for molarity is:
\[\begin{equation}M = \frac{n}{V}\end{equation}\]
Where:
\[\begin{equation}M = \frac{n}{V}\end{equation}\]
Where:
- ()M) is the molarity
- ()n) is the number of moles of the solute
- ()V) is the volume of the solution in liters
Ideal Gas Constant
The ideal gas constant, denoted as ()R), is a physical constant that appears in the equation of state for ideal gases. The value of this constant is key to connecting the physical properties of gases with the amount of substance present. In osmotic pressure calculations, the ideal gas constant provides a bridge between thermodynamic quantities and the properties of the solution.
The value of the ideal gas constant is 0.0821 L·atm/K·mol, which is derived from the relationship between pressure, volume, and temperature of an ideal gas. When we use it in osmotic pressure calculations, we essentially treat the solute particles as if they were an ideal gas, allowing us to apply gas laws to solutions.
The value of the ideal gas constant is 0.0821 L·atm/K·mol, which is derived from the relationship between pressure, volume, and temperature of an ideal gas. When we use it in osmotic pressure calculations, we essentially treat the solute particles as if they were an ideal gas, allowing us to apply gas laws to solutions.
Converting Milliliters to Liters
Accurate volume measurement is essential in solution chemistry, and it's often necessary to convert between units of volume. In particular, converting milliliters to liters is a common task since laboratory measurements may use different units. The conversion is simple:
\[\begin{equation}1 liter = 1,000 millilitersd \end{equation}\]
Therefore, to convert milliliters to liters, divide the number of milliliters by 1,000. This step is essential when calculating molarity, as the volume of the solution is required in liters. Ensuring that the volume units match those used in the molarity formula is crucial for accurate calculations.
\[\begin{equation}1 liter = 1,000 millilitersd \end{equation}\]
Therefore, to convert milliliters to liters, divide the number of milliliters by 1,000. This step is essential when calculating molarity, as the volume of the solution is required in liters. Ensuring that the volume units match those used in the molarity formula is crucial for accurate calculations.